Dimethyl-bis(trimethylgermyloxy)germane | 1370702-66-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Dimethyl-bis(trimethylgermyloxy)germane
• 英文别名: dimethyl-bis(trimethylgermyloxy)germane
• CAS: 1370702-66-1
• 化学式: C₈H₂₄Ge₃O₂
• 分子量: 370.047
• InChiKey: PNMZBGSFUWMAPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.39
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Trimethylgermyl-essigsaeure 以 甲醇 、 乙腈 为溶剂， 生成 Dimethyl-bis(trimethylgermyloxy)germane 、 1,2-bis(trimethylgermyl)ethane 、 二(三甲基锗烷基)氧化物
  参考文献：
  名称：

  Synthesis of α-germyl and α-silylcarboxylic acids and selected electrochemical oxidations

  摘要：

  New alpha-germylcarboxylic acids, alpha-silyl-alpha-halocarboxylic and alpha-silyl-alpha-alkylcarboxylic acids including some known alpha-silyl(cycloalkyl)carboxylic acids have been prepared by different synthetic methods. The anodic oxidation in basic methanol of selected examples of these acids has been investigated under various experimental conditions to afford mainly oxidative degermylation/desilylation and decarboxylation products. Based on the emerged products, various mechanisms are suggested and discussed. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.12.025

文献信息

• Synthesis of α-germyl and α-silylcarboxylic acids and selected electrochemical oxidations
  作者：Anna Rakovshik、Alex V. Shtelman、James Y. Becker

  DOI：10.1016/j.jorganchem.2011.12.025

  日期：2012.6

  New alpha-germylcarboxylic acids, alpha-silyl-alpha-halocarboxylic and alpha-silyl-alpha-alkylcarboxylic acids including some known alpha-silyl(cycloalkyl)carboxylic acids have been prepared by different synthetic methods. The anodic oxidation in basic methanol of selected examples of these acids has been investigated under various experimental conditions to afford mainly oxidative degermylation/desilylation and decarboxylation products. Based on the emerged products, various mechanisms are suggested and discussed. (C) 2011 Elsevier B. V. All rights reserved.