succinimidomelamine | 135020-91-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: succinimidomelamine
• 英文别名: 1-(4,6-Diamino-1,3,5-triazin-2-yl)pyrrolidine-2,5-dione
• CAS: 135020-91-6
• 化学式: C₇H₈N₆O₂
• 分子量: 208.18
• InChiKey: DFAZRVFSSZSFKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  128
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  succinimidomelamine 、 氯甲酸甲酯 在 正丁基锂 作用下， 以 1,4-二氧六环 、 正己烷 为溶剂， 反应 23.0h， 生成 N'-(methylcarbamoyl)-succinimidomelamine 、 N',N''-di-(methylcarbamoyl)-succinimidomelamine 、 N',N',N''-tri-(methylcarbamoyl)-succinimidomelamine
  参考文献：
  名称：

  Method for Producing Triazine Carbamates Using Chloroformates

  摘要：

  本发明涉及一种通过在至少一种三嗪与至少一种氯甲酸酯在至少一种碱性或碱土金属化合物存在下进行转化来生产三嗪氨基甲酸酯的方法，其中所述碱性或碱土金属化合物不以醇酸盐的形式存在。

  公开号：

  US20110295001A1

文献信息

• [EN] METHOD FOR ALKYLATING AN AMINO COMPOUND<br/>[FR] PROCÉDÉ D'ALKYLATION D'UN COMPOSÉ AMINÉ
  申请人：BOREALIS AGROLINZ MELAMINE

  公开号：WO2018096011A1

  公开（公告）日：2018-05-31

  The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II), (II), wherein • R4 and R5 mean independently from each other Q1 or a moiety of the formula R6-N-R7 or R8-N-R9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q1 means a linear or branched C1-C30-alkyl or a cyclic substituent in form of a C5-C20-cycloalkyl, a C5-C20-aryl, a C1-C20-alkylsubstituted C5-C20-aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C1-C30-alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-,-OC(O)-,-C(O)- and/or –OC(O)O-, • R1, R2, R3, R6, R7, R8 and R9 mean independently from each other H, linear or branched C1-C20-alkyl, C5-C20-cyclo alkyl, C5-C20-aryl, C1-C20-alkylsubstituted C5-C20-aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, - OC(O)-, -C(O)- and/or –OC(O) O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and • X means O or S, is reacted with at least one alcohol of the general formula (III) R10-OH wherein R10 means a linear or branched C1-C20-alkyl, C5-C20-cycloalkyl, or C1-C20- alkylsubstituted C5-C20-aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, -OC(O)-, -C(O)- and/or –OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) Mn(RuO4) and/or at least one Perruthenate of the general formula (V) M(RuO4)n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.

  本发明涉及一种烷基化氨基化合物的方法，其特征在于至少使用一种通式(I)的三嗪衍生物或至少使用一种通式(II)的脲或脲衍生物，其中•R4和R5分别独立地表示Q1或式R6-N-R7或R8-N-R9的基团，其中心氮原子与通式(I)的三嗪环结构相连，其中-Q1表示线性或支链的C1-C30烷基或形式为C5-C20环烷基，C5-C20芳基，C1-C20烷基取代的C5-C20芳基或环状不饱和羧酸酰胺的取代基，其中C1-C30烷基或环状取代基可以被一个或多个氧原子，硫原子，取代的氮原子和/或一个或多个-C(O)O-，-OC(O)-，-C(O)-和/或-OC(O)O-类型的基团所中断，•R1，R2，R3，R6，R7，R8和R9分别独立地表示H，线性或支链的C1-C20烷基，C5-C20环烷基，C5-C20芳基，C1-C20烷基取代的C5-C20芳基，其中每种情况都可以被一个或多个氧原子，硫原子和/或取代的氮原子和/或一个或多个-C(O)O-，-OC(O)-，-C(O)-和/或-OC(O)O-类型的基团所中断，并且可以通过一个或多个羟基和/或巯基进行官能化，•X表示O或S，与至少一种通式(III)的醇反应，通式(III)为R10-OH，其中R10表示线性或支链的C1-C20烷基，C5-C20环烷基或C1-C20烷基取代的C5-C20芳基，每种情况都可以被一个或多个氧原子，硫原子，取代的氮原子和/或一个或多个-C(O)O-，-OC(O)-，-C(O)-和/或-OC(O)O-类型的基团所中断，并且可以通过一个或多个羟基和/或巯基进行官能化，其中在至少一种Mn（RuO4）的通式（IV）钌酸盐和/或至少一种M（RuO4）n的通式（V）高钒酸盐的存在下进行反应，其中阳离子M选择自碱金属，碱土金属或取代或未取代的铵阳离子组成的群。
• METHOD FOR ALKYLATING AN AMINO COMPOUND
  申请人：Borealis Agrolinz Melamine GmbH

  公开号：EP3327009A1

  公开（公告）日：2018-05-30

  The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II) wherein • R4 and R5 mean independently from each other Q1 or a moiety of the formula R6-N-R7 or R8-N-R9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q1 means a linear or branched C1-C30-alkyl or a cyclic substituent in form of a C5-C20-cycloalkyl, a C5-C20-aryl, a C1-C20-alkylsubstituted C5-C20-aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C1-C30-alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O-, • R1, R2, R3, R6, R7, R8 and R9 mean independently from each other H, linear or branched C1-C20-alkyl, C5-C20-cyclo alkyl, C5-C20-aryl, C1-C20-alkylsubstituted C5-C20-aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, - OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and • X means O or S, is reacted with at least one alcohol of the general formula (III)          R10-OH wherein R10 means a linear or branched C1-C20-alkyl, C5-C20-cycloalkyl, or C1-C20-alkylsubstituted C5-C20-aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) Mn(RuO4) and/or at least one Perruthenate of the general formula (V) M(RuO4)n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.

  本发明涉及一种使氨基化合物烷基化的方法，其特征在于至少一种通式 (I) 的三嗪衍生物 或至少一种通式（II）的脲或脲衍生物 其中 - R4 和 R5 指彼此独立的 Q1 或式 R6-N-R7 或 R8-N-R9 的分子，其中心氮原子与式 (I) 结构的三嗪环结合，其中 - Q1 指线性或支链 C1-C30 烷基或环状取代基，其形式为 C5-C20 环烷基、C5-C20 芳基、C1-C20-烷基取代的 C5-C20 芳基或环状不饱和羧酸的酰胺、其中，C1-C30-烷基或环状取代基可以被一个或多个氧原子、硫原子、取代的氮原子和/或一个或多个-C(O)O-、-OC(O)-、-C(O)-和/或-OC(O)O-类型的基团打断、 - R1、R2、R3、R6、R7、R8 和 R9 相互独立地指 H、直链或支链 C1-C20-烷基、C5-C20-环烷基、C5-C20-芳基、C1-C20-烷基取代的 C5-C20-芳基，在每种情况下可被一个或多个氧原子打断、硫原子和/或取代的氮原子和/或一个或多个-C(O)O-、-OC(O)-、-C(O)-和/或-OC(O)O-类型的基团和/或可被一个或多个羟基和/或巯基官能化，以及 - X 指 O 或 S、 与至少一种通式（III）的醇反应 R10-OH 其中 R10 指线性或支链 C1-C20-烷基、C5-C20-环烷基或 C1-C20-烷基取代的 C5-C20-芳基，在每种情况下可被一个或多个氧原子、硫原子、取代的氮原子和/或一个或多个-C(O)O-、-OC(O)-、-C(O)-和/或-OC(O)O-类型的基团和/或可被一个或多个羟基和/或巯基官能化、其中，反应在至少一种通式（IV）Mn(RuO4)的钌酸盐和/或至少一种通式（V）M(RuO4)n 的珀钌酸盐存在下进行，其中阳离子 M 选自包括碱、土碱或取代或非取代铵阳离子的组。
• Aminoplast molding compounds for products exhibiting an improved flexibility and aminoplast products exhibiting and improved flexibility
  申请人：Ratzsch Manfred

  公开号：US20060100317A1

  公开（公告）日：2006-05-11

  An aminoplast molding compound comprised of mixtures consisting of meltable 20 to 1000-ring polytriazine ethers, in which the triazine rings are primarily linked by binding links of the —NH—CHR 2 —O—R 4 —O—CHR 2 —NH— and —NH—CHR 2 —NH— type, whereby: R 2 ═H, C 1 -C 7 -alkyl; R 4 ═C 2 -C 18 -alkylene, —CH(CH 3 )—CH 2 — C2-C12 —-alkylene-O—CH 2 —CH(CH 3 )—, —CH(CH 3 )—CH 2 —O— C2-C12 —-arylene-O—CH 2 —CH(CH 3 )—, —[CH 2 —CH 2 —O—CH 2 —CH 2 ] n —, —[CH 2 —CH(CH 3 )—O—CH 2 —CH(CH 3 )] n —, —[—O—CH 2 —CH 2 —CH 2 —CH 2 —] n —, —[(CH 2 ) 2-8 —O—CO— C6-C14 —-arylene-CO—O—(CH 2 ) 2-8 —] n —, —[(CH 2 ) 2-8 —O—CO— C2-C12 —-alkylene-CO—O—(CH 2 ) 2-8 —] n —, wherein n=1 to 200. The aminoplast molding compounds are also comprised of sequences containing siloxane groups, sequences based on the alkylene oxide adducts of melamine, phenol ether sequences based on bivalent phenols and diols, and these compounds can contain up to 50% by mass of additional reactive polymers of the ethylene-copolymer, maleic anhydride-copolymer, modified maleic anhydride-copolymer, poly(meth)acrylate, polyamide, polyester and/or polyurethane type, up to 75% by mass of fillers, up to 20% by mass of diols, and up to 5% by mass of stabilizers, UV absorbers and/or auxiliary agents.

  一种氨基塑料成型化合物，由可熔化的 20 至 1000 环聚三嗪醚混合物组成，其中的三嗪环主要通过 -NH-CHR 2 -O-R 4 -O-CHR 2 -NH-和-NH-CHR 2 -NH-型，其中R 2 ═H，C 1 -C 7 -烷基；R 4 ═C 2 -C 18 -烯烃，-CH(CH 3 ）-CH 2 - C2-C12 --亚烷基-O-CH 2 -CH(CH 3 )-、-CH(CH 3 )-CH 2 -O- C2-C12 --芳烃-O-CH 2 -CH(CH 3 )-、-[CH 2 -[CH 2 2 -O-CH 2 -CH 2 ] n -、-[CH 2 -CH(CH 3 )-O-CH 2 -CH(CH 3 )] n -、-[-O-CH 2 -CH 2 -CH 2 -CH 2 -] n -，-[(CH 2 ) 2-8 -O-CO- C6-C14 --芳烃-CO-O-(CH 2 ) 2-8 -] n -，-[(CH 2 ) 2-8 -O-CO- C2-C12 --烯烃-CO-O-(CH 2 ) 2-8 -] n -，其中 n=1 至 200。氨基塑料成型化合物还包括含有硅氧烷基团的序列、基于三聚氰胺的氧化亚烷加成物的序列、基于二价酚和二元醇的酚醚序列，这些化合物可含有高达 50%（质量百分比）的乙烯-共聚物附加反应性聚合物、马来酸酐-共聚物、改性马来酸酐-共聚物、聚（甲基）丙烯酸酯、聚酰胺、聚酯和/或聚氨酯类型的附加反应性聚合物，按重量计最多可含有 75%的填料，按重量计最多可含有 20%的二元醇，以及按重量计最多可含有 5%的稳定剂、紫外线吸收剂和/或辅助剂。
• AMINOPLAST-FORMMASSEN FÜR ERZEUGNISSE VERBESSERTER FLEXIBILITÄT UND AMINOPLASTERZEUGNISSE VERBESSERTER FLEXIBILITÄT
  申请人：AMI - Agrolinz Melamine International GmbH

  公开号：EP1521805A1

  公开（公告）日：2005-04-13
• PREPREGS FÜR FASERVERBUNDE HOHER FESTIGKEIT UND ELASTIZITÄT
  申请人：AMI Agrolinz Melamine International GmbH

  公开号：EP1603969A1

  公开（公告）日：2005-12-14