trans-dibromo(1,4,8,11-tetra-azacyclotetradecane)manganese(III) bromide | 134779-69-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: trans-dibromo(1,4,8,11-tetra-azacyclotetradecane)manganese(III) bromide
• CAS: 134779-69-4；60105-50-2
• 化学式: Br*C₁₀H₂₄Br₂MnN₄
• 分子量: 494.977
• InChiKey: PSJKSDBTQBSOLO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  在 hydrobromic acid 作用下， 以 水 为溶剂， 以25%的产率得到trans-dibromo(1,4,8,11-tetra-azacyclotetradecane)manganese(III) bromide
  参考文献：
  名称：

  Daugherty, Patricia A.; Glerup, Joergen; Goodson, Patricia A., Acta Chemica Scandinavica, 1991, vol. 45, # 3, p. 244 - 253

  摘要：

  DOI：

文献信息

• Structural and mechanistic studies of co-ordination compounds. Part XII. Syntheses and characterization of some dianiono(1,4,8,11-tetra-azacyclotetradecane)-manganese(III), -iron(III), and -nickel(III) salts
  作者：Pui-Ki Chan、Chung-Kwong Poon

  DOI：10.1039/dt9760000858

  日期：——

  r. spectra in the 790–910 cm–1 region. In some cases, the assignment of a trans configuration to the dihalogeno-complexes is confirmed by the presence of only one ν(M–X) stretching frequency in their far-i.r. spectra. Magnetic susceptibilities show that all the d4 complexes prepared are high spin, whereas d6 and d7 complexes are low spin. For the d5 iron(III) system, all the cis complexes prepared are

  顺式-[FeX 2（L 4）] + [L 4＝ 1,4,8,11-四氮杂环十四烷（cyclam）类型的配合物的合成与表征；X = Cl，Br和NCS]和反式-[MX 2（L 4）] +（M = Mn，X = Cl，Br，NCS或N 3； M = Fe，X = Cl，Br或NCS ：和M ＝ Ni，X ＝ Cl或Br）被描述。这些配合物的几何构型分配是根据它们在790–910 cm –1区域的红外光谱确定的。在某些情况下，的分配反式二卤代配合物的构型可通过其远红外光谱中仅存在一个ν（MX）拉伸频率来证实。磁化率表明，所有制备的d 4配合物均为高自旋，而d 6和d 7配合物均为低自旋。对于d 5 iron（III）系统，所有制备的顺式复合物均为高自旋，而反式复合物为低自旋。但是，反型-[FeBr 2（L 4）] [ClO 4 ]的µ 295室温下3.90 BM似乎处于高自旋-低自旋平衡。歧义的
• Manganese (III) cyclam complexes with aqua, iodo, nitrito, perchlorato and acetic acid/acetato axial ligands
  作者：Susanne Mossin、Henning Osholm Sørensen、Høgni Weihe、Jørgen Glerup、Inger Søtofte

  DOI：10.1016/j.ica.2004.10.005

  日期：2005.3

  The syntheses, structures and magnetic properties of five new manganese (III) cyclam complexes, trans-[Mn(cyclam)(OH2)(2)]-(CF3SO3)(3)center dot-H2O, trans-[Mn(cyclam)I-2]I, trans-[Mn(cyclam)(ONO)(2)]ClO4, trans-[Mn(cyclam)(OClO3)(2)]ClO4 and trans-[Mn(cyclam) (CH3COO)(CH3COOH)](ClO4)(2), are reported. Cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane. The complexes all exhibit pronounced tetragonal elongation of the coordination octahedron with the four cyclam nitrogens occupying the four equatorial positions. The magnetic properties are consistent with the formulation of the complexes as high-spin d(4) systems. trans-[Mn(cyclam)(OH2)(2)](CF3SO3)(3)center dot H2O is shown to be a convenient starting material for the syntheses of trans cyclam complexes. [Mn(cyclam)(CH3COO)(CH3COOH)](ClO4)(2) exhibits extremely short intermolecular hydrogen bonds resulting in a pseudo-chain structure. The tilt of the axial ligands with respect to the equatorial plane containing the manganese and the cyclam nitrogen atoms is discussed. (c) 2004 Elsevier B.V. All rights reserved.