iron(II) tris(pyrazolyl)methanesulfonate | 868363-75-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吖庚因类
• 英文名称: iron(II) tris(pyrazolyl)methanesulfonate
• CAS: 868363-75-1
• 化学式: C₂₀H₁₈FeN₁₂O₆S₂
• 分子量: 642.419
• InChiKey: XQRTVJZWIVSMLL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  iron(II) tris(pyrazolyl)methanesulfonate 以 异丙醇 、 乙腈 为溶剂， 生成 dilithium [tricyano(tris(pyrazolyl)methanesulfonate)iron(II)]
  参考文献：
  名称：

  Long-range superexchanged magnetic interaction observed in heterometallic complex: {[FeII(Tpms)(CN)3][MnII(H2O)2(DMF)2]}·DMF

  摘要：

  A new tri-cyanometalate building block for heterometallic complexes, [PPh4](2)[Fe-II(Tpms)(CN)(3)] (2) (PPh4 = tetraphenylphosphonium; Tpms = tris(pyrazolyl) methanesulfonate), has been prepared. Using it as a building block, a one-dimensional chain compound, {[Fe-II(Tpms)(CN)(3)][Mn-II(H2O)(2)( DMF)(2)]}. DMF (3), has been synthesized and structurally characterized. The magnetic properties of 3 correspond to a ferromagnetic chain with weak long-range superexchanged magnetic interaction between the high-spin manganese(II) ions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.060
• 作为产物：
  描述：

  ferrous(II) sulfate heptahydrate 、 lithium tris(1-pyrazolyl)methanesulfonate 以 水 为溶剂， 以89%的产率得到iron(II) tris(pyrazolyl)methanesulfonate
  参考文献：
  名称：

  Long-range superexchanged magnetic interaction observed in heterometallic complex: {[FeII(Tpms)(CN)3][MnII(H2O)2(DMF)2]}·DMF

  摘要：

  A new tri-cyanometalate building block for heterometallic complexes, [PPh4](2)[Fe-II(Tpms)(CN)(3)] (2) (PPh4 = tetraphenylphosphonium; Tpms = tris(pyrazolyl) methanesulfonate), has been prepared. Using it as a building block, a one-dimensional chain compound, {[Fe-II(Tpms)(CN)(3)][Mn-II(H2O)(2)( DMF)(2)]}. DMF (3), has been synthesized and structurally characterized. The magnetic properties of 3 correspond to a ferromagnetic chain with weak long-range superexchanged magnetic interaction between the high-spin manganese(II) ions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.060