(η(5)-C5H5)Fe(η(5)-C5H4-CCC6H4CCSi(i)Pr) | 185225-34-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: (η(5)-C5H5)Fe(η(5)-C5H4-CCC6H4CCSi(i)Pr)
• 英文别名: cyclopenta-1,3-diene;2-[4-(2-cyclopenta-2,4-dien-1-ylethynyl)phenyl]ethynyl-tri(propan-2-yl)silane;iron(2+)
• CAS: 185225-34-7
• 化学式: C₂₉H₃₄FeSi
• 分子量: 466.521
• InChiKey: LBDPBLHGSXEILG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η(5)-C5H5)Fe(η(5)-C5H4-CCC6H4CCSi(i)Pr) 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 以91%的产率得到(4-ethynylphenyl)ethynylferrocene
  参考文献：
  名称：

  Ruthenium or Ferrocenyl Homobimetallic and RuPdRu and FePdFe Heterotrimetallic Complexes Connected by Unsaturated, Carbon-Rich −C⋮CC₆H₄C⋮C− Bridges

  摘要：

  The reaction of 1,4-diethynylbenzene with cis-RuCl2(dppe)(2) and iodoferrocene gave the homobimetallic systems Cl(dppe)(2)Ru-C=CC6H4C=C-Ru(dppe)(2)Cl (2) and (eta 5-C5H5)Fe(eta(5)-C5H4)-C=CC6H4C= C-(eta(5)-C5H4)Fe(eta(5)-C5H5) (3), respectively. The organometallic terminal alkynes Cl(dppe)(2)Ru-C=CC6H4C=CH (6) and (eta(5)-C5H5)Fe(eta(5)-C5H4-C=CC6H4C=CH) (8), obtained by desilylation of the corresponding complexes Cl(dppe)(2)Ru-C=CC6H4C=(CSiPr3)-Pr-i (5) and (eta(5)-C5H5)Fe(eta(5)-C5H4-C=CC6H4C=(CSiPr3)-Pr-i) (7), were used as key starting products for access to the heterotrimetallic systems trans-(P(n)Bu(3))(2)Pd[-C=CC6H4C=C-Ru(dppe)(2)-Cl](2) (10; 53%) and trans-(PnBu(3))(2)Pd[(-C=CC6H4C-C5H4-eta(5))Fe(eta(5)-C5H5)](2). (11; 73%) by reaction with PdCl2(PBu(3))(2). The cyclic voltammetry studies of the complexes 2 and 3 have shown that the electrochemical response was strongly dependent on the connection type between the two terminal organometallic fragments and the organic bridge and that the insertion of the palladium moiety trans-Pd(PBu(3))(2) in the trimetallic complexes 10 and 11 induced totally different electrochemical behavior.

  DOI：

  10.1021/om960664a
• 作为产物：
  描述：

  iodoferrocene 、 ((4-乙炔苯基)乙炔)三异丙基硅烷 在 bis-triphenylphosphine-palladium(II) chloride 、 copper diacetate 、 二异丙胺 作用下， 以 further solvent(s) 为溶剂， 以64%的产率得到(η(5)-C5H5)Fe(η(5)-C5H4-CCC6H4CCSi(i)Pr)
  参考文献：
  名称：

  Ruthenium or Ferrocenyl Homobimetallic and RuPdRu and FePdFe Heterotrimetallic Complexes Connected by Unsaturated, Carbon-Rich −C⋮CC₆H₄C⋮C− Bridges

  摘要：

  The reaction of 1,4-diethynylbenzene with cis-RuCl2(dppe)(2) and iodoferrocene gave the homobimetallic systems Cl(dppe)(2)Ru-C=CC6H4C=C-Ru(dppe)(2)Cl (2) and (eta 5-C5H5)Fe(eta(5)-C5H4)-C=CC6H4C= C-(eta(5)-C5H4)Fe(eta(5)-C5H5) (3), respectively. The organometallic terminal alkynes Cl(dppe)(2)Ru-C=CC6H4C=CH (6) and (eta(5)-C5H5)Fe(eta(5)-C5H4-C=CC6H4C=CH) (8), obtained by desilylation of the corresponding complexes Cl(dppe)(2)Ru-C=CC6H4C=(CSiPr3)-Pr-i (5) and (eta(5)-C5H5)Fe(eta(5)-C5H4-C=CC6H4C=(CSiPr3)-Pr-i) (7), were used as key starting products for access to the heterotrimetallic systems trans-(P(n)Bu(3))(2)Pd[-C=CC6H4C=C-Ru(dppe)(2)-Cl](2) (10; 53%) and trans-(PnBu(3))(2)Pd[(-C=CC6H4C-C5H4-eta(5))Fe(eta(5)-C5H5)](2). (11; 73%) by reaction with PdCl2(PBu(3))(2). The cyclic voltammetry studies of the complexes 2 and 3 have shown that the electrochemical response was strongly dependent on the connection type between the two terminal organometallic fragments and the organic bridge and that the insertion of the palladium moiety trans-Pd(PBu(3))(2) in the trimetallic complexes 10 and 11 induced totally different electrochemical behavior.

  DOI：

  10.1021/om960664a