Ge(NON^tBu) | 146748-67-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Ge(NON^tBu)
• 英文别名: (O(SiMe₂NtBu)₂)Ge；(NON^tBu)Ge；Ge(O(SiMe₂NtBu)₂)
• CAS: 146748-67-6
• 化学式: C₁₂H₃₀GeN₂OSi₂
• 分子量: 347.144
• InChiKey: NLDKTPGCZOAGIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.16
• 重原子数：
  18.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  15.71
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  Ge(NON^tBu) 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  “ Metallo” -Diels-Alder反应：研究锗亚胺的类金属行为。

  摘要：

  将MesN3（Mes = 2,4,6-Me3 C6 H2）添加到亚甲基[[NONtBu）Ge]（NONtBu = O（SiMe2 NtBu）2）（1）得到锗亚胺，[（NONtBu）Ge = NMes]（2 ）。化合物2表现为准金属，显示出两种反应性，它们都让人联想到过渡金属-亚氨基配合物（经过杂原子和质子源的[2 + 2]加成）以及活化的二烯，经历了[4 + 2]环加成，或“ “-Diels-Alder，反应。在后一种情况下，二烯包括Ge = N键和Mes取代基的π系统，它对包括苯甲醛，二苯甲酮，苯乙烯和苯乙炔在内的亲二烯体具有反应性。

  DOI：

  10.1002/chem.201905693
• 作为产物：
  描述：

  Dilithium;tert-butyl-[[tert-butylazanidyl(dimethyl)silyl]oxy-dimethylsilyl]azanide 以84%的产率得到
  参考文献：
  名称：

  Elias Anil J., Roesky Herbert W., Robinson Ward T., Sheldrick George M., J. Chem. Soc. Dalton Trans, (1993) N 4, S 495-500

  摘要：

  DOI：

文献信息

• Synthesis of Heavy <i>N‐</i> Heterocyclic Tetrylenes: Influence of Ligand Sterics on Structure
  作者：Ryan J. Schwamm、Clara A. Randow、Ahmed Mouchfiq、Matthew J. Evans、Martyn P. Coles、J. Robin Fulton

  DOI：10.1002/ejic.202100447

  日期：2021.9.14

  [(NONDmp)Sn]2 linked through Sn⋅⋅⋅Ar contacts and [(NONtBu)Sn]2 forming the first distannene bearing two amido ligands. In contrast, [(NONDipp)Sn] is monomeric in the solid-state. The lead complexes [(NONPh)Pb]2 and [(NONDmp)Pb]2 are isostructual with their tin analogues while [(NONtBu)Pb] is monomeric in the solid-state. Solution phase NMR spectroscopic data suggest that all [(NONR)M] compounds are monomeric

  [(NON R )M] (NON=O(SiMe 2 NR) 2 ] 2−的合成和结构表征；R= t Bu, Ph, 2,6-Me 2 C 6 H 3 (Dmp), 2,描述了6- i Pr 2 C 6 H 3 (Dipp)；M=Ge、Sn、Pb)。锗配合物 [(NON Ph )Ge]、[(NON Dmp )Ge] 和 [(NON Dipp )Ge] 是单体。锡络合物 [(NON Ph )Sn] 2 , [(NON Dmp )Sn] 2和 [(NON t Bu )Sn] 2在固态下是二聚体，[(NON Ph )Sn] 2通过桥接 N 原子形成链接，[(NON Dmp )Sn] 2通过 Sn⋅⋅⋅Ar 接触和 [(NON t Bu )Sn] ] 2形成带有两个酰胺基配体的第一个二锡烯。相比之下，[(NON Dipp )Sn] 在固态下是单体。铅配合物 [(NON Ph )Pb] 2和 [(NON
• Synthesis and characterization of silazoxy metallacycles
  作者：Anil J. Elias、Herbert W. Roesky、Ward T. Robinson、George M. Sheldrick

  DOI：10.1039/dt9930000495

  日期：——

  Novel transition-metal-containing metallacycles of the type [M[O(SiMe2NBut)2]}2] (M = Mn(II) 2, Fe(II) 3, Ni(II) 4 or Cr(II) 5) as well as six-membered heterocycles of the type O(SiMe2NBUt)2M (M = Te(II) 8, Ge(II) 9 or Sn(II) 10) have been synthesised by the reaction of O(SiMe2NButLi)2 with the corresponding metal halides. Reaction of CuCl2 and CuCl with O(SiMe2NButLi)2 yielded a novel copper amide [Cu4O(SiMe2NBUt)2}2] 7 having four copper atoms in a square plane bridged symmetrically from above and below by the diamide ligand. This compound was also prepared by the reaction of O[SiMe2N(But)SnMe3], with CuCl2 and CuCl. X-Ray crystallographic data obtained are as follows: 2, triclinic, space group P1BAR, a = 8.550(2), b = 9.838(2), c = 11.668(2) angstrom, alpha = 83.81(3), beta = 70.35(3), gamma = 72.55(3)-degrees, Z = 1; 3, triclinic, space group P1BAR, a = 11.201(5), b = 11.579(4), c = 14.946(9) angstrom, alpha 1 06.90 (3), beta = 97.59 (2), gamma = 1 0 1 . 27 (2)-degrees, Z = 2.