Frozen solution proton endor spectroscopy of solvated Mo(V) oxochloro complexes
作者:Donato Attanasio、Maria Funicello、Lorenza Suber
DOI:10.1016/0009-2614(88)85098-x
日期:1988.6
Proton ENDOR spectra of randomly oriented [MoOCl4(S)]− complexes, with S = H2O, CH3OH, C2H5OH, and CH3CHO, have been measured at ≈15 K. Complete hyperfine coupling parameters have been obtained for the hydroxyl and aldehydic protons, as well as for some of the alkyl hydrogens. Structural information concerning coordination of the solvent molecules has been obtained in the limit of the point dipole
在≈15K处测量了随机取向的[MoOCl 4(S)] -配合物的质子ENDOR光谱,其中S = H 2 O,CH 3 OH,C 2 H 5 OH和CH 3 CHO。完整的超精细耦合参数已经获得了羟基和醛质子以及一些烷基氢的质子。在点偶极近似的极限中已经获得了与溶剂分子的配位有关的结构信息。在甲醇溶剂化物的光谱中已经检测到归因于有序的第二壳溶剂化球的存在的共振线。