5,8-dimethyl-piperazinocyclam | 78707-10-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: 5,8-dimethyl-piperazinocyclam
• 英文别名: 5,8-Dimethyl-1,5,8,12-tetrazabicyclo[10.2.2]hexadecane
• CAS: 78707-10-5
• 化学式: C₁₄H₃₀N₄
• 分子量: 254.419
• InChiKey: QMRWQYZNYCDEBG-UHFFFAOYSA-N

物化性质

• 沸点：
  343.9±10.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3a-methyl-cis-10b,10c-perhydro-1H,6H:3a,5a,8a,10a-tetraazapyren-3a-ium iodide 在 sodium tetrahydroborate 、 sodium cyanoborohydride 作用下， 以 乙醇 、 水 、 乙腈 为溶剂， 反应 121.25h， 生成 5,8-dimethyl-piperazinocyclam
  参考文献：
  名称：

  Kolinski, Ryszard A., Polish Journal of Chemistry, 1995, vol. 69, # 7, p. 1039 - 1045

  摘要：

  DOI：

文献信息

• Regioselective carbonyl amination using diisobutylaluminum hydride
  作者：Hisashi Yamamoto、Keiji Maruoka

  DOI：10.1021/ja00404a035

  日期：1981.7
• YAMAMOTO, HISASHI;MARUOKA, KEIJI, J. AMER. CHEM. SOC., 1981, 103, N 14, 4186-4194
  作者：YAMAMOTO, HISASHI、MARUOKA, KEIJI

  DOI：——

  日期：——
• Catalysts and methods for catalytic oxidation
  申请人：Busch Hadley Daryle

  公开号：US20070093379A1

  公开（公告）日：2007-04-26

  Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.
• Bleach compositions
  申请人：Busch Daryle Hadley

  公开号：US20080125343A1

  公开（公告）日：2008-05-29

  Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
• CATALYSTS AND METHODS FOR CATALYTIC OXIDATION
  申请人：Busch Daryle Hadley

  公开号：US20100041545A1

  公开（公告）日：2010-02-18

  Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.