O,O'-pivalatobis(trimethylphosphine)silver(I) | 408510-50-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: O,O'-pivalatobis(trimethylphosphine)silver(I)
• 英文别名: silver;2,2-dimethylpropanoate;trimethylphosphane
• CAS: 408510-50-9
• 化学式: C₁₁H₂₇AgO₂P₂
• 分子量: 361.15
• InChiKey: STFNNIISNOZQNH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三甲基乙酸 在 NH₃ 作用下， 以 水 、 甲苯 、 苯 为溶剂， 生成 O,O'-pivalatobis(trimethylphosphine)silver(I)
  参考文献：
  名称：

  Aerosol-assisted chemical vapour deposition (AACVD) of silver films from triorganophosphine adducts of silver carboxylates, including the structure of [Ag(O2CC3F7)(PPh3)2]

  摘要：

  Silver carboxylates [Ag(O2CR): R = Me, Bu-t, 2,4,6-Me3C6H2], fluorocarboxlyates [Ag(O2CRf): R-f = C3F7, C6F13, C7F15] and their phosphine adducts [Ag(O2CR).nPR(3)': R = Me, Bu-t, 2,4,6-Me3C6H2, R' = Me, Ph, n = 2; R = Me, R' = Me, n = 3; Ag(O2CRf).2PPh(3), R-f = C3F7, C6F13, C7F15] have been synthesised, characterised spectroscopically and used as precursors in the aerosol-assisted chemical vapour deposition of silver films. All the phosphine adducts produced films, though in general PMe3 adducts, proved more successful than PPh3 analogues. The fluoro-carboxylates and their PPh3 adducts all generated silver film, though the growth rate for the adducts was lower. All these latter films showed carbon impurities while fluorine was also evident in most cases. The X-ray structure of AgO2CC3F7.2PPh(3) is also reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00718-6