dimethyl-dithiocarbamic acid-(3-hydroxy-propyl ester) | 98278-11-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 二硫代氨基甲酸及其衍生物
• 英文名称: dimethyl-dithiocarbamic acid-(3-hydroxy-propyl ester)
• 英文别名: Dimethyl-dithiocarbamidsaeure-(3-hydroxy-propylester)；3-hydroxypropyl N,N-dimethylcarbamodithioate
• CAS: 98278-11-6
• 化学式: C₆H₁₃NOS₂
• mdl: MFCD30479218
• 分子量: 179.307
• InChiKey: FVOSRYQGZOXFKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.833
• 拓扑面积：
  80.9
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  dimethyl-dithiocarbamic acid-(3-hydroxy-propyl ester) 、 对甲苯磺酰氯 在 N,N-二甲基甲酰胺 作用下， 生成 [1,3]dithian-2-ylidene-dimethyl-ammonium; toluene-4-sulfonate
  参考文献：
  名称：

  Dithiocarbamates. II. The Formation of 1,3-Dithiane, 1,3-Dithiolane, and 1,3-Dithiepane Quaternary Salts

  摘要：

  DOI：

  10.1021/jo01086a008
• 作为产物：
  描述：

  3-溴-1-丙醇 、 sodium dimethyldithiocarbamate 生成 dimethyl-dithiocarbamic acid-(3-hydroxy-propyl ester)
  参考文献：
  名称：

  Dithiocarbamates. II. The Formation of 1,3-Dithiane, 1,3-Dithiolane, and 1,3-Dithiepane Quaternary Salts

  摘要：

  DOI：

  10.1021/jo01086a008

文献信息

• Fluorescent polymer fine particle
  申请人：Fujifilm Corporation

  公开号：EP1783168A2

  公开（公告）日：2007-05-09

  The invention provides a fluorescent polymer fine particle having at least; a polymer particle having a core-shell configuration having a hydrophobic core and a hydrophilic shell; and a fluorescent lanthanoid dye that is integrated with the polymer particle and has a fluorescent lanthanoid cation, wherein a hydrophilic polymer which forms the hydrophilic shell has a polymerizable unit and at least one hydrophilic unit selected from the group consisting of a hydrophilic (meth)acrylamide unit and a hydrophilic vinyl amine unit. The invention further provides a method for forming the fluorescent polymer fine particle having at least dispersing and polymerizing a hydrophobic radical polymerizable monomer in an aqueous solvent in the presence of a radical generator and the presence of a components for forming a hydrophilic polymer which forms the hydrophilic shell; and introducing the fluorescent lanthanoid dye with the polymer particle.

  本发明提供了一种荧光聚合物微粒，该微粒至少具有；具有芯壳构型的聚合物微粒，该聚合物微粒具有疏水芯和亲水壳；以及与聚合物微粒结合并具有荧光镧系阳离子的荧光镧系染料，其中形成亲水壳的亲水聚合物具有可聚合单元和至少一个亲水单元，该亲水单元选自由亲水(甲基)丙烯酰胺单元和亲水乙烯基胺单元组成的组。本发明进一步提供了一种形成荧光聚合物微粒的方法，该方法至少在水性溶剂中，在自由基发生器和形成亲水聚合物的组分存在的情况下，分散和聚合疏水自由基可聚合单体，形成亲水外壳；并将荧光镧系染料引入聚合物微粒。
• Fluorescent polymer fine particle set, fluorescence detecting complex member set, fluorescent polymer fine particle composition and fluorescence detecting method
  申请人：FUJIFILM Corporation

  公开号：EP1903075A1

  公开（公告）日：2008-03-26

  The invention provides a fluorescent polymer fine particle set including at least a first fluorescent polymer fine particle including a polymer fine particle having a core-shell configuration formed by a hydrophobic core and a hydrophilic shell, and a first fluorescent lanthanoid dye incorporated in the polymer fine particle and containing a lanthanoid cation, and a second fluorescent polymer fine particle including the polymer fine particle, and a second fluorescent lanthanoid dye different from the first fluorescent lanthanoid dye, a fluorescence detecting complex member set, a fluorescent polymer fine particle composition, and a fluorescence detecting method utilizing the same.

  本发明提供了一种荧光聚合物微粒组，至少包括第一荧光聚合物微粒，包括具有由疏水核和亲水壳形成的核壳构型的聚合物微粒，以及掺入聚合物微粒并含有镧系阳离子的第一荧光镧系染料、第二荧光聚合物微粒，包括该聚合物微粒和不同于第一荧光镧系染料的第二荧光镧系染料、荧光检测复合物构件组、荧光聚合物微粒组合物，以及利用该组合物的荧光检测方法。
• Fluorescent polymer fine particle set, fluorescence detecting complex member set, use of fluorescent polymer fine particle set and fluorescence detecting method
  申请人：FUJIFILM Corporation

  公开号：EP1903075B1

  公开（公告）日：2010-01-27
• Fluorescent polymer fine particle, method for forming thereof, fluorescence detection kit, and method for detecting fluorescence
  申请人：Makino Naonori

  公开号：US20070105990A1

  公开（公告）日：2007-05-10

  The invention provides a fluorescent polymer fine particle having at least: a polymer particle having a core-shell configuration having a hydrophobic core and a hydrophilic shell; and a fluorescent lanthanoid dye that is integrated with the polymer particle and has a fluorescent lanthanoid cation, wherein a hydrophilic polymer which forms the hydrophilic shell has a polymerizable unit and at least one hydrophilic unit selected from the group consisting of a hydrophilic (meth)acrylamide unit and a hydrophilic vinyl amine unit. The invention further provides a method for forming the fluorescent polymer fine particle having at least dispersing and polymerizing a hydrophobic radical polymerizable monomer in an aqueous solvent in the presence of a radical generator and the presence of a components for forming a hydrophilic polymer which forms the hydrophilic shell; and introducing the fluorescent lanthanoid dye with the polymer particle.
• NON-TRULY-SPHERICAL HIGH-MOLECULAR FINE PARTICLES, PROCESS FOR PRODUCING THE SAME, INKJET INK COMPOSITION CONTAINING FINE PARTICLES, LITHOGRAPHIC PRINTING PLATE USING THE SAME, PROCESS FOR PRODUCING PRINTING PLATE, AND ELECTROPHORETIC PARTICLES-CONTAINING COMPOSITION CONTAINING FINE PARTICLES
  申请人：KAKINO Ryuki

  公开号：US20080038669A1

  公开（公告）日：2008-02-14

  Non-truly-spherical high-molecular fine particles are produced by a radical polymerization between a first radical-polymerizable monomer having a nucleophilic group and a second radical-polymerizable monomer having a group reacting with the nucleophilic group to form a covalent bond in a non-aqueous solvent in the presence of a dispersion-stabilizing resin.