bis(acetone 3-hexamethyleneiminylthiosemicarbazonato)zinc(II) | 405229-58-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 英文名称: bis(acetone 3-hexamethyleneiminylthiosemicarbazonato)zinc(II)
• CAS: 405229-58-5
• 化学式: C₂₀H₃₆N₆S₂Zn
• 分子量: 490.068
• InChiKey: OLGMTGLITQEWBV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc diacetate 、 acetone 3-hexamethyleneiminylthiosemicarbazone 以 乙醇 为溶剂， 生成 bis(acetone 3-hexamethyleneiminylthiosemicarbazonato)zinc(II)
  参考文献：
  名称：

  Structural study of a zinc(II) complex with acetone 3-hexamethyleneiminylthiosemicarbazone

  摘要：

  The crystal structure of a zinc complex with acetone 3-hexamethyleneiminylthiosemicarbazone has been determined and contains two anionic thiosemicarbazone ligands prepared from acetone. Bis(acetone 3-hexamethyleneiminylthtiosemicarbazone) zinc (II), [Zn(Acehexim)(2)], crystallizes monoclinic, P2(1)/c, a = 8.406(3), b = 13.518(5), c = 22.136(3) Angstrom, beta = 100.61(3), V = 2472.3(12) Angstrom(3), Z = 4. The distortion from tetrahedral symmetry, while substantial, is less than found for other 4-coordinate zinc complexes with bulkier thiosemicarbazone ligands. The largest angle, S-Zn-S, is 126.44(14)degrees and the smallest angle, 87.1(3)degrees, is the average of the chelating N-Zn-S angles. The angle between the mean planes of the two chelate rings is 79.41(21)degrees. Disorder within the hexamethyleneiminyl rings, which is common for this function, causes a larger than desired R-value. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(01)00657-3