六氢-1H-氮杂卓-1-硫代羧酸 | 53563-24-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 中文名称: 六氢-1H-氮杂卓-1-硫代羧酸
• 英文名称: 1H-Azepine-1-carbothioic acid, hexahydro-
• 英文别名: azepane-1-carbothioic S-acid
• CAS: 53563-24-9
• 化学式: C₇H₁₃NOS
• mdl: MFCD03701743
• 分子量: 159.25
• InChiKey: UGFSSCKCYPZCAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.857
• 拓扑面积：
  21.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  禾草敌 生成 六氢-1H-氮杂卓-1-硫代羧酸
  参考文献：
  名称：

  IMAI, YASUFUMI;KUWATSUKA, SHOZO, J. PESTIC. SCI., 1982, 7, N 4, 487-497

  摘要：

  DOI：

文献信息

• [EN] 15-PGDH INHIBITORS<br/>[FR] INHIBITEURS DE 15-PGDH
  申请人：KYORIN SEIYAKU KK

  公开号：WO2020160151A1

  公开（公告）日：2020-08-06

  A compound having one of formula (1), formula (2), formula (3) and formula (4) or a pharmacologically acceptable salt thereof.

  具有以下式之一的化合物（1），（2），（3）和（4）或其药理学上可接受的盐。
• Novel herbicides, usage thereof, novel thienopyrimidine derivatives, intermediates of the same, and process for production thereof
  申请人：Ota Chikako

  公开号：US20070010402A1

  公开（公告）日：2007-01-11

  A herbicide comprising, as an active ingredient, a substituted thienopyrimidine derivative represented by the formula (I): wherein all symbols are defined in the description, a method of using the same, a novel compound useful as the herbicide and a process for producing the same, and an intermediate thereof.

  一种除草剂，其活性成分为由式(I)表示的取代噻唑嘧啶衍生物，其中所有符号在说明中定义，使用该除草剂的方法，作为除草剂有用的新化合物及其生产方法，以及其中间体。
• Herbicidal compositions which contain a thiocarbamate and an organophosphorous compound and their application
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0010178A1

  公开（公告）日：1980-04-30

  Herbicidally active thiocarbamates are employed in combination with organophosphorothioates, the latter in sufficient qualtity to prevent soil degradation of the former. As a result, the herbicidal effectiveness of the thiocarbamate is significantly enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.

  具有除草活性的硫代氨基甲酸酯与有机硫代磷酸酯结合使用，后者的质量足以防止前者在土壤中降解。因此，硫代氨基甲酸酯类除草剂的除草效果明显增强并延长，使除草剂的单次施用在更长的时间内有效。
• Thiocarbamate preparation utilizing quaternary ammonium salt catalysts
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0004377A1

  公开（公告）日：1979-10-03

  Thiocarbamates are prepared by a process comprising reacting an aqueous solution of a thiocarbamate salt with an organic halide in the presence of a catalytic amount of a quaternary ammonium salt having the formula in which R4 and R5 are independently selected from the group consisting of C1-C25 alkyl and C2-C25 alkenyl, R6 and R7 are independently selected from the group consisting of C6-C25 alkyl and C6-C25 alkenyl, and Y- is an anion selected from the group consisting of chloride and bromide; and separating the thiocarbamate from the aqueous solution.

  硫代氨基甲酸酯的制备方法包括：在催化量的季铵盐存在下，使硫代氨基甲酸酯盐的水溶液与有机卤化物反应，该季铵盐的式为 R4 和 R5 独立地选自 C1-C25 烷基和 C2-C25 烯基，R6 和 R7 独立地选自 C6-C25 烷基和 C6-C25 烯基，Y- 是选自氯化物和溴化物的阴离子；然后将硫代氨基甲酸酯从水溶液中分离出来。
• Impregnated porous granules with slow-release pore membranes, and process for the manufacture thereof
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0005302A2

  公开（公告）日：1979-11-14

  Open-ended pores of a porous granule are filled with a liquid material which is at least partially immiscible with water, and sealed with a porous polyurea membrane which limits the release rate of the material into the surrounding medium. The membrane is formed by (a) applying to the bare granule an organic solution comprising the liquid material and an organic polyisocyanate, followed by (b) applying to the granule an aqueous solution comprising water and a catalytic amount of a catalyst selected from the group consisting of a basic organic tertiary amine and an alkyl tin carboxylate.

  在多孔颗粒的开口孔中填充至少部分与水不相溶的液态材料，并用多孔聚脲膜密封，以限制材料释放到周围介质中的速度。聚脲膜的形成过程如下 (a) 在裸颗粒上涂抹由液态材料和有机多异氰酸酯组成的有机溶液，然后 (b) 对颗粒施加水溶液，该水溶液由水和一定量的催化剂组成，催化剂选自碱性有机叔胺和烷基羧酸锡。