二甲基氧化锗 | 5061-27-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 二甲基氧化锗
• 英文名称: dimethylgermanone
• 英文别名: Me2GeO；Dimethyl-germanium-oxid；Dimethyl-germaniumoxid；Dimethylgermaniumoxid；dimethyl(oxo)germane
• CAS: 5061-27-8
• 化学式: C₂H₆GeO
• 分子量: 118.659
• InChiKey: NORMVWSAUPLVTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.67
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2914190090

反应信息

• 作为反应物：
  描述：

  二甲基氧化锗 以 solid matrix 为溶剂， 生成 Dimethylgermaniumoxidtrimer
  参考文献：
  名称：

  Generation, low-temperature stabilization, structure, and reactivity of intermediates with low-coordinated carbon, silicon, and germanium atoms

  摘要：

  The mechanisms of thermal and photochemical transformations of organic and organometallic compounds which pass through formation of different reactive intermediates were investigated by low-temperature matrix IR spectroscopy. Low-temperature matrix stabilization of the intermediates, the primary products of these reactions, was conducted at 10-15 K. The spectral and structural parameters of the free radicals (CCl3, CCl2Br, CClBr2, CH2CH=CH2, CF2CF=CF2, CH2-C=CH, CH2C=N, CH2Ph, CF2C6F5), halocarbenes and their silicon and germanium analogs, and unstable molecules with double-bond silicon and germanium atoms were obtained as a result.

  DOI：

  10.1007/bf00961022
• 作为产物：
  描述：

  3,3-dimethyl-3-germa-6-oxabicyclo[3.1.0]hexane 以 solid matrix 为溶剂， 生成 二甲基氧化锗
  参考文献：
  名称：

  Generation, low-temperature stabilization, structure, and reactivity of intermediates with low-coordinated carbon, silicon, and germanium atoms

  摘要：

  The mechanisms of thermal and photochemical transformations of organic and organometallic compounds which pass through formation of different reactive intermediates were investigated by low-temperature matrix IR spectroscopy. Low-temperature matrix stabilization of the intermediates, the primary products of these reactions, was conducted at 10-15 K. The spectral and structural parameters of the free radicals (CCl3, CCl2Br, CClBr2, CH2CH=CH2, CF2CF=CF2, CH2-C=CH, CH2C=N, CH2Ph, CF2C6F5), halocarbenes and their silicon and germanium analogs, and unstable molecules with double-bond silicon and germanium atoms were obtained as a result.

  DOI：

  10.1007/bf00961022

文献信息

• Insertion Reactions of Dimethylgermanone [(CH₃)₂Ge=O] into Si–O and Si–Cl Bonds
  作者：Kyung-Tae Kang、Georges Manuel、William P. Weber

  DOI：10.1246/cl.1986.1685

  日期：1986.10.5

  Flash vacuum co-pyrolysis (FVP) of 3,3-dimethyl-6-oxa-3-germabicyclo[3,1,0]hexane with various trapping reagents has been carried out. Adducts which result from insertion of dimethylgermanone into Si–O and Si–Cl bonds have been outlined.

  对3,3-二甲基-6-氧-3-锗双环[3,1,0]己烷进行的闪速真空共热解(FVP)与各种捕获试剂已被实施。已概述了通过二甲基锗酮插入Si–O和Si–Cl键所形成的加合物。
• Barrau, J.; Rima, G.; El Amine, M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1988, vol. 18, p. 317 - 324
  作者：Barrau, J.、Rima, G.、El Amine, M.、Satge, J

  DOI：——

  日期：——
• Reactions of 1-germa-3-cyclopentenes involving the germylene fragment: Transgermylenation and oxidation
  作者：S. P. Kolesnikov、I. S. Rogozhin、M. G. Safarov、O. M. Nefedov

  DOI：10.1007/bf00950320

  日期：1981.6
• LAVAYSSIERE, H.;SATGE, J.;BARRAU, J.;TRAORE, M., J. ORGANOMETAL. CHEM., 1982, 240, N 4, 335-348
  作者：LAVAYSSIERE, H.、SATGE, J.、BARRAU, J.、TRAORE, M.

  DOI：——

  日期：——
• BARRAU, J.;RIMA, G.;LAVAYSSIERE, H.;DOUSSE, G.;SATGE, J., J. ORGANOMET. CHEM., 1983, 246, N 3, 227-242
  作者：BARRAU, J.、RIMA, G.、LAVAYSSIERE, H.、DOUSSE, G.、SATGE, J.

  DOI：——

  日期：——