phenyl 2-hydroxy-3-methoxybenzoate | 59569-06-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: phenyl 2-hydroxy-3-methoxybenzoate
• 英文别名: 2-hydroxy-3-methoxy-benzoic acid phenyl ester；2-Hydroxy-3-methoxy-benzoesaeure-phenylester；Phenyl 2-hydroxy-3-methoxybenzoate
• CAS: 59569-06-1
• 化学式: C₁₄H₁₂O₄
• 分子量: 244.247
• InChiKey: YKEAZOGAZWPICS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-氨甲基吡啶 、 phenyl 2-hydroxy-3-methoxybenzoate 反应 1.5h， 以66%的产率得到2-hydroxy-3-methoxy-N-(3-pyridylmethyl)benzamide
  参考文献：
  名称：

  A new group of potential antituberculotics: N-(2-pyridylmethyl)salicylamides and N-(3-pyridylmethyl)salicylamides

  摘要：

  摘要：作为我们系统研究水杨酰胺类抗结核活性衍生物的一部分，合成了一系列19个N-(2-吡啶甲基)水杨酰胺和N-(3-吡啶甲基)水杨酰胺衍生物。这些化合物在体外显示出对结核分枝杆菌和分枝杆菌的活性。通过在三十八烷基硅烷浸渍的硅胶上进行薄层色谱测量它们的亲脂性R M，并计算了分配系数（辛醇-水）的对数值logP。两个亲脂性参数相关。计算了结构与抗结核活性之间的定量关系。随着亲脂性的增加，抗结核活性增强。N-(2-吡啶甲基)水杨酰胺衍生物比同分异构体N-(3-吡啶甲基)水杨酰胺衍生物更活跃。计算了化合物的几何结构，并通过测量水杨酸基团上羟基和羰基之间氢键的长度来验证计算结果。

  DOI：

  10.2478/s11696-010-0084-9
• 作为产物：
  描述：

  3-甲氧基水杨酸 、 苯酚 在 三氯氧磷 作用下， 反应 4.0h， 以64%的产率得到phenyl 2-hydroxy-3-methoxybenzoate
  参考文献：
  名称：

  A new group of potential antituberculotics: N-(2-pyridylmethyl)salicylamides and N-(3-pyridylmethyl)salicylamides

  摘要：

  摘要：作为我们系统研究水杨酰胺类抗结核活性衍生物的一部分，合成了一系列19个N-(2-吡啶甲基)水杨酰胺和N-(3-吡啶甲基)水杨酰胺衍生物。这些化合物在体外显示出对结核分枝杆菌和分枝杆菌的活性。通过在三十八烷基硅烷浸渍的硅胶上进行薄层色谱测量它们的亲脂性R M，并计算了分配系数（辛醇-水）的对数值logP。两个亲脂性参数相关。计算了结构与抗结核活性之间的定量关系。随着亲脂性的增加，抗结核活性增强。N-(2-吡啶甲基)水杨酰胺衍生物比同分异构体N-(3-吡啶甲基)水杨酰胺衍生物更活跃。计算了化合物的几何结构，并通过测量水杨酸基团上羟基和羰基之间氢键的长度来验证计算结果。

  DOI：

  10.2478/s11696-010-0084-9

文献信息

• FLAME-RETARDANT POLYMER MEMBER, FLAME-RETARDANT PRODUCT, AND FLAME-RETARDING METHOD
  申请人：Nitto Denko Corporation

  公开号：EP2570259A1

  公开（公告）日：2013-03-20

  Provided is a flame-retardant member having flexibility and a high degree of flame retardancy. A flame-retardant polymer member of the present invention is a flame-retardant polymer member having a polymer layer (B) and a flame-retardant layer (A) on at least one surface of the polymer layer (B), in which the flame-retardant layer (A) is a layer containing a layered inorganic compound (f) in a polymer (X) .

  本发明提供了一种具有柔韧性和高阻燃性的阻燃构件。本发明的阻燃聚合物构件是一种阻燃聚合物构件，具有聚合物层（B）和位于聚合物层（B）至少一个表面上的阻燃层（A），其中阻燃层（A）是在聚合物（X）中含有分层无机化合物（f）的层。
• WEATHER-RESISTANT HARD COAT COMPOSITION FOR GLASS-SUBSTITUTE SUBSTRATE, CURED PRODUCT AND LAYERED PRODUCT
  申请人：Daicel Corporation

  公开号：EP3885053A1

  公开（公告）日：2021-09-29

  The purpose of the present invention is to provide a weather-resistant hard coat composition for a glass-substitute substrate capable of efficiently forming a coating film excelling in weather resistance, scratch resistance, and toughness. The present invention provides: a weather-resistant hard coat composition for a glass-substitute substrate, the composition containing a polyorganosilsesquioxane having a constituent unit represented by Formula (1); a cured product thereof; and a laminate having a glass-substitute substrate and a coating film formed on at least one surface of the glass-substitute substrate. The coating film is a layer of a cured product of the weather-resistant hard coat composition for a glass-substitute substrate. [In formula (1), R1 represents a group containing an active energy ray-curable functional group.]

  本发明的目的是提供一种用于玻璃替代基材的耐候硬质涂层组合物，该组合物能够有效地形成具有优异耐候性、抗划伤性和韧性的涂膜。本发明提供：一种用于玻璃替代基材的耐候硬质涂层组合物，该组合物含有一种具有由式（1）表示的组成单元的聚有机硅烷；其固化产物；以及一种层压板，该层压板具有玻璃替代基材和在玻璃替代基材的至少一个表面上形成的涂膜。涂膜是用于玻璃替代基材的耐候硬质涂层组合物的固化产物层。式（1）中，R1 代表含有活性能量射线固化官能团的基团。
• WEATHER-RESISTANT HARD COAT COMPOSITION FOR METAL, CURED PRODUCT AND COATED METAL SUBSTRATE
  申请人：Daicel Corporation

  公开号：EP3885054A1

  公开（公告）日：2021-09-29

  The purpose of the present invention is to provide a weather-resistant hard coat composition for a metal, the composition being capable of efficiently forming a coating film excelling in weather resistance, scratch resistance, and flexibility. The present invention provides: a weather-resistant hard coat composition for a metal, the composition containing a polyorganosilsesquioxane having a constituent unit represented by Formula (1); a cured product thereof; and a coated metal substrate having a metal substrate and a coating film formed on at least one surface of the metal substrate. The coating film is a layer of a cured product of the weather-resistant hard coat composition for a metal. [In Formula (1), R1 represents a group containing an active energy ray-curable functional group.]         [R1SiO3/2]     (1)

  本发明的目的是提供一种用于金属的耐候硬质涂层组合物，该组合物能够有效地形成一层具有优异的耐候性、抗划伤性和柔韧性的涂膜。本发明提供：一种用于金属的耐候性硬涂层组合物，该组合物含有一种具有式（1）表示的组成单元的聚有机硅烷；其固化产物；以及一种涂覆金属基底，该金属基底具有金属基底和在金属基底的至少一个表面上形成的涂膜。涂膜是一层金属耐候硬涂层组合物的固化产物。式（1）中，R1 代表含有活性能量射线固化官能团的基团。 [R1SiO3/2] (1)
• METHOD FOR PEELING ADHEREND, AND ADHESIVE COMPOSITION
  申请人：Nitto Denko Corporation

  公开号：EP4011995A1

  公开（公告）日：2022-06-15

  A method for releasing an adherend of the present invention includes a first step and a second step. In the first step, a bonded product (100) including a pressure-sensitive adhesive layer (10), and an adherend (20) bonded thereto is prepared. The pressure-sensitive adhesive layer (10) includes a pressure-sensitive adhesive component and a gas generating agent. In the second step, a laser light (L) is irradiated to the pressure-sensitive adhesive layer (10)-side of the bonded product (100) to heat a part of the pressure-sensitive adhesive layer (10). A pressure-sensitive adhesive composition of the present invention is a composition used for forming the pressure-sensitive adhesive layer (10) in the method.

  本发明的粘合剂释放方法包括第一步和第二步。第一步，制备粘合产品（100），包括压敏胶层（10）和与其粘合的粘合剂（20）。压敏胶层（10）包括压敏胶成分和气体发生剂。在第二步中，激光（L）照射到粘合产品（100）的压敏胶层（10）侧，以加热压敏胶层（10）的一部分。本发明的压敏胶组合物是用于在该方法中形成压敏胶层（10）的组合物。
• Double-sided pressure-sensitive-adhesive-layer-attached polarizing film, and image display device
  申请人：NITTO DENKO CORPORATION

  公开号：US10310333B2

  公开（公告）日：2019-06-04

  A double-sided pressure-sensitive adhesive-layer-attached polarizing film has a polarizing film nearest to a viewer-side of an image display device among at least one polarizing film, a pressure-sensitive adhesive layer A located on the viewer-side, and a pressure-sensitive adhesive layer B on a side of the polarizing film that is opposite to the pressure-sensitive adhesive layer A. The pressure-sensitive adhesive layers A and B are equipped with separators SA and SB, respectively. The polarizing film is a single-side protected polarizing film having a polarizer of 15 μm or less thickness and having a transparent protective film on only a single side of the polarizer. The pressure-sensitive adhesive layer B is located on the polarizer side of the single-side protected polarizing film. The pressure-sensitive adhesive layer A has a thickness of 25 μm or more; and the pressure-sensitive adhesive layer B has a thickness of 25 μm or less.

  一种双面压敏胶层附着式偏光片，在至少一种偏光片中，有一种偏光片最靠近图像显示设备的观看侧，在观看侧有压敏胶层A，在偏光片与压敏胶层A相对的一侧有压敏胶层B，压敏胶层A和B上分别装有隔板SA和SB。偏光膜是一种单面保护偏光膜，其偏光片厚度为 15 μm 或更小，且仅在偏光片的单面上有一层透明保护膜。压敏胶层 B 位于单面保护偏光膜的偏光片一侧。压敏胶层 A 的厚度为 25 μm 或以上；压敏胶层 B 的厚度为 25 μm 或以下。