3,5,7-Trithia-4-phospha-1,2,6-triarsatricyclo[2.2.1.02,6]heptane | 80585-65-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: 3,5,7-Trithia-4-phospha-1,2,6-triarsatricyclo[2.2.1.02,6]heptane
• CAS: 80585-65-5
• 化学式: As₃PS₃
• 分子量: 351.937
• InChiKey: AIACMOWXZVMMOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.66
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,5,7-Trithia-4-phospha-1,2,6-triarsatricyclo[2.2.1.02,6]heptane 生成 三硫化四砷
  参考文献：
  名称：

  Blachnik, R.; Hoppe, A.; Rabe, U., Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981, vol. 36, # 12, p. 1493 - 1499

  摘要：

  DOI：
• 作为产物：
  描述：

  三硫化四磷 、 三硫化四砷 以 melt 为溶剂， 生成 3,5,7-Trithia-4-phospha-1,2,6-triarsatricyclo[2.2.1.02,6]heptane
  参考文献：
  名称：

  Blachnik, R.; Hoppe, A.; Rabe, U., Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981, vol. 36, # 12, p. 1493 - 1499

  摘要：

  DOI：

文献信息

• PAs₃S₃ Cage as a New Building Block in Copper Halide Coordination Polymers
  作者：Patrick Schwarz、Joachim Wachter、Manfred Zabel

  DOI：10.1021/ic201060b

  日期：2011.9.5

  atoms interact with copper, while As···X interactions determine the dimensionality of the frameworks. The structures of 2 and 3 contain tetrahedral [(PAs3S3)4Cu]+ cations as secondary building units (SBUs), which are arranged by interactions with Cl– or Br– anions into two- and three-dimensional substructures. These interpenetrate into a (2D + 3D) polycatenane. Compound 4 is built up by a one-dimensional

  PAS的配位化学的第一实施例3 š 3从PA的溶液获得笼3 š 3 ·W（CO）5（1）的CH 2氯2或CH 2氯2 /甲苯和的CuX（X =氯， Br，I）通过互扩散技术在MeCN中进行。[[Cu（PAs 3 S 3）4 ] X（2，X = Cl; 3，X = Br）和[（Cu 2 I）（PAs 3 S 3）3 ] I（4的晶体）获得并通过拉曼光谱法（2）和单晶X射线晶体学表征。固态结构揭示了PAs 3 S 3配体的出乎意料的配位多功能性：顶部的磷原子和桥连的硫原子与铜相互作用，而As··X相互作用决定了骨架的尺寸。的结构2和3含有四面体[（PAS 3 š 3）4的Cu] +阳离子作为次级结构单元（的SBU），其由有Cl相互作用布置-或Br -阴离子分为二维和三维子结构。这些相互渗透成（2D + 3D）聚环丁烷。化合物4由一维[（Cu 2 I）（PAs 3 S 3）3 ] n n +碳带和PAs
• Suppression of Realgar Cage Degradation during Complexation: Formation of Hybrid Coordination Polymers with As₄S₄, PAs₃S₃, and Cu(I) Halide Building Blocks
  作者：Patrick Schwarz、Joachim Wachter、Manfred Zabel

  DOI：10.1021/ic2018049

  日期：2011.12.19

  Realgar, As4S4, reacts with Cr(CO)(5)THF under cage degradation to give As4S3 center dot Cr(CO)(5) (1). The reverse structural change is found if solutions of 1 in CH2Cl2 react with equimolar amounts of PAs3S3 center dot W(CO)(5) and CuX (X = Cl, Br, I) in CH3CN under biphasic diffusion conditions. The resulting coordination polymers 2-4 contain a reconstituted realgar molecule along with the PAs3S3 cage. The crystal structures of (CuX)(As4S4)(PAs3S3) (X = Cl: 2; Br: 3) are characterized by one-dimensional (1D) (CuX)(As4S4) strands, which are formed by alternating As4S4 cages and CuX dumbbells. Terminal PAs3S3 molecules are coordinated to copper by apical phosphorus and bridging realgar through sulfur. The As-3 triangles of the resulting (CuX)(As4S4)(PAs3S3) strands interact with halides of neighbored strands to give a folded three-dimensional (3D) network. The structure of (CuI)(3)(As4S4)(PAs3S3) (4) contains 1D (Cu3I3) strands as backbones, which are bridged by sulfur atoms of two eta(1:2)-As4S4 molecules while PAs3S3 confines the resulting sheet. The As-3 triangles at the surface of the layers interact with iodide of the next layer to form a layered 3D network.
• Bues, W.; Somer, M.; Brockner, W., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Bues, W.、Somer, M.、Brockner, W.

  DOI：——

  日期：——