methylvinylbis(1,1,3-trihydroperfluoro-2,4-dimethylpentyloxy)silane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: methylvinylbis(1,1,3-trihydroperfluoro-2,4-dimethylpentyloxy)silane
• 英文别名: Ethenyl-bis[2,3,4,5,5,5-hexafluoro-2,4-bis(trifluoromethyl)pentoxy]-methylsilane；ethenyl-bis[2,3,4,5,5,5-hexafluoro-2,4-bis(trifluoromethyl)pentoxy]-methylsilane
• 化学式: C₁₇H₁₂F₂₄O₂Si
• 分子量: 732.328
• InChiKey: YJASQPGFAXLIEM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  44
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为产物：
  描述：

  甲基乙烯基二氯硅烷 、 2,3,4,5,5,5-六氟-2,4-二(三氟甲基)-1-戊醇 以 甲苯 为溶剂， 反应 4.0h， 以32%的产率得到methylvinylbis(1,1,3-trihydroperfluoro-2,4-dimethylpentyloxy)silane
  参考文献：
  名称：

  Synthesis of methylvinylpolyfluoroalkoxysilanes by photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene

  摘要：

  A new method was elaborated for the synthesis of vinylsilanes with polyfluoroalkoxy substituents at the silicon atom using the photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene in the presence of di-tert-butyl peroxide at room temperature.

  DOI：

  10.1007/bf01430653

文献信息

• Synthesis of methylvinylpolyfluoroalkoxysilanes by photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene
  作者：N. A. Chernyavskaya、M. A. Kurykin

  DOI：10.1007/bf01430653

  日期：1996.12

  A new method was elaborated for the synthesis of vinylsilanes with polyfluoroalkoxy substituents at the silicon atom using the photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene in the presence of di-tert-butyl peroxide at room temperature.