2-phenyl-4,6-bis-trichloromethyl-[1,3,5]triazine | 24504-22-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-phenyl-4,6-bis-trichloromethyl-[1,3,5]triazine
• 英文别名: phenyl-bis-trichloromethyl-[1,3,5]triazine；Phenyl-bis-trichlormethyl-[1,3,5]triazin；2-phenyl-4, 6-bis(trichloromethyl)-s-triazine；2-Phenyl-4,6-bis(trichloromethyl)-1,3,5-triazine
• CAS: 24504-22-1
• 化学式: C₁₁H₅Cl₆N₃
• mdl: MFCD00521485
• 分子量: 391.899
• InChiKey: HAZQZUFYRLFOLC-UHFFFAOYSA-N

物化性质

• 熔点：
  175-176 °C(Solv: acetone (67-64-1); water (7732-18-5)(1:1))
• 沸点：
  430.5±55.0 °C(Predicted)
• 密度：
  1.653±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-phenyl-4,6-bis-trichloromethyl-[1,3,5]triazine 在 甲醇 、 氢氧化钾 、 copper diacetate 、 锌 作用下， 生成 phenyl-di-trans-styryl-[1,3,5]triazine
  参考文献：
  名称：

  Grundmann et al., Chemische Berichte, 1953, vol. 86, p. 181,184

  摘要：

  DOI：
• 作为产物：
  描述：

  bis-(2,2,2-trichloro-acetimidoyl)-amine 、 苄脒盐酸盐 生成 2-phenyl-4,6-bis-trichloromethyl-[1,3,5]triazine
  参考文献：
  名称：

  Synthesis of the sym-Triazine System. II.¹ Preparation of Monosubstituted sym-Triazines by Reaction of sym-Triazine with Amidines

  摘要：

  DOI：

  10.1021/ja01515a047
• 作为试剂：
  描述：

  3,5-二叔丁基-4-羟基苄醇 在 2-phenyl-4,6-bis-trichloromethyl-[1,3,5]triazine 、 三乙胺 作用下， 以 1,4-二氧六环 为溶剂， 反应 4.0h， 以0.55 g的产率得到2,6-二叔丁基苯酚
  参考文献：
  名称：

  Synthesis and properties of sym-triazine derivatives. 8. Synthesis of amino and alkoxy derivatives of sym-triazine containing fragments of a sterically-hindered phenol from 2,4-bis(trichloromethyl)-sym-triazines

  摘要：

  DOI：

  10.1007/bf00755699

文献信息

• SILANE COUPLING COMPOUNDS AND MEDICAL AND/OR DENTAL CURABLE COMPOSITIONS COMPRISING THE SAME
  申请人：KABUSHIKI KAISHA SHOFU

  公开号：US20190300552A1

  公开（公告）日：2019-10-03

  The present invention relate to a novel silane coupling agent and a medical and/or dental curable composition comprising the same. It is an object of the present invention to provide a novel silane coupling agent that imparts high affinity to a radical polymerizable monomer, thereby imparting high mechanical strength, flexibility and durability when used for a medical and/or dental curable composition, and an inorganic filler surface-treated with the novel silane coupling agent and a novel medical and/or dental curable composition. A silane coupling agent including repeating units such as a urethane bond and polyethylene glycol (ether bond) at a specific position is used.

  本发明涉及一种新型硅烷偶联剂以及包括该偶联剂的医用和/或牙科可固化组合物。本发明的目的是提供一种新型硅烷偶联剂，使其对自由基聚合单体具有高亲和力，从而在用于医用和/或牙科可固化组合物时赋予高机械强度、柔韧性和耐久性，并且包括经新型硅烷偶联剂表面处理的无机填料和新型医用和/或牙科可固化组合物。该硅烷偶联剂包括在特定位置具有尿素键和聚乙二醇（醚键）等重复单元。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• Novolac resin-containing resist underlayer film-forming composition using bisphenol aldehyde
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US10017664B2

  公开（公告）日：2018-07-10

  Resist underlayer film-forming composition for forming resist underlayer film with high dry etching resistance, wiggling resistance and exerts good flattening property and embedding property for uneven parts, including resin obtained by reacting organic compound A including aromatic ring and aldehyde B having at least two aromatic hydrocarbon ring groups having phenolic hydroxy group and having structure wherein the aromatic hydrocarbon ring groups are bonded through tertiary carbon atom. The aldehyde B may be compound of Formula (1): The obtained resin may have a unit structure of Formula (2): Ar1 and Ar2 each are C6-40 aryl group. The organic compound A including aromatic ring may be aromatic amine or phenolic hydroxy group-containing compound. The composition may contain further solvent, acid and/or acid generator, or crosslinking agent. Forming resist pattern used for semiconductor production, including forming resist underlayer film by applying the resist underlayer film-forming composition onto semiconductor substrate and baking it.

  用于形成具有高干法蚀刻抗性、抗扭曲性并具有良好的平整性和嵌入性能的抗蚀底层膜形成组合物，包括通过使含有芳香环的有机化合物A和至少具有两个含酚羟基的芳香烃环团的醛B反应而获得的树脂，并具有芳香烃环团通过三级碳原子键合的结构。醛B可以是化合物的化学式（1）： 所得的树脂可能具有化学式（2）的单元结构： Ar1和Ar2各自是C6-40芳基团。含有芳香环的有机化合物A可能是芳香胺或含酚羟基的化合物。该组合物可能进一步含有溶剂、酸和/或酸发生剂，或交联剂。用于半导体生产的形成抗蚀图案，包括通过将抗蚀底层膜形成组合物涂覆在半导体衬底上并对其进行烘烤来形成抗蚀底层膜。
• [EN] COLORANT MULTIMER, COLORED CURABLE COMPOSITION, COLOR FILTER AND METHOD FOR PRODUCING THE SAME, AND SOLID-STATE IMAGE SENSOR, IMAGE DISPLAY DEVICE, LIQUID CRYSTAL DISPLAY DEVICE AND ORGANIC EL DISPLAY WITH THE COLOR FILTER<br/>[FR] MULTIMÈRE COLORANT, COMPOSITION DURCISSABLE COLORÉE, FILTRE COLORÉ ET PROCÉDÉ DE FABRICATION DE CEUX-CI, ET DÉTECTEUR D'IMAGES À L'ÉTAT SOLIDE, DISPOSITIF D'AFFICHAGE D'IMAGES, DISPOSITIF D'AFFICHAGE À CRISTAUX LIQUIDES ET DISPOSITIF D'AFFICHAGE ÉLEC
  申请人：FUJIFILM CORP

  公开号：WO2011040628A1

  公开（公告）日：2011-04-07

  A colorant multimer includes, as a partial structure of a colorant moiety, a dipyrromethene metal complex compound or tautomer thereof obtained from: (i) a dipyrromethene compound represented by the following Formula (M); and (ii) a metal or a metal compound: wherein in Formula (M), R4, R5, R6, R7, R8, R9, and R10 each independently represent a hydrogen atom or a monovalent substituent.

  一种着色剂多聚体包括作为着色剂部分结构的二吡咯甲烷金属配合物化合物或其互变异构体，所述化合物由以下公式（M）表示的二吡咯甲烷化合物和金属或金属化合物得到：其中在公式（M）中，R4、R5、R6、R7、R8、R9和R10分别独立地表示氢原子或一价取代基。
• Novel Compound, Photosensitive Resin Composition Comprising the Same, and Color Filter
  申请人：Samsung SDI Co., Ltd.

  公开号：US20170107224A1

  公开（公告）日：2017-04-20

  A compound represented by Chemical Formula 1 wherein each substituent is the same as defined in the specification, a photosensitive resin composition including the same, and a color filter manufactured using the photosensitive resin composition are provided.

  提供了一种由化学式1表示的化合物，其中每个取代基与规范中定义的相同，包括该化合物的感光树脂组合物，以及使用该感光树脂组合物制造的彩色滤光片。