1,7-bis(2',6',7'-trioxa-1'-phosphabicyclo[2.2.2]-octyl-4')-4,4-bishydrohymethyl-2,6-dioxaheptane | 68294-31-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: 1,7-bis(2',6',7'-trioxa-1'-phosphabicyclo[2.2.2]-octyl-4')-4,4-bishydrohymethyl-2,6-dioxaheptane
• 英文别名: 1,7-bis(2',6',7'-trioxa-1'-phosphabicyclo[2.2.2]octyl-4')-4,4-bishydroxymethyl-2,6-dioxaheptane
• CAS: 68294-31-5
• 化学式: C₁₅H₂₆O₁₀P₂
• 分子量: 428.313
• InChiKey: TUCYZHUTKVSLEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.57
• 重原子数：
  27.0
• 可旋转键数：
  10.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  114.3
• 氢给体数：
  2.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  1,7-bis(2',6',7'-trioxa-1'-phosphabicyclo[2.2.2]-octyl-4')-4,4-bishydrohymethyl-2,6-dioxaheptane 在 吡啶 、 sulfur 作用下， 反应 3.0h， 以82.6%的产率得到1,7-bis(2',6',7'-trioxa-1'-thio-1'-phosphabicyclo[2.2.2]octyl-4')-4,4-bishydroxymethyl-2,6-dioxaheptane
  参考文献：
  名称：

  Tripentaerythritol in the synthesis of new types of framework bicyclophosphites

  摘要：

  Regioselective reaction of tripentaerythritol with phosphorous hexaethyltriamide resulted in the preparation of singular framework bisbicyclophosphite. A study of chemical characteristics of the obtained product is started.

  DOI：

  10.1134/s1070363209120081
• 作为产物：
  描述：

  三季戊四醇 、 六乙基亚磷酸胺 在 吡啶 作用下， 反应 24.0h， 以47%的产率得到1,7-bis(2',6',7'-trioxa-1'-phosphabicyclo[2.2.2]-octyl-4')-4,4-bishydrohymethyl-2,6-dioxaheptane
  参考文献：
  名称：

  Tripentaerythritol in the synthesis of new types of framework bicyclophosphites

  摘要：

  Regioselective reaction of tripentaerythritol with phosphorous hexaethyltriamide resulted in the preparation of singular framework bisbicyclophosphite. A study of chemical characteristics of the obtained product is started.

  DOI：

  10.1134/s1070363209120081

文献信息

• Hydrolysis of bisbicyclophosphite and related thionophosphate, derivatives of tripentaerythritol. Arbuzov alkylation of the bisbicyclophosphite
  作者：M. A. Malenkovskaya、O. V. Vyunskovskaya、L. K. Vasyanina、D. A. Predvoditelev、E. E. Nifant’ev

  DOI：10.1134/s1070363211070097

  日期：2011.7

  The first data on the study of hydrolysis of bisbicyclophosphite and related thionophosphates of tripentaerythritol series in acidic and basic media are presented. Arbuzov alkylation of bisbicyclophosphite with methyl iodide was studied.

  提出了关于在酸性和碱性介质中水解双季戊四醇系列的双二环亚磷酸酯和相关的硫代磷酸酯的研究的第一份数据。研究了双二环亚磷酸酯与甲基碘的Arbuzov烷基化反应。