methoxydimethyl gallium | 54747-88-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: methoxydimethyl gallium
• 英文别名: Dimethylgallium-methoxid；Dimethylgallium methoxide；methoxy(dimethyl)gallane
• CAS: 54747-88-5
• 化学式: C₃H₉GaO
• 分子量: 130.827
• InChiKey: SLQBFRPCXWCGOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.88
• 重原子数：
  5
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  methoxydimethyl gallium 在 甲醇 作用下， 以 甲醇 为溶剂， 以>99的产率得到methyl(dimethoxy)gallium
  参考文献：
  名称：

  Aleksandrov, Yu. A.; Chikinova, N. V.; Makin, G. I., Journal of general chemistry of the USSR, 1984, vol. 54, p. 858 - 858

  摘要：

  DOI：
• 作为产物：
  描述：

  三甲基镓 在 水 作用下， 生成 methoxydimethyl gallium
  参考文献：
  名称：

  Polymeric Dimethylgallium Hydroxide¹ and its Condensation

  摘要：

  DOI：

  10.1021/ja01648a020

文献信息

• 514. Trimethylgallium. Part II. Reactions with hydroxy- and similar compounds
  作者：G. E. Coates、R. G. Hayter

  DOI：10.1039/jr9530002519

  日期：——
• Synthesis and Structure of Zirconium-Group 13 Heterobimetallic Compounds
  作者：Francis M. G. de Rege、William M. Davis、Stephen L. Buchwald

  DOI：10.1021/om00010a048

  日期：1995.10

  The reaction of main-group (B, Al, and Ga) alkoxides with, zirconocene complexes of benzynes was used to prepare novel zirconium-group 13 heterobimetallic compounds [R(2)E-(mu-OR')(mu-1,2-aryl)Zr(eta(5)-C5H5)(2)][E = B, R = Et, R' = Me, aryl = phenyl (1); E = B, R = Me, R'= Et, aryl = phenyl (2); E = B, R = Et, R' = Me, aryl = 3-methoxyphenyl (3); E = Al, R = Et, R'= Et, aryl = phenyl (5); E = Ga, R = Me, R'= Me, aryl = 3-methoxyphenyl (6)] and [(EtO)(2)B(mu-1,2-naphthyl)Zr(eta(5)-C5H5)(2)(OEt)] (4). Complexes 3 and 4 have been characterized by X-ray crystallography. Compound 3 contains a dative bond from an oxygen lone pair of the methoxy ligand on the zirconium to an acceptor p-orbital on the boron atom (B-11 NMR; delta 8.26 ppm). In contrast, the weakly Lewis acidic boron center in 4 (B-11 NMR; delta 29.7 ppm) does not show a bonding interaction between the alkoxy ligand on the zirconocene fragment and the boron center.
• Chikinova, N. V.; Alferov, V. A.; Alyasov, V. N., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1599 - 1601
  作者：Chikinova, N. V.、Alferov, V. A.、Alyasov, V. N.、Aleksandrov, Yu. A.、Vyshinskii, N. N.、Tsvetkov, V. G.

  DOI：——

  日期：——
• Aleksandrov, Yu. A.; Chikinova, N. V.; Makin, G. I., Journal of general chemistry of the USSR, 1989, vol. 59, p. 2276 - 2280
  作者：Aleksandrov, Yu. A.、Chikinova, N. V.、Makin, G. I.

  DOI：——

  日期：——
• ALEKSANDROV, YU. A.;CHIKINOVA, N. V.;MAKIN, G. I.;BREGADZE, V. I.;GOLUBIN+, METALLOORGAN. XIMIYA, 2,(1989) N, S. 524-529
  作者：ALEKSANDROV, YU. A.、CHIKINOVA, N. V.、MAKIN, G. I.、BREGADZE, V. I.、GOLUBIN+

  DOI：——

  日期：——