zirconyl chloride hexahydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: zirconyl chloride hexahydrate
• 英文别名: ZrOCl2*6H2O；zirconium oxychloride hexahydrate；Oxygen(2-);zirconium(4+);dichloride;hydrate
• 化学式: Cl₂OZr*6H₂O
• 分子量: 286.221
• InChiKey: LRQNMBKJEQWSJT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -6.94
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  zirconyl chloride hexahydrate 、 正戊酸 在 氨 作用下， 以 甲醇 、 水 为溶剂， 反应 1.0h， 以63%的产率得到
  参考文献：
  名称：

  Synthesis, FTIR, and Raman Spectroscopic and Thermogravimetric Analysis of UO2(II), ZrO(II), VO(II), and Th(IV) Valerate Complexes

  摘要：

  DOI：

  10.1134/s1070363220120282

文献信息

• A Stable Zr(IV)-Based Metal–Organic Framework Constructed from C═C Bridged Di-isophthalate Ligand for Sensitive Detection of Cr₂O₇^2– in Water
  作者：Ming-Ming Xu、Xiang-Jing Kong、Tao He、Xue-Qian Wu、Lin-Hua Xie、Jian-Rong Li

  DOI：10.1021/acs.inorgchem.8b02282

  日期：2018.11.19

  new sensors have been developing for its effective detection from water, among which metal–organic frameworks (MOFs) show distinct superiority over many other materials. Herein, a new fluorescent Zr(IV)-based MOF, [Zr6O4(OH)8(H2O)4(sbtc)2] (referred to as BUT-28), based on the di-isophthalate ligand with a central CH═CH moiety, trans-stilbene-3,3′,5,5′-tetracarboxylate (sbtc4–), has been prepared and

  由于Cr 2 O 7 2–阴离子具有剧毒，因此已经开发出新的传感器以从水中进行有效检测，其中金属有机框架（MOF）表现出优于许多其他材料的独特优势。在此，基于二间邻苯二甲酸酯配体，基于Zr（IV）的新型荧光MOF [Zr 6 O 4（OH）8（H 2 O）4（sbtc）2 ]（称为BUT-28） CH═CH的中心部分，反式-stilbene-3,3'，5,5'-四羧酸盐（sbtc 4–），已经准备好并在结构上确定了。MOF在中性，高酸性和弱碱性水溶液中显示出极好的稳定性。此外，对于BUT-28，在三个水蒸气吸附-解吸测量周期中均未观察到必要的吸收损失，这表明多孔骨架的坚固性及其长期使用的巨大潜力。对BUT-28和同构MOF Zr-abtc进行了荧光测量，该结构由具有中心N═N部分的二间苯二甲酸配体，偶氮苯3,3'，5,5'-四羧酸（abtc 4–）。有趣的是，Zr-abtc显示出非常弱的荧
• Development of new, highly efficient and stable visible light active photocatalyst Ag2ZrO3 for methylene blue degradation
  作者：Sanjay R. Thakare、G.S. Gaikwad、N.T. Khati、A.V. Wankhade

  DOI：10.1016/j.catcom.2014.12.027

  日期：2015.3

  A novel visible light driven photocatalyst of Ag2ZrO3 was prepared by solid-state reaction technique for the first time and the photocatalytic properties were investigated. Reactive powder of the photocatalyst was obtained by heating a 1:2 molar mixture of zirconyl oxychloride and silver nitrate at 900 °C up to 24 h and characterized by XRD, SEM, TEM, EDAX, and UV–visible diffuse reflectance spectroscopy

  首次通过固相反应技术制备了新型的可见光驱动的Ag 2 ZrO 3光催化剂，并对其光催化性能进行了研究。光催化剂的反应性粉末是通过在900°C下加热24小时的1：2氧氯化锆和硝酸银的摩尔比混合物而获得的，并通过XRD，SEM，TEM，EDAX和紫外可见漫反射光谱进行表征。在可见光照射下，研究了以Ag 2 ZrO 3为催化剂对亚甲基蓝染料水溶液的光催化降解。该光催化剂优于已知的光催化剂，并且具有高稳定性和可重复使用性。
• Proton conductor NASICON-structure Li_1+<i>x</i>Cd_<i>x</i>/2Zr_{2−<i>x</i>/2}(PO₄)₃ as solid electrolyte for intermediate-temperature fuel cells
  作者：Xiuxiu Li、Enyi Hu、Faze Wang、Peter Lund、Bin Zhu、Jun Wang

  DOI：10.1039/d3ta05182j

  日期：——

  Li1+xCdx/2Zr2−x/2(PO4)3 (x = 0.5, 1, 1.5, 2) derived from CdZr4(PO4)6 to construct a fuel cell device. Among all samples, the Li3Cd1Zr1(PO4)3 cell device exhibits a high performance including peak power density 815 mW cm−2, proton conductivity 0.165 S cm−1 and activation energy 0.372 eV at 550 °C. Theoretical and experimental studies both suggest that the high proton conductivity benefits from the

  固体电解质在中温下的低离子电导率阻碍了固体燃料电池技术的商业化进程。具有刚性三维网络和互连间隙空间的钠超离子导体（NASICON）结构有望成为燃料电池的理想固体电解质。基于H + /Li +交换工程策略，我们报告了NASICON结构的质子导体Li 1+ x Cd x /2 Zr 2− x /2 (PO 4 ) 3 ( x = 0.5, 1, 1.5, 2 ）从CdZr 4 (PO 4 ) 6衍生来构建燃料电池装置。在所有样品中，Li 3 Cd 1 Zr 1 (PO 4 ) 3电池装置表现出高性能，包括在550℃下峰值功率密度815 mW cm -2、质子电导率0.165 S cm -1和活化能0.372 eV。理论和实验研究均表明，高质子电导率得益于NASICON 材料中独特的 3D 间隙空间和快速的 H + /Li +交换。在燃料电池工作条件下，Li 1+ x Cd x /2 Zr 2−
• Catalytic combustion of particulate matter
  作者：N.F. Galdeano、A.L. Carrascull、M.I. Ponzi、I.D. Lick、E.N. Ponzi

  DOI：10.1016/j.tca.2004.04.006

  日期：2004.11

  In order to explore a method to remove particulate matter, catalysts of different alkaline nitrates (Li, K and Cs) supported on hydrous zirconium were prepared by the method of incipient humidity and tested as catalysts for particulate matter combustion. The catalytic activity was determined by using the temperature programmed oxidation technique (TPO), utilizing two equipments, a thermogravimetric reactor and other of fixed bed. In the first case the particulate matter/catalyst mixture was milled carefully in a mortar (tight contact) while in the second case more realistic operative conditions were used, particulate matter/catalyst mixture was made with a spatula (loose contact). All prepared catalysts showed good activity for the particulate matter combustion. The cesium catalyst was the one that presented higher activity, decreasing the combustion temperature between 200 and 250degreesC with respect to the combustion without catalyst. The catalyst with lithium nitrate became active at higher temperature than its melting point and the same occurred with the potassium catalyst. This did not occur for the catalyst containing cesium nitrate that melts at 407 degreesC and became active from 350degreesC. (C) 2004 Elsevier B.V. All rights reserved.
• Synthesis, FTIR, and Raman Spectroscopic and Thermogravimetric Analysis of UO2(II), ZrO(II), VO(II), and Th(IV) Valerate Complexes
  作者：M. S. Refat、S. B. Bakare、T. Altalhi

  DOI：10.1134/s1070363220120282

  日期：2020.12