1-(2-呋喃基)-2,8,9-三氧杂-5-氮杂-1-硅杂双环[3.3.3]十一烷 | 68011-86-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 1-(2-呋喃基)-2,8,9-三氧杂-5-氮杂-1-硅杂双环[3.3.3]十一烷
• 英文名称: 1-furan-2-yl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane
• 英文别名: (TB-5-23)-(2,2',2''-azanetriyl-tris-ethanolato(3-)-N,O,O',O'')-furan-2-yl-silicon；2,8,9-Trioxa-5-aza-1-silabicyclo(3.3.3)undecane, 1-(2-furanyl)-；1-(furan-2-yl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
• CAS: 68011-86-9
• 化学式: C₁₀H₁₅NO₄Si
• 分子量: 241.319
• InChiKey: QXZVYVKBVRCKKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  44.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-furyltriethoxysilane 、 三乙醇胺 在 dihydrogen hexachloroplatinate 作用下， 以 xylene 为溶剂， 以88%的产率得到1-(2-呋喃基)-2,8,9-三氧杂-5-氮杂-1-硅杂双环[3.3.3]十一烷
  参考文献：
  名称：

  Lukevits, E'.; Pudova, O. A.; Popelis, Yu., Journal of general chemistry of the USSR, 1981, vol. 51, # 2, p. 300 - 304

  摘要：

  DOI：

文献信息

• A novel route to pentacoordinated organylsilanes and -germanes
  作者：Vladimir Gevorgyan、Larisa Borisova、Armand Vyater、Victoria Ryabova、Edmunds Lukevics

  DOI：10.1016/s0022-328x(97)00454-3

  日期：1997.12

  New convenient methods of sila- and germatranes synthesis from ethoxy-and tetraorganylsilanes and -germanes have been elaborated. The reaction of ethoxysilanes with boratrane in the presence of catalytic amounts of metal alcoholates has been investigated. Dimethylformamide (DMF) as a solvent and NaOEt as a catalyst used instead of xylene and Al(O-i-Pr)(3) were found to give better yields. The possibility of using alkoxy-, aminosilanes, tetraethoxygermane and even tetraorganylsilanes in this reaction leading to the corresponding atranes with good yields has been demonstrated. Triethanolamine in the presence of catalytic amounts of base or CsF easily substitutes furyl-, dihydrofuryl-, dihydropyranyl- and thienyl groups in tris-and tetraheterylsilanes, leading to organylsilatranes with good to excellent yields. (C) 1997 Elsevier Science S.A.
• Organylsilatranes from the reaction of tetraorganylsilanes with triethanolamine
  作者：Vladimir Gevorgyan、Larisa Borisova、Edmunds Lukevics

  DOI：10.1016/s0022-328x(96)06652-1

  日期：1997.1

  Triethanolamine selectively cleaves Si-C bonds in heterylsilanes (3) under basic/nucleophilic catalysis, leading to organylsilatranes (4) with good to excellent yields.