4-amino-2,6-didodecylamino-1,3,5-triazine | 53790-49-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 4-amino-2,6-didodecylamino-1,3,5-triazine
• 英文别名: N~2~,N~4~-Didodecyl-1,3,5-triazine-2,4,6-triamine；2-N,4-N-didodecyl-1,3,5-triazine-2,4,6-triamine
• CAS: 53790-49-1
• 化学式: C₂₇H₅₄N₆
• 分子量: 462.766
• InChiKey: TZWOBTBQHFEZCD-UHFFFAOYSA-N

物化性质

• 沸点：
  605.6±38.0 °C(Predicted)
• 密度：
  0.977±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  33
• 可旋转键数：
  24
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  88.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  、 4-amino-2,6-didodecylamino-1,3,5-triazine 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  非介晶三嗪和酸对超分子盘状结构的性质调整

  摘要：

  在这项工作中，提出了由三嗪T x和芳香酸A y之间的氢键诱导的一系列新的超分子盘状液晶，其中大部分表现出柱状介晶特性。利用平行于分子平面的氢键与三嗪衍生物和芳香酸的π-堆积趋势相结合的设计策略，已被向列相、近晶相或柱状液晶相广泛证实。FT-IR 和1证实了氢键配合物的形成通过变温 FT-IR 技术研究 H NMR 光谱及其稳定性。所有制备的氢键配合物均表现出介晶性质，并通过DSC、POM和XRD研究了它们的液晶性质。这项工作为我们进一步设计用于光电应用的氢键超分子液晶提供了有用的信息。

  DOI：

  10.1071/ch21189
• 作为产物：
  描述：

  2-氨基-4,6-二氯-S-三嗪 、 十二烷基伯胺 在 碳酸氢钠 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以90%的产率得到4-amino-2,6-didodecylamino-1,3,5-triazine
  参考文献：
  名称：

  非介晶三嗪和酸对超分子盘状结构的性质调整

  摘要：

  在这项工作中，提出了由三嗪T x和芳香酸A y之间的氢键诱导的一系列新的超分子盘状液晶，其中大部分表现出柱状介晶特性。利用平行于分子平面的氢键与三嗪衍生物和芳香酸的π-堆积趋势相结合的设计策略，已被向列相、近晶相或柱状液晶相广泛证实。FT-IR 和1证实了氢键配合物的形成通过变温 FT-IR 技术研究 H NMR 光谱及其稳定性。所有制备的氢键配合物均表现出介晶性质，并通过DSC、POM和XRD研究了它们的液晶性质。这项工作为我们进一步设计用于光电应用的氢键超分子液晶提供了有用的信息。

  DOI：

  10.1071/ch21189

文献信息

• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。
• Hierarchical Self-Organization of Perylene Bisimide–Melamine Assemblies to Fluorescent Mesoscopic Superstructures
  作者：Frank Würthner、Christoph Thalacker、Armin Sautter、Wolfgang Schärtl、Wolfram Ibach、Olaf Hollricher

  DOI：10.1002/1521-3765(20001103)6:21<3871::aid-chem3871>3.3.co;2-w

  日期：2000.11.3

  A series of three perylene tetracarboxylic acid bisimide dyes 3a-c bearing phenoxy substituents at the four bay positions of the perylene core were synthesized and their complexation behavior to complementary ditopic dialkyl melamines 8a-c was investigated. Binding constants and Gibbs binding energies for the hydrogen bonds between the imide and the complementary melamine moiety have been determined in several solvents by NMR and UV/Vis titration experiments with monotopic model compounds 5 and 9. The effects of the solvent polarity and specific solvent-solute interactions on the degree of polymerization of (3.8)(n), are discussed, and a general formula to estimate the chain length of [AA - BB](n) nylon-type supramolecular polymers is derived. In addition to the formation of a hydrogen-bonded supramolecular chain, pi-pi interactions were observed for perylene bisimide - melamine assemblies 3b.8b and 3b.8c in aliphatic solvents. The orthogonal nature of hydrogen bonding and pi-pi interactions leads to three-dimensional growth yielding large-sized aggregates already in dilute solution. On suitable substrates, densely intertwined networks of nano- to mesoscopic strands are formed which have been investigated by electron microscopy, confocal fluorescence microscopy and optical polarization microscopy. The high fluorescence and excellent photostability of these superstructures is promising for future studies on energy migration and artificial light harvesting at the nano- and mesoscopic length scale.
• Effect of Melamine-Amphiphile Structure on the Extent of Two-Dimensional Hydrogen-Bonded Networks Incorporating Barbituric Acid
  作者：Hiroshi Koyano、Philippe Bissel、Kanami Yoshihara、Katsuhiko Ariga、Toyoki Kunitake

  DOI：10.1002/chem.19970030715

  日期：1997.7

  AbstractFour alkyl melamine amphiphiles each containing identical triads of hydrogen‐bonding sites (hydrogen donor, acceptor, and donor) but different numbers of alkyl chains were examined in order to determine their monolayer properties and binding behavior towards barbituric acid (BA). Their structural organization in supramolecular assemblies at the air–water interface was affected by the bulkiness of the hydrophobic part of the amphiphile. Aqueous BA and amphiphiles with two or three alkyl chains formed a 1:1 alternate network structure. In contrast, a melamine amphiphile with four alkyl chains formed a 2:1 (BA:amphiphile) complex rather than a 1:1 alternate network structure. The 2:1 complex appears to behave like an independent molecular entity without further networking. The results point to the importance of size matching between the hydrophobic part of the monolayer and the underlying hydrogen‐bonded network in order to maintain the overall supramolecular structure.
• US6124381A
  申请人：——

  公开号：US6124381A

  公开（公告）日：2000-09-26
• Properties tuning of supramolecular discotics by non-mesogenic triazines and acids
  作者：Chunming He、Kunlun Wang、Yue Wang、Shengang Xu、Yingliang Liu、Shaokui Cao

  DOI：10.1071/ch21189

  日期：——

  confirmed by nematic, smectic or columnar liquid crystal phases. The formation of hydrogen bonded complexes was proven by FT-IR and 1H NMR spectroscopy and their stability studied by variable temperature FT-IR techniques. All prepared hydrogen bonded complexes displayed mesogenic properties and their liquid crystalline properties were investigated by means of DSC, POM and XRD. This work provides useful

  在这项工作中，提出了由三嗪T x和芳香酸A y之间的氢键诱导的一系列新的超分子盘状液晶，其中大部分表现出柱状介晶特性。利用平行于分子平面的氢键与三嗪衍生物和芳香酸的π-堆积趋势相结合的设计策略，已被向列相、近晶相或柱状液晶相广泛证实。FT-IR 和1证实了氢键配合物的形成通过变温 FT-IR 技术研究 H NMR 光谱及其稳定性。所有制备的氢键配合物均表现出介晶性质，并通过DSC、POM和XRD研究了它们的液晶性质。这项工作为我们进一步设计用于光电应用的氢键超分子液晶提供了有用的信息。