potassium tetrachlorogallate | 18154-89-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属盐
• 英文名称: potassium tetrachlorogallate
• 英文别名: gallium;potassium;tetrachloride
• CAS: 18154-89-7
• 化学式: Cl₄Ga*K
• 分子量: 250.633
• InChiKey: ZMXSIFWQSHIYAG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -0.62
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  potassium tetrachlorogallate 、 三氧化硫 以 liquid sulphur dioxide 为溶剂， 生成
  参考文献：
  名称：

  Vandorpe, B.; Drache, M .; Dubois, B., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1973, vol. 276, p. 73 - 76

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 氯化镓 在 CO 作用下， 以 苯 为溶剂， 生成 potassium tetrachlorogallate
  参考文献：
  名称：

  Binuclear palladium(I) and platinum(I) dimers stabilized by aromatic ligands: synthesis, structural characterization and reactivity with carbon monoxide

  摘要：

  Reaction of PdCl2 with excess of GaCl3 in aromatic solvents leads to binuclear compounds of the general formula [Pd2X2(arene)(2)], where arene = C6H6, X- = GaCl7- (1); arene = C7H8, X- = GaCl4- (2). The solid-state structures of compounds 1 and 2 have been determined by X-ray crystallography. Two molecules of the arene are bound to the dipalladium unit. The compounds 1 and 2 do not react with triphenyl phosphine. Reaction of carbon monoxide with 1 in benzene solution yields [Pd-2(GaCl4)(2)(C6H6)(2)] (3), for which the crystal structure has also been determined. The compound [Pt-2(GaCl4)(2)(C10H10)(2)].2C(6)H(6) (4), which was obtained by reaction of K-2[PtCl4] with GaCl3 and naphthalene in a benzene solution, has a similar structure in the solid state. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01577-3

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.3, 3.1.7.6.3.2, page 307 - 309
  作者：

  DOI：——

  日期：——
• Staffel, Th.; Meyer, G., Zeitschrift für Kristallographie
  作者：Staffel, Th.、Meyer, G.

  DOI：——

  日期：——
• Vandorpe, B.; Drache, M .; Dubois, B., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1973, vol. 276, p. 73 - 76
  作者：Vandorpe, B.、Drache, M .、Dubois, B.

  DOI：——

  日期：——
• Binuclear palladium(I) and platinum(I) dimers stabilized by aromatic ligands: synthesis, structural characterization and reactivity with carbon monoxide
  作者：Mikhail Gorlov、Andreas Fischer、Lars Kloo

  DOI：10.1016/s0020-1693(02)01577-3

  日期：2003.7

  Reaction of PdCl2 with excess of GaCl3 in aromatic solvents leads to binuclear compounds of the general formula [Pd2X2(arene)(2)], where arene = C6H6, X- = GaCl7- (1); arene = C7H8, X- = GaCl4- (2). The solid-state structures of compounds 1 and 2 have been determined by X-ray crystallography. Two molecules of the arene are bound to the dipalladium unit. The compounds 1 and 2 do not react with triphenyl phosphine. Reaction of carbon monoxide with 1 in benzene solution yields [Pd-2(GaCl4)(2)(C6H6)(2)] (3), for which the crystal structure has also been determined. The compound [Pt-2(GaCl4)(2)(C10H10)(2)].2C(6)H(6) (4), which was obtained by reaction of K-2[PtCl4] with GaCl3 and naphthalene in a benzene solution, has a similar structure in the solid state. (C) 2003 Elsevier Science B.V. All rights reserved.