Ruthenium--scandium (1/1) | 39388-94-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Ruthenium--scandium (1/1)
• 英文别名: ruthenium;scandium
• CAS: 39388-94-8
• 化学式: RuSc
• 分子量: 146.026
• InChiKey: FQTSENLSXYSRGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氢化钪 、 钌 以 neat (no solvent) 为溶剂， 生成 Ruthenium--scandium (1/1)
  参考文献：
  名称：

  Standard enthalpies of formation of scandium alloys, Sc+Me (MeFe, Co, Ni, Ru, Rh, Pd, Ir, Pt), by high-temperature calorimetry

  摘要：

  The standard enthalpies of formation of scandium alloys, Sc+Me (Me=Fe, Co, Ni, Ru, Rh, Pd, Ir, Pt) were determined by direct synthesis calorimetry at 1473 +/- 2K. The following values of DELTA(f)H(m)-degrees/(kJ g atom-1) are reported: Fe2SC, -(11.2 +/- 1.2); Co2Sc, -(32.5 +/- 2.1); CoSc2, -(26.7 +/- 1.9); Ni2SC, -(43.0 +/- 2.3); NiSc, -(44.7 +/- 2.3); RuSc, -(44.5 +/- 2.2); Rh3SC, -(51.7 +/- 1.4); RhSc, -(94.5 +/- 1.5); PdSc, -(89.3 +/- 2.2); IrSc, -(89.7 +/- 3.0); lr2SC, -(66.3 +/- 1.3); PtSc, -(104.8 +/- 5.4). The results are compared with predicted values, and with earlier data for some of the corresponding yttrium and titanium alloys.

  DOI：

  10.1016/0925-8388(93)90287-w

文献信息

• Remarkable Metal-Rich Ternary Chalcogenides Sc₁₄M₃Te₈ (M = Ru, Os)
  作者：Ling Chen、John D. Corbett

  DOI：10.1021/ja0291540

  日期：2003.2.1

  In this novel motif, scandium atoms define infinite parallel chains of alternate trans-face-sharing cubes and pairs of square antiprisms in which each polyhedron is also centered by an M atom (M = Ru, Os). These chains are further linked into a three-dimensional structure by Sc(Te2Te4/2) octahedra. Physical property measurements show Sc14Ru3Te8 to be metallic and Pauli-paramagnetic, consistent with

  在这个新颖的主题中，钪原子定义了无限平行的交替跨面共享立方体和成对方形反棱镜，其中每个多面体也以 M 原子为中心（M = Ru，Os）。这些链通过Sc(Te2Te4/2)八面体进一步连接成三维结构。物理性质测量表明 Sc14Ru3Te8 是金属的和泡利顺磁性的，这与扩展 Hückel 能带结构计算的结果一致。矩阵效应在链中的维度上很明显。主要的相互作用是 Sc-M 和 Sc-Te。
• Standard enthalpies of formation of scandium alloys, Sc+Me (MeFe, Co, Ni, Ru, Rh, Pd, Ir, Pt), by high-temperature calorimetry
  作者：N. Selhaoui、O.J. Kleppa

  DOI：10.1016/0925-8388(93)90287-w

  日期：1993.1

  The standard enthalpies of formation of scandium alloys, Sc+Me (Me=Fe, Co, Ni, Ru, Rh, Pd, Ir, Pt) were determined by direct synthesis calorimetry at 1473 +/- 2K. The following values of DELTA(f)H(m)-degrees/(kJ g atom-1) are reported: Fe2SC, -(11.2 +/- 1.2); Co2Sc, -(32.5 +/- 2.1); CoSc2, -(26.7 +/- 1.9); Ni2SC, -(43.0 +/- 2.3); NiSc, -(44.7 +/- 2.3); RuSc, -(44.5 +/- 2.2); Rh3SC, -(51.7 +/- 1.4); RhSc, -(94.5 +/- 1.5); PdSc, -(89.3 +/- 2.2); IrSc, -(89.7 +/- 3.0); lr2SC, -(66.3 +/- 1.3); PtSc, -(104.8 +/- 5.4). The results are compared with predicted values, and with earlier data for some of the corresponding yttrium and titanium alloys.