[(Me3C)2AlNHNH2]2 | 339528-81-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: [(Me3C)2AlNHNH2]2
• 英文别名: dialuminum;aminoazanide;2-methylpropane
• CAS: 339528-81-3
• 化学式: C₁₆H₄₂Al₂N₄
• 分子量: 344.499
• InChiKey: WKDFNFFTQOQXNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris[di(tert-butyl)aluminium hydride] 、 [(Me3C)2AlNHNH2]2 以 正己烷 、 甲苯 为溶剂， 以56%的产率得到[(Me3C)2AlNHNH]2[μ-Al(CMe3)2]2
  参考文献：
  名称：

  Dialkylaluminum Hydrazides Derived from Free Hydrazine N₂H₄. Molecular Structures of [(Me₃C)₂AlN₂H₃]₂ and [(Me₃C)₂Al]₄(N₂H₂)₂

  摘要：

  The reaction of di(tert-butyl)aluminum hydride with hydrazine N2H4 afforded the hydrazide (Me3C)(2)AIN(2)H(3), 1, by the release of elemental hydrogen. Compound I is a dimer ill solution and in the solid state and possesses a six-membered Al2N4 heterocycle in a twist conformation with two intact N-N bonds. Further reaction of 1 with an excess of Hal(CMe3)(2) yielded the tricyclic aluminum and nitrogen rich Al4N4 compound [(Me3C)(2)AlN2H2](2-) [Al(CMe3)(2)](2), 2, in which each N-N bond of a central six-membered Al2N4 ring similar to that of 1 is side-on-coordinated to an Al(CMe3)(2) group. The structure of 2 may be interpreted as a dimer of the dialuminum hydrazide (Me3C)(2)Al-NH-NH -Al(CMe3)(2).

  DOI：

  10.1021/ic000969o
• 作为产物：
  描述：

  tris[di(tert-butyl)aluminium hydride] 、 肼 以 正己烷 为溶剂， 以86%的产率得到[(Me3C)2AlNHNH2]2
  参考文献：
  名称：

  Dialkylaluminum Hydrazides Derived from Free Hydrazine N₂H₄. Molecular Structures of [(Me₃C)₂AlN₂H₃]₂ and [(Me₃C)₂Al]₄(N₂H₂)₂

  摘要：

  The reaction of di(tert-butyl)aluminum hydride with hydrazine N2H4 afforded the hydrazide (Me3C)(2)AIN(2)H(3), 1, by the release of elemental hydrogen. Compound I is a dimer ill solution and in the solid state and possesses a six-membered Al2N4 heterocycle in a twist conformation with two intact N-N bonds. Further reaction of 1 with an excess of Hal(CMe3)(2) yielded the tricyclic aluminum and nitrogen rich Al4N4 compound [(Me3C)(2)AlN2H2](2-) [Al(CMe3)(2)](2), 2, in which each N-N bond of a central six-membered Al2N4 ring similar to that of 1 is side-on-coordinated to an Al(CMe3)(2) group. The structure of 2 may be interpreted as a dimer of the dialuminum hydrazide (Me3C)(2)Al-NH-NH -Al(CMe3)(2).

  DOI：

  10.1021/ic000969o