tetra-(trimethylsilylmethyl)-silane | 18547-10-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: tetra-(trimethylsilylmethyl)-silane
• 英文别名: tetrakis-(trimethylsilanyl-methyl)-silane；Tetrakis-(trimethylsilyl-methyl)-silan；Trimethyl({tris[(trimethylsilyl)methyl]silyl}methyl)silane；tetrakis(trimethylsilylmethyl)silane
• CAS: 18547-10-9
• 化学式: C₁₆H₄₄Si₅
• 分子量: 376.953
• InChiKey: WRAOXASUQBQISK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.94
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  trimethylsilylmethyllithium 在 四氯化硅 作用下， 生成 tetra-(trimethylsilylmethyl)-silane
  参考文献：
  名称：

  Malonic Ester Syntheses with Organosilicon Compounds. New Silicon-containing Malonic Esters, Mono- and Dicarboxylic Acids, Barbituric Acids and a Disiloxanetetracarboxylic Acid¹

  摘要：

  DOI：

  10.1021/ja01635a043

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 31, page 96 - 99
  作者：

  DOI：——

  日期：——
• Silahydrocarbons and their preparation
  申请人：DOW CORNING

  公开号：US02507551A1

  公开（公告）日：1950-05-16
• Synthesis and characterization of mono-, bis-, tris- and tetrakis(trimethylsilylmethyl)silanes: (Me3SiCH2)xSiH4−x (x = 1−4)
  作者：Chris.K. Whitmarsh、Leonard V. Interrante

  DOI：10.1016/0022-328x(91)86347-s

  日期：1991.10

  The mono-, bis-, tris-, and tetrakis(trimethylsilylmethyl)silanes, (Me3SiCH2)(x)SiH4-x (x = 1-4), have been prepared for use as "models" of the various Si-centered functional units in a complex, highly branched polycarbosilane polymer of the approximate composition, "(SiH2CH2)n". These compounds have been characterized by GC, IR, H-1, C-13, Si-29 NMR, MS, and elemental analysis. The IR and NMR data for this series of compounds show distinct trends on increasing substitution, which are related to the structural differences within the series.
• Malonic Ester Syntheses with Organosilicon Compounds. New Silicon-containing Malonic Esters, Mono- and Dicarboxylic Acids, Barbituric Acids and a Disiloxanetetracarboxylic Acid¹
  作者：L. H. Sommer、G. M. Goldberg、G. H. Barnes、L. S. Stone

  DOI：10.1021/ja01635a043

  日期：1954.3