Zr(HPO₄)₂

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: Zr(HPO₄)₂
• 英文别名: Zr(HPO4)2；Dihydrogen phosphate;zirconium(4+);phosphate
• 化学式: H₂O₈P₂Zr
• 分子量: 283.183
• InChiKey: QOKYJGZIKILTCY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -4.39
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  167
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Zr(HPO₄)₂ 、 次磷酸 以 水 为溶剂， 生成 zirconium phosphate hypophosphite
  参考文献：
  名称：

  Preparation and some properties of Zr phosphate hypophosphite and Zr phosphate dimethylphosphinate with γ-layered structure

  摘要：

  It was found that the interlayer dihydrogen phosphate of gamma-Zr phosphate, other than by O2P(OH)R groups, can be totally or partially replaced by O2PR2 groups (R = H or organic radical). The preparations of two new compounds having composition ZrPO4.O2PH2 (interlayer distance = 8.84 angstrom) and ZrPO4.[O2P(OH)2]0.33[O2P(CH3)2]0.67 (int. dist. = 10.33 angstrom) are reported and discussed. The compounds were characterized by X-ray powder diffraction and thermogravimetric analysis, as well as, after dissolution, by chemical and NMR analysis. The formulation of the gamma-layered compounds can be now generalized as ZrPO4(O2PR'R")1-x(O2PR'"R"")x.nS, where the various R can be H, OH or an organic radical while S is a solvent in the interlayer region. Some considerations on their structure and their ion-exchange properties are also reported.

  DOI：

  10.1016/s0020-1693(00)85334-7
• 作为产物：
  描述：

  氟化锆 、 磷酸 生成 Zr(HPO₄)₂
  参考文献：
  名称：

  SADAOKA, Y.;MATSUGUCHI, M.;SAKAI, Y.;MITSUI, S., J. MATER. SCI., 22,(1987) N 8, 2975-2982

  摘要：

  DOI：

文献信息

• Process for cleaving the by-products of the direct synthesis of
  申请人：Rhone-Poulenc Chimie

  公开号：US05627297A1

  公开（公告）日：1997-05-06

  The process for cleaving the heavy by-products derived from the synthesis of alkylchlorosilanes, in particular C.sub.1 to C.sub.6 alkylchlorosilanes, more particularly methylchlorosilanes, in particular for the cleavage of alkylchlorodisilanes, in particular methylchlorodisilanes having from one to five chlorine atoms, is carried out by treatment with hydrochloric acid in the presence of a catalytic system which comprises at least one metal phosphate, preferably associated with a basic impregnation compound. The metal phosphate may in particular correspond to the formula: M(XPO.sub.4).sub.y in which M represents a metal chosen from: monovalent metals, in which case X is 2H and y=1 divalent metals, in which case X is H and y=1 trivalent metals, in which case X is absent and y=1 tetravalent metals, in which case X is: H and y=2 pentavalent metals, in which case X is 0 and y=1.

  从合成烷基氯硅烷的重质副产物中裂解的过程，特别是C.sub.1至C.sub.6烷基氯硅烷，更特别是甲基氯硅烷的裂解，特别是用于裂解具有一到五个氯原子的烷基氯二硅烷，通过在催化体系的存在下用氢氯酸处理来进行。该催化体系包括至少一种金属磷酸盐，优选与碱性浸渍化合物结合。金属磷酸盐可以特别对应于以下公式：M（XPO.sub.4）.sub.y，其中M表示所选金属：一价金属，此时X为2H且y=1；二价金属，此时X为H且y=1；三价金属，此时X不存在且y=1；四价金属，此时X为H且y=2；五价金属，此时X为0且y=1。
• ORTIZ-AVILA, C. YOLANDA;CLEARFIELD, ABRAHAM, J. CHEM. SOC. DALTONG TRANS,(1989) N, C. 1617-1623
  作者：ORTIZ-AVILA, C. YOLANDA、CLEARFIELD, ABRAHAM

  DOI：——

  日期：——
• WANG, JIQIANG;RAISTRICK, I. D.;HUGGINS, R. A., J. ELECTROCHEM. SOC., 136,(1989) N, C. 2529-2532
  作者：WANG, JIQIANG、RAISTRICK, I. D.、HUGGINS, R. A.

  DOI：——

  日期：——
• KRYUKOVA, A. I.;KORSHUNOV, I. A.;BRYZGALOVA, L. YU.;SKIBA, O. V.
  作者：KRYUKOVA, A. I.、KORSHUNOV, I. A.、BRYZGALOVA, L. YU.、SKIBA, O. V.

  DOI：——

  日期：——
• BORISOVA, A. L.;TKACHENKO, A. A., POROSH. METALLURGIYA,(1987) N 11, 26-30
  作者：BORISOVA, A. L.、TKACHENKO, A. A.

  DOI：——

  日期：——