methyl fluorosilane | 753-44-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: methyl fluorosilane
• 英文别名: Methyl-fluor-silan；Fluor-methyl-silan；Fluoro(methyl)silane
• CAS: 753-44-6
• 化学式: CH₅FSi
• 分子量: 64.1346
• InChiKey: OVBSGCLBYYVGQR-UHFFFAOYSA-N

物化性质

• 沸点：
  -41.6±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.09
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  tris-(monomethylsilyl)amine 在 三氟化硼 作用下， 生成 methyl fluorosilane
  参考文献：
  名称：

  439.一些甲硅烷基胺的制备和给体性质

  摘要：

  DOI：

  10.1039/jr9580002150

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.4, 4.4.1, page 110 - 117
  作者：

  DOI：——

  日期：——
• The synthesis and properties of (CH2F)SiH3 and related monofluoromethylsilanes
  作者：H. Bürger、P. Moritz

  DOI：10.1016/0022-328x(92)80068-9

  日期：1992.4

  The reduction of (CFCl2)SiCl3 by LiAlH4, Me3SnH, and (nBu)3SnH has been studied. The compound (CH2F)SiH3 (I) and all the compounds of the series (CFCl2-mHm)SiCl3-nHn, m = 0, 1 and n = 0-3 were detected and characterized by NMR spectroscopy. Conditions for the synthesis of I, (CHFCl)SiH3 (IX) and (CFCl2)SiH3 (V) with acceptable yields have been optimized. These novel compounds were studied by H-1, F-19, C-13 and Si-29 NMR spectroscopy; their infrared and Raman spectra were recorded and assigned with the assistance of a normal coordinate analysis of I and its isotopomer (CD2F)SiD3. The thermolyses of I, IX and (CHF2)SiH3 (X) which start at about 120, 200 and 180-degrees-C, respectively, have been studied. Whereas I decomposes by a migration of F from C to Si, compound X undergoes elimination of the carbene CHF, insertion of which into SiH bonds ultimately gives CH3Si derivatives.
• The Reaction of Silylamines with Boron Trifluoride. Methyl- and Silylaminoboron Difluorides
  作者：Sei Sujishi、Samuel Witz

  DOI：10.1021/ja01567a025

  日期：1957.5
• 117. The reaction of methyldisiloxanes and 1 : 1-dimethyldisilthiane with boron and hydrogen halides
  作者：H. J. Emeléus、M. Onyszchuk

  DOI：10.1039/jr9580000604

  日期：——
• 439. The preparation and donor properties of some silylamines
  作者：E. A. V. Ebsworth、H. J. Emeléus

  DOI：10.1039/jr9580002150

  日期：——