barium molybdate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱土金属氧阴离子化合物
• 英文名称: barium molybdate
• 英文别名: barium(2+);dioxido(dioxo)molybdenum
• 化学式: Ba*MoO₄
• 分子量: 297.268
• InChiKey: RCMWGBKVFBTLCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.0
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  barium molybdate 在 氨 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Heine, Journal fuer Praktische Chemie (Leipzig), 1836, vol. 9, p. 204 - 204

  摘要：

  DOI：
• 作为产物：
  描述：

  barium molybdate 以 neat (no solvent) 为溶剂， 生成 barium molybdate
  参考文献：
  名称：

  Phase formation, structural and microstructural characterization of novel oxynitride–perovskites synthesized by thermal ammonolysis of (Ca,Ba)MoO4 and (Ca,Ba)MoO3

  摘要：

  Reactions of AMoO(4) and AMoO(3) (A = Ca2+, Ba2+) with ammonia were investigated at 873 K

  DOI：

  10.1016/j.jssc.2008.05.012
• 作为试剂：
  描述：

  2-(benzotriazol-1-yl)acetophenone 在 barium molybdate 作用下， 生成 T406石油添加剂 、 苯甲醛 、 苯甲腈 、 苯胺 、 苯乙酮
  参考文献：
  名称：

  Mixed Oxides as Highly Selective Catalysts for the Flash Pyrolysis of Phenacyl Benzotriazole: One-Pot Synthesis of Dibenzazepin-7-one

  摘要：

  The one-pot synthesis of dibenzo[b,d]azepin-7-one (3) was selectively achieved from 1-phenacyl-1,2,3-benzotriazole (1) using the catalytic flash vacuum pyrolysis (cfvp) methodology. Catalysts with the scheelite structure ABO(4) (A = Ca2+, Sr2+, Ba2+ and B = Mo6+, W6+) and fergusonite BiVO4 were explored in this new catalytic reaction. These oxides promoted high conversion of starting material at lower temperatures than those observed for noncatalytic reactions. The chemical nature of A and B cations in the scheelite structure showed a strong influence on the formation toward the desired azepinone. In addition, the catalyst's morphology had a significant influence on the course of the cfvp reaction.

  DOI：

  10.1021/cs3008335

文献信息

• Tm3+ doped barium molybdate: A potential long-lasting blue phosphor
  作者：Ana Paula de Azevedo Marques、Roseli Künzel、Nancy K. Umisedo、Renato Mazin Latini、Elizabeth Mateus Yoshimura、Emico Okuno

  DOI：10.1016/j.jallcom.2017.10.225

  日期：2018.2

  (with x = 0, 0.01 or 0.03). The scheelite-type crystalline structure was identified from XRD and Raman studies. Under ultraviolet (359 nm) excitation, photoluminescence (PL) spectra present the characteristic emission bands at 453 nm and 545 nm which are due to the D 1 2 → F 3 4 and D 1 2 → H 3 4 , 5 transitions, respectively, from Tm3+ ions. Thermoluminescence (TL) measurements were performed with powdered

  摘要 钼酸盐在荧光粉、光纤、闪烁体、磁铁、传感器和催化剂等多个领域都有应用。铥离子是一种极好的蓝色活化剂，在持久发光材料的设计中起着重要作用。本文报告了对钼酸钡 (Ba1−xTmx)MoO4 微晶（x = 0、0.01 或 0.03）的结构和发光特性的研究。从 XRD 和拉曼研究中鉴定出白钨矿型晶体结构。在紫外 (359 nm) 激发下，光致发光 (PL) 光谱在 453 nm 和 545 nm 处呈现特征发射带，这分别是由于 D 1 2 → F 3 4 和 D 1 2 → H 3 4 , 5 跃迁，来自 Tm3+ 离子。热释光 (TL) 测量是用先前用 β 辐射照射的粉末样品进行的。陷阱的深度与位于带隙内的陷阱水平相关，是使用不同的辉光曲线分析方法从 TL 数据确定的。由热释光发光曲线确定的动力学参数提供了关于 (Ba0.97Tm0.03)MoO4 样品可能持续发光的证据。这是一种潜在的蓝光或紫外线长效荧光粉，在室温
• Well-defined barium molybdate hierarchical architectures with different morphologies: Controllable synthesis, formation process, and luminescence properties
  作者：Cuimiao Zhang、Lei Zhang、Changying Song、Guang Jia、Shuying Huo、Shigang Shen

  DOI：10.1016/j.jallcom.2013.11.075

  日期：2014.3

  BaMoO 4 microspheres has been investigated by time-dependent experiments. The as-synthesized BaMoO 4 :Ln 3+ (Ln = Eu, Tb, Dy, and Sm) phosphors show intense characteristic red, green, green–yellow, and orange–red emissions under ultraviolet light excitation, which might find potential applications in the fields of light emitting phosphors, advanced flat panel displays, and light-emitting diodes (LEDs)

  摘要 以十二烷基苯磺酸钠（SDBS）为表面活性剂，通过水热法成功合成了均匀且分散良好的钼酸钡（BaMoO 4 ）分级微球和微花。反应条件，包括 SDBS 添加剂、初始溶液的 pH 值以及反应温度，对 BaMoO 4 产物的尺寸和形貌有很大影响。BaMoO 4 微球的可能形成过程已经通过时间相关实验进行了研究。合成的 BaMoO 4 :Ln 3+（Ln = Eu、Tb、Dy 和 Sm）荧光粉在紫外光激发下显示出强烈的特征红色、绿色、绿-黄色和橙-红色发射，这可能会在以下领域找到潜在的应用发光磷光体、高级平板显示器和发光二极管 (LED) 领域。
• Order and Disorder: Toward the Thermodynamically Stable α-BaMoO₂F₄ from the Metastable Polymorph
  作者：Hongil Jo、Min Hyung Lee、Kang Min Ok

  DOI：10.1021/acs.chemmater.1c00074

  日期：2021.3.9

  been synthesized by a hydrothermal reaction at 200 °C in a concentrated hydrofluoric acid solution. A centrosymmetric polymorph with O/F disorder, β-BaMoO2F4, has been obtained in several minutes when the reaction mixture was stirred at room temperature in the same medium. Interestingly, we found that the metastable β-BaMoO2F4 transforms into the thermodynamically stable α-BaMoO2F4 in an ambient condition

  甲完全有序非中心对称钡钼氧氟化物，α-BaMoO 2 ˚F 4，已经通过在200℃的浓氢氟酸溶液的水热反应合成的。用O / F障碍，β-BaMoO甲中心对称多晶型物2 ˚F 4，在若干分钟的时候，反应混合物在相同的培养基中在室温下搅拌获得。有趣的是，我们发现，亚稳β-BaMoO 2 ˚F 4变换成热力学稳定的α-BaMoO 2 ˚F 4在环境条件。使用粉末X射线衍射的更详细的动力学研究表明，MoO 2 F 4八面体在动力学相，β-BaMoO 2 ˚F 4，重新排列通过不断溶解/沉淀过程中找到一个更稳定的方向，并形成完全有序α-BaMoO 2 ˚F 4。密度泛函理论（DFT）计算表明，热力学稳定的α-BaMoO的形成2 ˚F 4是由强的Mo-O由Ba诱导π-相互作用驱动2+阳离子。对固态反应动力学理解的新发现为有效发现具有不对称结构的功能材料提供了一种新颖的方法。
• Microstructure and Spectroscopic Properties of AMoO4 (A = Ca, Ba) Particles Synthesized via Cyclic Microwave-Assisted Metathetic Route
  作者：Chang Sung Lim

  DOI：10.14233/ajchem.2014.16519

  日期：——

  AMoO4 (A=Ca, Ba) particles have been successfully synthesized via cyclic microwave-assisted metathetic route in ethylene glycol followed by further heat-treatment. The AMoO4 (A=Ca, Ba) particles were well crystallized after heat-treatment at 400-600 °C for 3 h. The microstructures exhibited fine morphologies with sizes of 0.5-1 and 1.5-2 μm for the CaMoO4 and BaMoO4 particles, respectively. The synthesized AMoO4 (A=Ca, Ba) particles were characterized by X-ray diffraction, scanning electron microscopy. Other spectroscopic properties were also examined using photoluminescence emission measurements and Raman spectroscopy.

  AMoO4 (A=Ca, Ba) 粒子通过在乙二醇中循环微波辅助的变质路线成功合成，随后进行了进一步的热处理。经在 400-600 °C 下热处理 3 小时后，所得到的 AMoO4 (A=Ca, Ba) 粒子结晶良好。微观结构显示出 CaMoO4 和 BaMoO4 粒子的细致形态，尺寸分别为 0.5-1 μm 和 1.5-2 μm。合成的 AMoO4 (A=Ca, Ba) 粒子经过 X 射线衍射和扫描电子显微镜表征。还使用光致发光发射测量和拉曼光谱检查了其他光谱特性。
• Synthesis, Characterization and Luminescent Properties of Green Phosphor BaMoO4:Tb3+
  作者：Jianfu Zhang、Lili Zhu、Jianping Xie、Yuanpeng Chen、Zhenling Wang

  DOI：10.14233/ajchem.2015.18411

  日期：——

  The green phosphor BaMoO4:Tb3+ was prepared by sol-gel method. The effects of doping concentration and sintering temperature on the crystal structure and luminescent properties were investigated by X-ray powder diffraction, scanning electron microscope, UV-visible spectroscopy and photoluminescence spectroscopy. The XRD results showed a pure BaMoO4 phase can be obtained when calcinating phosphor at 900 °C. The photoluminescence spectroscopy spectra exhibited four peaks, the most intense peak of 542 nm can be attributed to 5D4 ® 7F5 transition of Tb3+ and the optimized mol percent of Tb3+ was 0.05. All the results indicated that BaMoO4: Tb3+ could be used as a white-light emitting diodes ultraviolet photoexcitation green phosphors.

  绿色磷光体BaMoO4:Tb3+是通过溶胶-凝胶方法制备的。通过X射线粉末衍射、扫描电子显微镜、紫外-可见光谱和光致发光光谱研究了掺杂浓度和烧结温度对晶体结构和发光特性的影响。XRD结果显示，磷光体在900°C煅烧后可以获得纯BaMoO4相。光致发光光谱展现了四个峰，其中最强的542 nm峰可归因于Tb3+的5D4到7F5跃迁，优化的Tb3+摩尔百分比为0.05。所有结果表明，BaMoO4:Tb3+可以作为白光发光二极管的紫外光激发绿色磷光体使用。