mercury(II) selenite

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: mercury(II) selenite
• 英文别名: mercury selenite；Mercuric selenite；mercury(2+);selenite
• 化学式: Hg*O₃Se
• 分子量: 327.548
• InChiKey: AVIMRQLSVPLDRI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.88
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  mercury(II) selenite 在 C 作用下， 生成 mercury(II) selenide
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B3, 2.5.2, page 1096 - 1100

  摘要：

  DOI：
• 作为产物：
  描述：

  mercury(II) selenate 以 neat (no solvent, solid phase) 为溶剂， 生成 mercury(II) selenite
  参考文献：
  名称：

  Gospodinov, G.; Barkov, D., Crystal Research and Technology

  摘要：

  DOI：

文献信息

• Polymorphism in mercury(I) selenite(IV): preparation, crystal structures of α-, β-and γ-Hg2SeO3, and thermal behavior of the α- and β-modification
  作者：Matthias Weil

  DOI：10.1016/s0022-4596(02)00082-8

  日期：2003.4

  highest density of the three modifications. Colorless needle-shaped single crystals of β-Hg2SeO3 and very few single crystals of γ-Hg2SeO3 co-crystallize from strongly diluted Hg2(NO3)2 and H2SeO3 solutions and were grown by a diffusion technique. All crystal structures were solved and refined from single crystal diffractometer data sets and are based on Hg22+ dumbbells and trigonal pyramidal SeO32−

  汞（I）的亚硒酸盐（IV）是多态和在3个修饰，命名为至少结晶α - ，β -和γ -Hg 2的SeO 3。多晶β -Hg 2的SeO 3通过用亚硒酸的浓硝酸亚汞溶液的沉淀制备的。无色的水热处理β -Hg 2的SeO 3在250℃下（10天）粉末在去离子水中得到的浅黄色单晶α -Hg 2的SeO 3显示了三个修改的最高密度。的无色针状单晶β -Hg 2的SeO 3和很少的单晶γ -Hg 2的SeO 3共结晶从强烈稀释汞柱2（NO 3）2和H 2的SeO 3溶液和通过扩散生长技术。所有晶体结构都根据单晶衍射仪数据集进行了解析和细化，并基于Hg 2 2+哑铃和三角锥SeO 3 2-阴离子为主要的建筑单位。所有修改的共同结构特征是形成平行于最短结晶学轴延伸的开放通道。Se IV原子的非键合轨道具有立体化学活性，并突出到通道中。在氮气氛下在开放体系中进行加热2气氛下，将两个α -和β -Hg 2的SeO
• Investigations in the Systems Ag-Hg-X-O (X = As^V, Se^IV, Se^VI): Hydrothermal Single Crystal Growth of Ag₃AsO₄, AgHg^I ₂AsO₄, AgHg^IIAsO₄, Ag₂SeO₄ and the Crystal Structure of Ag₂Hg^II(SeO₃)₂
  作者：Matthias Weil

  DOI：10.1515/znb-2003-1110

  日期：2003.11.1

  Single crystals of the already known phases Ag₃AsO₄, AgHg^I ₂AsO₄, AgHg^IIAsO₄, Ag₂SeO₄ and of the hitherto unknown compound Ag₂Hg^II(SeO₃)₂ were obtained under hydrothermal conditions (250 °C, 5d) from starting mixtures of the metal nitrates and the respective acids. Both Ag₃AsO₄ and AgHg^I ₂AsO₄ are isotypic with the corresponding phosphates, Ag₃PO₄ and AgHg^I ₂PO₄, whereas AgHg^IIAsO₄ and Ag₂SeO₄ crystallize in the thenardite (Na₂SO₄ (V)) structure. All crystal structures were refined by means of single crystal X-ray data. The crystal structure of Ag2Hg^II(SeO₃)₂ [Pbca, Z = 8, a = 6.8206(11), b = 11.237(3), c = 16.876(2) Å , 1677 structure factors, 101 parameters, R[F² > 2σ (F²)] = 0.0193, wR(F² all) =0.0394] consists of considerably distorted [AgO₆] and [HgO₆] octahedra, and trigonal Se^IVO₃ pyramids as the main building units. The [MO₆] octahedra build a complex framework by sharing common edges and corners, and the Se^IVO₃ pyramids are located in the vacancies of this arrangement. The average Hg-O distance of 2.399 Å is significantly shorter than the average Ag-O distance of 2.551Å . The geometries of the two crysta̱llographically independent Se^IVO₃ pyramids are very similar and the average distance and angle (d(Se-O) = 1.709 Å , ∠(O-S-O) = 100.1°) lie in the characteristic range for a selenite(IV) group. A short comparative structural discussion between the various compounds obtained during the hydrothermal experiments is given.

  在250°C、5天的水热条件下，从金属硝酸盐和相应酸的起始混合物中得到了已知相Ag₃AsO₄、AgHg^I₂AsO₄、AgHg^IIAsO₄、Ag₂SeO₄以及迄今为止未知的化合物Ag₂Hg^II(SeO₃)₂的单晶。Ag₃AsO₄和AgHg^I₂AsO₄与相应的磷酸盐Ag₃PO₄和AgHg^I₂PO₄同晶，而AgHg^IIAsO₄和Ag₂SeO₄结晶于thenardite（Na₂SO₄（V））结构中。所有晶体结构都通过单晶X射线数据进行了精确修正。Ag2Hg^II(SeO₃)₂的晶体结构[Pbca，Z = 8，a = 6.8206(11)，b = 11.237(3)，c = 16.876(2) Å，1677个结构因子，101个参数，R[F² > 2σ(F²)] = 0.0193，wR(F² all) = 0.0394]由明显扭曲的[AgO₆]和[HgO₆]八面体以及三角形的Se^IVO₃金字塔作为主要构建单元组成。[MO₆]八面体通过共享公共边和角构建复杂的框架，Se^IVO₃金字塔位于这种排列的空位中。平均Hg-O距离为2.399 Å，明显短于平均Ag-O距离2.551 Å。两个晶体学上独立的Se^IVO₃金字塔的几何形状非常相似，平均距离和角度（d(Se-O) = 1.709 Å，∠(O-S-O) = 100.1°）处于硒酸盐（IV）群的特征范围内。对水热实验中得到的各种化合物进行了简短的结构比较讨论。

• Cameron, C. A.; Davy, E. W., Chemical news and journal of industrial science, 1881, vol. 44, p. 63 - 64
  作者：Cameron, C. A.、Davy, E. W.

  DOI：——

  日期：——
• Cameron, C. A.; Davy, E. W., 1880, vol. 28, p. 137 - 147
  作者：Cameron, C. A.、Davy, E. W.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B3, 2.5.4, page 1101 - 1103
  作者：

  DOI：——

  日期：——