mercurous nitrate | 10415-75-5

• 物质功能分类: 无机化工 - 无机盐 - 金属硝酸盐及亚硝酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: mercurous nitrate
• 英文别名: Nitrooxymercury
• CAS: 10415-75-5
• 化学式: Hg*NO₃
• 分子量: 262.595
• InChiKey: DRXYRSRECMWYAV-UHFFFAOYSA-N

物化性质

• 熔点：
  decomposes at 70℃ [HAW93]
• 密度：
  4.785
• 溶解度：
  微溶于H2O
• 物理描述：
  Mercurous nitrate appears as a white solid. Usually exists as the dihydrate. Toxic by ingestion.
• 颜色/状态：
  Solid, white
• 气味：
  Slight odor of nitric acid
• 腐蚀性：
  Solution may corrode metals
• 稳定性/保质期：
  失火时，消防人员必须穿戴全身防护服。他们可以使用雾状水、砂土或各类灭火器进行灭火。

计算性质

• 辛醇/水分配系数(LogP)：
  -0.24
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  62.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险等级：
  6.1(a)
• 海关编码：
  2834299090
• 包装等级：
  II
• 危险类别：
  6.1(a)
• 危险品运输编号：
  UN 1627
• 储存条件：
  应将仓储于阴凉、干燥且通风良好的库房内，避免吸潮导致变质。远离热源和火种，并与其他有机物、可燃物质、还原剂、硫黄及磷等分开存放与运输。在搬运过程中，请轻装轻卸，以防容器破损。同时注意防雨淋和日晒。

SDS

Name:	Mercury(I) nitrate dihydrate p.a. Material Safety Data Sheet
Synonym:	Nitric acid, mercury(1+)salt, dihydrate
CAS:	10415-75-5

Section 1 - Chemical Product MSDS Name:Mercury(I) nitrate dihydrate p.a. Material Safety Data Sheet
Synonym:Nitric acid, mercury(1+)salt, dihydrate

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
10415-75-5	Mercury(I) nitrate dihydrate	>98	unlisted

Hazard Symbols: T+
Risk Phrases: 26/27/28 33

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.Light sensitive.
Potential Health Effects
Eye:
May cause chemical conjunctivitis. Causes eye irritation and possible injury.
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
May cause dermatitis.
Ingestion:
May be fatal if swallowed. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Inorganic mercury compounds may cause central and peripheral nervous system effects.
Inhalation:
May be fatal if inhaled. Exposure produces central nervous system depression. May produce general weakness, vomiting, diarrhea, chest pains, coughing, shortness of breath, and cardiac insufficiency.
Causes irritation of the mucous membrane and upper respiratory tract.
Chronic:
Chronic ingestion may cause accumulation of mercury in body tissues.
There is a danger of cumulative effects. May cause kidney damage.
Prolonged or repeated exposure may cause inflammation of the mouth and gums, excessive salivation, and loosening of the teeth.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May decompose explosively when heated or involved in a fire.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Store protected from light. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Poison room locked. Store protected from light. Store in a cool, dry area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 10415-75-5: CAS# 14836-60-3: United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds): mg/m3 VLE (as Hg) France - VME: (listed as mercury, aryl and inorganic compounds): mg/m3 VME (as Hg) Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m VME (as Hg) Germany: (listed as mercury inorganic compounds): Skin absorber Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1 mg/m3 TWA (as Hg) Netherlands: (listed as mercury inorganic compounds): 0.15 mg/m3 Netherlands: (listed as mercury inorganic compounds): 0.05 mg/m3 Russia: (listed as mercury inorganic compounds): 0.2 mg/m3 TWA (a Hg) Russia: (listed as mercury inorganic compounds): 0.05 mg/m3 STEL Hg) Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/ VLA-ED (as Hg) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 70 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 20 g/l (20 c)
Specific Gravity/Density: 4.7800g/cm3
Molecular Formula: HgNO3.2H2O
Molecular Weight: 298.60

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Light sensitive.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Metals, reducing agents, ammonia, copper, acetylene, lithium, rubidium, sodium carbide, calcium, chlorine dioxide, azides, heat, direct light, wood, combustible materials.
Hazardous Decomposition Products:
Nitrogen oxides, nitrogen, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10415-75-5: OW8000000 CAS# 14836-60-3 unlisted.
LD50/LC50:
CAS# 10415-75-5: Oral, mouse: LD50 = 49300 ug/kg; Oral, rat: LD50 = 170 mg/kg; Skin, rat: LD50 = 2330 mg/kg.
CAS# 14836-60-3.
Carcinogenicity:
Mercurous nitrate - Not listed by ACGIH, IARC, or NTP.
Mercury(I) nitrate dihydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION
Other No information available.

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: MERCUROUS NITRATE
Hazard Class: 6.1
UN Number: 1627
Packing Group: II
IMO
Shipping Name: MERCUROUS NITRATE
Hazard Class: 6.1
UN Number: 1627
Packing Group: II
RID/ADR
Shipping Name: MERCUROUS NITRATE
Hazard Class: 6.1
UN Number: 1627
Packing group: II
USA RQ: CAS# 10415-75-5: 10 lb final RQ; 4.54 kg final RQ

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 1/2 Keep locked up and out of reach of children.
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10415-75-5: 3
CAS# 14836-60-3: No information available.
Canada
CAS# 10415-75-5 is listed on Canada's DSL List.
CAS# 10415-75-5 is listed on Canada's Ingredient Disclosure List.
CAS# 14836-60-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10415-75-5 is listed on the TSCA inventory.
CAS# 14836-60-3 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

毒性

参见一水硝酸汞。

化学性质

无色晶体，具有硝酸气味。

用途

用作分析试剂及氧化剂；用于制药、作为氧化剂和通用分析试剂。

生产方法

将稀硝酸加入耐酸反应器中，在40～50℃下缓缓加入汞进行反应。经蒸发浓缩、冷却结晶、离心分离后制得二水硝酸亚汞。 [2\text{Hg} + 2\text{HNO}_3 + 2\text{H}_2\text{O} \rightarrow 2\text{Hg(NO}_3)_2·2\text{H}_2\text{O} + \text{H}_2↑]

类别

氧化剂

毒性分级

高毒

急性毒性

• 大鼠口服 LD50: 170毫克/公斤
• 小鼠口服 LD50: 49.3毫克/公斤

爆炸物危险特性

与还原剂、硫、磷等混合受热、撞击或摩擦可爆炸。

可燃性危险特性

受热分解产生有毒汞蒸气和氮氧化物烟雾；与有机物、还原剂、易燃物质（如硫、磷）混合可能燃烧。

储运特性

库房需通风低温干燥；轻装轻卸；与有机物、还原剂、硫、磷等易燃物品及食品原料分开存放。

灭火剂

使用雾状水、砂土或泡沫灭火。

职业标准

• 时间加权平均容许浓度（TWA）：0.1毫克/立方米
• 短时间接触容许浓度（STEL）：0.15毫克/立方米（汞）

反应信息

• 作为反应物：
  描述：

  mercurous nitrate 在 Na niobate 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Nb: MVol.B3, 8.2, page 115 - 116

  摘要：

  DOI：
• 作为产物：
  描述：

  mercury(II) platinum(II) cyanide*2HgNO3*10H2O 在 水 作用下， 生成 mercurous nitrate
  参考文献：
  名称：

  Rammelsberg, C., Annalen der Physik, 1848, vol. 73, p. 117

  摘要：

  DOI：
• 作为试剂：
  描述：

  D-lyxose 在 mercurous nitrate 作用下， 以48%的产率得到D-阿拉伯糖酸
  参考文献：
  名称：

  Krupenskii, V. I., Journal of general chemistry of the USSR, 1988, vol. 58, # 7, p. 1479 - 1481

  摘要：

  DOI：

文献信息

• Design and synthesis of new thiobarbituric acid metal complexes as potent protease inhibitors: spectral characterization, thermal analysis and DFT calculations
  作者：Mostafa Y. Nassar、Walaa H. El-Shwiniy、A. M. El-Sharkawy、S. I. El-Desoky

  DOI：10.1007/s13738-017-1229-3

  日期：2018.2

  Five novel metal complexes of thiobarbituric acid (TBAH) have been prepared with the general formulae: [Ti(TBA)2(H2O)2]Cl2·2H2O, [Pd(TBA)2]·4H2O, Na[Ag(TBA)2(H2O)2]·4H2O, [Hg(TBA)2(H2O)2] and [Ce(TBA)2(H2O)3]SO4·H2O. The complexes have been fully characterized employing physicochemical and diverse spectroscopic techniques (IR, UV–Vis, mass and 1H NMR) as well as thermal analysis. Elemental analyses

  制备了五种新的硫代巴比妥酸（TBAH）金属配合物，其通式为：[Ti（TBA）2（H 2 O）2 ] Cl 2 ·2H 2 O，[Pd（TBA）2 ]·4H 2 O， Na [Ag（TBA）2（H 2 O）2 ]·4H 2 O，[Hg（TBA）2（H 2 O）2 ]和[Ce（TBA）2（H 2 O）3 ] SO 4 ·H 2 O.使用理化和多种光谱技术（红外，紫外-可见，质谱和质谱）对络合物进行了充分表征。1 H NMR）以及热分析。元素分析和光谱数据表明，所有配合物的化学计量比均为1：2。热分析测量表明该配合物具有良好的热稳定性。密度泛函理论计算是在理论的B3LYP级别上进行的，其中包括钛，钯，铈原子的双基组，LANL2DZ基组，或银，汞原子和6-31 + G（d，p）的LANL2MB基组。其他原子的基础集。基于优化的结构获得了配体及其配合物的优化的几何形状。配体及其金属配合物充当蛋白酶抑制剂，并显着抑制其酶促活性。
• Coordination polymers of Ag(<scp>i</scp>) and Hg(<scp>i</scp>) ions with 2,2′-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(<scp>ii</scp>) ions
  作者：Suvendu Maity、Kaushik Naskar、Tanmay Bhowmik、Amalendu Bera、Thomas Weyhermüller、Chittaranjan Sinha、Prasanta Ghosh

  DOI：10.1039/d0dt01470b

  日期：——

  the crystals confirmed that 1 and 2 are conductors of electricity. The relative conductivity of 1 is 62 times greater than that of 2. The conductivity of 1 increases 70 fold when it reacts with Cu2+ ions.

  类型为[Hg 2（abpy）2 ] n [PF 6 ] 2 n（1）和[Ag（abpy）] n [PF 6 ] n（2）（abpy = 2,2）的阳离子配位聚合物（CPs）合成了'-偶氮二吡啶）并进行了表征。使用晶体进行的实验证实了1和2是电的导体。的相对电导率1比更大的62倍2。1与Cu 2+离子反应时，电导率1增加70倍。
• Optical behavior of mercury films studied by surface plasmon excitation
  作者：A. Tadjeddine、A. Rahamani、G. Piazza、M. Costa

  DOI：10.1016/0013-4686(89)85048-0

  日期：1989.12

  Mercury films electrochemically coated on a platinum substrate to be used as vertical electrode have been studied by surface plasmon excitation. Their optical properties change drastically with their thicknesses; thin films appear as a mercury—platinum compound showing a negative surface plasmon dispersion due to the virtual bound states which may exist in such materials.

  通过表面等离子体激元激发研究了电化学涂覆在铂基底上用作垂直电极的汞膜。它们的光学特性随厚度的变化而急剧变化。薄膜以汞-铂化合物的形式出现，由于这种材料中可能存在的虚拟键合态，因此显示出负的等离激元弥散。
• Protein-Directed Synthesis of NIR-Emitting, Tunable HgS Quantum Dots and their Applications in Metal-Ion Sensing
  作者：Nirmal Goswami、Anupam Giri、Shantimoy Kar、Megalamane Siddaramappa Bootharaju、Robin John、Paulrajpillai Lourdu Xavier、Thalappil Pradeep、Samir Kumar Pal

  DOI：10.1002/smll.201200760

  日期：2012.10.22

  X‐ray analysis (EDX), and picosecond‐resolved optical spectroscopy. Formation of various sizes of QDs is observed by modifying the conditions suitably. The QDs also show tunable luminescence over the 680–800 nm spectral regions, with a quantum yield of 4–5%. The as‐prepared QDs can serve as selective sensor materials for Hg(II) and Cu(II), based on selective luminescence quenching. The quenching mechanism

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• Zn(II), Cd(II) and Hg(I) complexes of cinnamic acid: FT-IR, FT-Raman, 1H and 13C NMR studies
  作者：M. Kalinowska、R. Świsłocka、W. Lewandowski

  DOI：10.1016/j.molstruc.2011.01.063

  日期：2011.5

  The effect of zinc, cadmium(II) and mercury(I) ions on the electronic structure of cinnamic acid (phenylacrylic acid) was studied. In this research many miscellaneous analytical methods, which complement one another, were used: infrared (FT-IR), Raman (FT-Raman), nuclear magnetic resonance ( 1 H, 13 C NMR) and quantum mechanical calculations. The spectroscopic studies provide some knowledge on the distribution

  摘要 研究了锌、镉(II)和汞(I)离子对肉桂酸(苯基丙烯酸)电子结构的影响。在这项研究中，使用了许多相互补充的杂项分析方法：红外（FT-IR）、拉曼（FT-Raman）、核磁共振（ 1 H、 13 C NMR）和量子力学计算。光谱研究提供了一些关于分子中电子电荷分布、π电子离域能和金属配合物反应性的知识。在 Zn(II) → Cd(II) → Hg(I) 肉桂酸酯系列中：(1) 实验和理论红外和拉曼光谱中几个波段的系统位移和 (2) 质子 1 H 和 13 的常规化学位移观察到C核。