二乙基二氯化铅 | 13231-90-8
中文名称
二乙基二氯化铅
中文别名
——
英文名称
diethyllead dichloride
英文别名
Diaethylbleidichlorid
CAS
13231-90-8
化学式
C4H10Cl2Pb
mdl
——
分子量
336.229
InChiKey
LXKLAFGSADZFAV-UHFFFAOYSA-L
BEILSTEIN
——
EINECS
——
-
物化性质
-
计算性质
-
ADMET
-
安全信息
-
SDS
-
制备方法与用途
-
上下游信息
-
文献信息
-
表征谱图
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同类化合物
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相关功能分类
-
相关结构分类
物化性质
-
熔点：220 °C (decomp)
-
沸点：193.4±23.0 °C(Predicted)
计算性质
-
辛醇/水分配系数(LogP)：-4.42
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重原子数：7
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可旋转键数：0
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环数：0.0
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sp3杂化的碳原子比例：1.0
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拓扑面积：0
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氢给体数：0
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氢受体数：2
安全信息
-
海关编码：2931900090
SDS
Version 1.2
Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name DICHLORODIETHYLLEAD - 50 MG
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Toxic if swallowed.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
DICHLORODIETHYLLEAD 13231-90-8 None None
Formula C4H10CL2PB
Molecular Weight 336,2300 AMU
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.
5 - Fire Fighting Measures
ALDRICH www.molbase.com
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face particle respirator type N99 (US)
or type P2 (EN 143) respirator cartridges as a backup to
engineering controls. If the respirator is the sole means of
protection, use a full-face supplied air respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
ALDRICH www.molbase.com
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Lead/lead oxides, Hydrogen chloride gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
ACUTE TOXICITY
LD50
Oral
Rat
146,000000 mg/kg
LD50
Oral
Mouse
420,000000 mg/kg
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: Toxic if swallowed.
12 - Ecological Information
ALDRICH www.molbase.com
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 3467
Class: 6.1
PG: III
Proper Shipping Name: Organometallic compound, toxic,
solid, n.o.s.
IMDG
UN#: 3467
Class: 6.1
PG: III
Proper Shipping Name: Organometallic compound, toxic,
solid, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3467
Class: 6.1
PG: III
Proper Shipping Name: Organometallic compound, toxic,
solid, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: T
Toxic.
R-PHRASES: 25
Toxic if swallowed.
S-PHRASES: 45
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Caution: Substance not yet fully tested (EU).
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
ALDRICH www.molbase.com
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICH www.molbase.com
SECTION 16 - ADDITIONAL INFORMATION
N/A
Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name DICHLORODIETHYLLEAD - 50 MG
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Toxic if swallowed.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
DICHLORODIETHYLLEAD 13231-90-8 None None
Formula C4H10CL2PB
Molecular Weight 336,2300 AMU
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.
5 - Fire Fighting Measures
ALDRICH www.molbase.com
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face particle respirator type N99 (US)
or type P2 (EN 143) respirator cartridges as a backup to
engineering controls. If the respirator is the sole means of
protection, use a full-face supplied air respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
ALDRICH www.molbase.com
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Lead/lead oxides, Hydrogen chloride gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
ACUTE TOXICITY
LD50
Oral
Rat
146,000000 mg/kg
LD50
Oral
Mouse
420,000000 mg/kg
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: Toxic if swallowed.
12 - Ecological Information
ALDRICH www.molbase.com
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 3467
Class: 6.1
PG: III
Proper Shipping Name: Organometallic compound, toxic,
solid, n.o.s.
IMDG
UN#: 3467
Class: 6.1
PG: III
Proper Shipping Name: Organometallic compound, toxic,
solid, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3467
Class: 6.1
PG: III
Proper Shipping Name: Organometallic compound, toxic,
solid, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: T
Toxic.
R-PHRASES: 25
Toxic if swallowed.
S-PHRASES: 45
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Caution: Substance not yet fully tested (EU).
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
ALDRICH www.molbase.com
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICH www.molbase.com
SECTION 16 - ADDITIONAL INFORMATION
N/A
反应信息
-
作为反应物：参考文献：名称：有机油化学：VII。与锌反应去除水溶液中的乙基铅化合物摘要：水溶液中的三乙基氯化铅与锌反应生成六乙基铅作为主要产物。反应分两步进行，从溶液中除去可溶性有机铅。比六乙基铅的形成要快。二氯化二乙基铅在与锌反应时还会产生六乙基铅，并且在反应的中间阶段检测到三乙基铅（IV）种类。据认为，六乙基铅不是由涉及具有铅锌键的化合物的反应形成的，而可能是由Et 3 Pb的二聚作用形成的。部首。该反应已用于处理四乙铅生产的废水。DOI：10.1016/s0022-328x(00)93760-4
-
作为产物：参考文献：名称：Goddard,A.E.; Goddard,D., Journal of the Chemical Society, 1922, vol. 121, p. 260摘要：DOI：
文献信息
-
Synthesis and structural characterization of Group 14 complexes containing two {9-[2-(dimethylamino)ethyl]fluorenyl-} ligands and a unique coupling product作者：Richard A Kemp、Linfeng Chen、Ilia Guzei、Arnold L RheingoldDOI：10.1016/s0022-328x(99)00540-9日期：2000.2Reaction of two equivalents of 9-[2-(dimethylamino)ethyl]fluorenyl}lithium (FlNLi) with either Me2GeCl2 or Me2SnCl2 leads cleanly to the new compounds (FlN)2MMe2, where M=Ge, Sn. These new complexes are the first compounds that contain multiple FlN ligands which have been characterized by X-ray diffraction. Attempts to prepare the analogous Pb compound using Et2PbCl2 were not successful, yielding
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DE313876申请人：——公开号：——公开（公告）日：——
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Gruettner; Krause, Chemische Berichte, 1916, vol. 49, p. 1421作者：Gruettner、KrauseDOI：——日期：——
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STUDIES OF ORGANIC LEAD COMPOUNDS. III. THE REACTION OF ORGANIC LEAD SALTS ON MERCURY AND LEAD ARYLS作者：Paul R. AustinDOI：10.1021/ja01347a039日期：1932.8
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Gilman; Robinson, Journal of the American Chemical Society, 1930, vol. 52, p. 1977作者：Gilman、RobinsonDOI：——日期：——
同类化合物
黄原酸环癸酯
高纯三甲基锑
顺式-二氯二(环丙胺)铂(II)
顺式-二氯二(乙二胺)氯化铑(1+)
顺式-二(环己基丁氨合)二氯铂(II)
顺式-二(异丙基氨合)二氯铂(II)
顺式-(2-氨基甲基-1-环戊基氨合)二氯铂(II)
顺二氯二羰基铂（II）
顺-二氯双(乙二胺)氯化铱
雷(酸)汞[含水或水加乙醇≥20]
间碳硼烷-9-硫醇
镍,加合(7:2)钪
镉二(二戊基二硫代氨基甲酸盐)
镁,溴-6-庚烯基-
manganese carbide
butyl manganese bromide
锡烷,氯二环己基-
锡四丁醇
锑,(1:1)混合物和钪
锌叔-丁氧化物
锌,溴-1-丙烯基-,(E)-
锇,加合(2:1)钪
锆酸四丁酯
锂丁酯
锂4-异丙氧基-2-甲基-丁烷-2-醇
锂1-丁醇
锂(三氟甲基)乙炔化物
锂(3-氨基丙基)酰胺
铼五羰基碘化物
铼五羰基
银(I)2-羟基乙烷-1-硫醇盐
铯三氯三羰基锇
铬三乙二胺
铬,五羰基(环己胺)-,(OC-6-22)-
铬,二(乙酰腈)二氯-
铝,加合(3:1)钪
铜-乙二胺络合物
铜(II)乙二胺
铜(I)乙炔化物
铍,环戊-1,3-二烯,溴化
铊N,N-二正丁胺
铊,甲氧基二甲基-
铂(2+)二氯化3-甲基丁烷-1,2-二胺(1:1)
铁(3+)三(1-丁醇)
铁(2+)1,1'-(硫烷二基二-1,1-乙二基)二-2,4-环戊二烯化
铀,三甲基-
钾,[三(三甲基甲硅烷基)甲基]-
钴四异硫氰酸酯
钴,乙烷-1,2-二胺
钠辛基二硫代氨基甲酸酯
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