8,8-Bis(3,7-dimethyloctyl)-4,11-dimethyl-7-oxa-3,12-dithiatricyclo[7.3.0.02,6]dodeca-1(9),2(6),4,10-tetraene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 8,8-Bis(3,7-dimethyloctyl)-4,11-dimethyl-7-oxa-3,12-dithiatricyclo[7.3.0.02,6]dodeca-1(9),2(6),4,10-tetraene
• 英文别名: 8,8-bis(3,7-dimethyloctyl)-4,11-dimethyl-7-oxa-3,12-dithiatricyclo[7.3.0.02,6]dodeca-1(9),2(6),4,10-tetraene
• 化学式: C₃₁H₅₀OS₂
• 分子量: 502.9
• InChiKey: KQTFWSWCQVPQTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  34
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  65.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• METHOD FOR PRODUCING CONJUGATED POLYMER, CONJUGATED POLYMER, PHOTOELECTRIC CONVERSION ELEMENT, SOLAR CELL, AND SOLAR CELL MODULE
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20140243488A1

  公开（公告）日：2014-08-28

  The invention addresses a problem of obtaining a conjugated polymer having a higher molecular weight through coupling reaction of monomers using a transition metal catalyst. The invention relates to a method for producing a conjugated polymer, which comprises polymerizing one or more monomers through a coupling reaction, wherein the coupling reaction of the monomer is carried out by using one or more kinds of homogeneous transition metal complex catalysts and one or more kinds of heterogeneous transition metal complex catalysts in combination.
• POLYMER COMPOUND AND ELECTRONIC DEVICE
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20140239284A1

  公开（公告）日：2014-08-28

  By using a polymer compound comprising a constituent unit represented by the formula (1) and a constituent unit represented by the formula (2) in an organic layer of an organic photoelectric conversion device, photoelectric conversion efficiency can be enhanced: wherein R 1 represents a hydrogen atom; or a substituent; Y 1 represents an oxygen atom, a sulfur atom or —N(R 3 )—; R 3 represents a hydrogen atom or a substituent; ring Z 1 and ring Z 2 represent each independently an optionally substituted aromatic carbocyclic ring or an optionally substituted heterocyclic ring; wherein R 2 is different from R 1 and represents a hydrogen atom or a substituent; Y 2 represents an oxygen atom, a sulfur atom or —N(R 3 )—; R 3 represents a hydrogen atom or a substituent; ring Z 3 and ring Z 4 represent each independently an optionally substituted aromatic carbocyclic ring or an optionally substituted heterocyclic ring.
• METHOD FOR PRODUCING CONDENSED POLYCYCLIC AROMATIC COMPOUND, AND CONJUGATED POLYMER
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20140243492A1

  公开（公告）日：2014-08-28

  The invention addresses a problem of purifying a monomer to be a precursor according to a simpler and milder method so as to obtain a polymer having a higher molecular weight. The invention relates to a method for producing a condensed polycyclic aromatic compound having n active groups (wherein n is an integer of 1 or more and 4 or less), which comprises bringing a composition containing the condensed polycyclic aromatic compound and a solvent into contact with zeolite.
• POLYMER COMPOUND AND ORGANIC PHOTOELECTRIC CONVERSION DEVICE
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20140373912A1

  公开（公告）日：2014-12-25

  A polymer compound comprising a repeating unit represented by the formula (A) and a repeating unit represented by the formula (B) manifests large absorbance of light having long wavelength, and can be used in an organic photoelectric conversion device and an organic thin film transistor. [in the formula (A) and the formula (B), R represents a hydrogen atom, a fluorine atom, an optionally substituted alkyl group, an alkoxy group optionally substituted by a fluorine atom, an aryl group, a heteroaryl group, a group represented by the formula (2a) or a group represented by the formula (2b). A plurality of R may be the same or mutually different. Ar 1 and Ar 2 represent an optionally substituted tri-valent aromatic hydrocarbon group having 6 to 60 carbon atoms or a trivalent heterocyclic group having 4 to 60 carbon atoms.].
• COMPOSITION AND ELECTRONIC DEVICE USING THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20150144200A1

  公开（公告）日：2015-05-28

  A composition comprising a first compound, a second compound and a third compound, wherein the first compound is a polymer compound having a constitutional unit represented by the formula (1), the second compound is a polymer compound having a constitutional unit represented by the formula (2) and the third compound is a compound different from the first compound and the second compound: wherein R 1 , R 2 , Y 1 , Z 1 and ring Z 2 are as defined herein, wherein R 3 , R 4 , Y 2 , Z 3 and Z 4 are as defined herein. An organic photoelectric conversion device having a first electrode and a second electrode, having an active layer between the first electrode and the second electrode, and comprising the above-described composition in the active layer.