6-phenyl-3-(4-pyridyl)-1,2,4-triazine | 64494-17-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 6-phenyl-3-(4-pyridyl)-1,2,4-triazine
• 英文别名: 6-phenyl-3-pyridin-4-yl-[1,2,4]triazine；6-phenyl-3-pyridin-4-yl-1,2,4-triazine
• CAS: 64494-17-3
• 化学式: C₁₄H₁₀N₄
• 分子量: 234.26
• InChiKey: DQHRXHWHIFYWTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-phenyl-3-(4-pyridyl)-1,2,4-triazine 、 2,5-降冰片二烯 以 xylene 为溶剂， 生成 5-苯基-2,4’-二吡啶
  参考文献：
  名称：

  An efficient route to 5-(hetero)aryl-2,4′- and 2,2′-bipyridines through readily available 3-pyridyl-1,2,4-triazines

  摘要：

  A new route to substituted bipyridines based on a new method for the synthesis of substituted 3-pyridyl-1,2,4-triazines and their aza-Diels-Alder reactions is shown to be an efficient strategy for the preparation of structurally diverse bipyridine ligands. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.01.135
• 作为产物：
  描述：

  在 溶剂黄146 作用下， 反应 0.5h， 生成 6-phenyl-3-(4-pyridyl)-1,2,4-triazine
  参考文献：
  名称：

  Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II) complexes

  摘要：

  A wide series Of Substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels-Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit 'off-on' fluorescence response toward Zn 2 cations. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.06.040