mercury dimer | 12596-25-7

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: mercury dimer
• 英文别名: mercury；Mercuriomercury
• CAS: 12596-25-7
• 化学式: Hg₂
• 分子量: 401.18
• InChiKey: KYKQHSMYWLWROM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  汞 以 gaseous matrix 为溶剂， 生成 mercury dimer
  参考文献：
  名称：

  Experimental study of the cold mercury dimer

  摘要：

  The mercury dimer is among the most weakly bound metal dimers and has been extensively studied.1 The ground state O+g dissociation energy has been considered to lie between 0.55 eV (440 cm−1) and 0.091 eV (730 cm−1). We report here a spectroscopic study of Hg2 in a supersonic jet. The first optical transition, 1u←O+g, was characterized by its fluorescence excitation spectrum and the binding energy of the ground state has been measured precisely through the threshold of collision induced dissociation of Hg2 1u to Hg(1S0)+Hg(3P0).

  DOI：

  10.1063/1.452401

文献信息

• Laser induced fluorescence (LIF) of Hg2 and Hg3 via dissociation of HgBr2 at 157 nm
  作者：C. Skordoulis、E. Sarantopoulou、S. M. Spyrou、C. Kosmidis、A. C. Cefalas

  DOI：10.1007/bf01437444

  日期：1991.6

  Laser induced fluorescence of the mercury clusters Hg2 and Hg3 in the spectral range between 300 nm to 510 nm has been obtained from the dissociation of HgBr2 at 7.88 eV (157.5 nm) with an F2 molecular laser, together with fluorescence form mercury atomic transitions from highly excited states. The excitation process involves two photon absorption which dissociates the molecule at 15.76 eV total photon energy with the subsequent formation of the metallic clusters.
• Experimental study of the cold mercury dimer
  作者：A. Zehnacker、M. C. Duval、C. Jouvet、C. Lardeux‐Dedonder、D. Solgadi、B. Soep、O. Benoist d’Azy

  DOI：10.1063/1.452401

  日期：1987.6

  The mercury dimer is among the most weakly bound metal dimers and has been extensively studied.1 The ground state O+g dissociation energy has been considered to lie between 0.55 eV (440 cm−1) and 0.091 eV (730 cm−1). We report here a spectroscopic study of Hg2 in a supersonic jet. The first optical transition, 1u←O+g, was characterized by its fluorescence excitation spectrum and the binding energy of the ground state has been measured precisely through the threshold of collision induced dissociation of Hg2 1u to Hg(1S0)+Hg(3P0).