tris(piperidino)sulfonium bifluoride | 113122-15-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: tris(piperidino)sulfonium bifluoride
• 英文别名: Tri(piperidin-1-yl)sulfanium;fluoride;hydrofluoride
• CAS: 113122-15-9
• 化学式: C₁₅H₃₀N₃S*FH*F
• 分子量: 323.494
• InChiKey: ZMKHKGDUUUVWHS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.04
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  10.7
• 氢给体数：
  1
• 氢受体数：
  5

文献信息

• [EN] POLYMERIZATION OF SILYL- AND FLUORO-CONTAINING MONOMERS<br/>[FR] POLYMÉRISATION DE MONOMÈRES CONTENANT DU FLUOR ET DU SILYLE
  申请人：SCRIPPS RESEARCH INST

  公开号：WO2016209920A1

  公开（公告）日：2016-12-29

  Condensation of fluoro-substituted and silyl-substituted monomers provides polymers suitable for use, e.g., as engineering polymers. A monomer composition is condensed in the presence of a bifluoride or poly(hydrogen fluoride) fluoride salt. The monomer composition contains a compound of formula F-X-F and a compound of formula (R1)3Si-Z-Si(R1)3, and forms an alternating X-Z polymer chain and a silyl fluoride byproduct. X has the formula -A(-R2-A)n -; each A is SO2, C(=O), or Het; R2 is an organic moiety; n is 0 or 1; Het is an aromatic nitrogen heterocycle; Z has the formula -L-R3-L-; each L is O, S, or N(R4); and each R3 is an organic moiety, and R4 comprises H or an organic moiety.

  氟取代和硅取代单体的缩聚提供了适用于工程聚合物的聚合物。在双氟化物或聚(氢氟酸)氟盐存在下缩聚单体组成物。单体组成物包含化合物F-X-F的公式和化合物(R1)3Si-Z-Si(R1)3的公式，并形成交替的X-Z聚合物链和一个硅氟化物副产物。X具有公式-A(-R2-A)n-；每个A是SO2，C(=O)或Het；R2是一个有机基团；n为0或1；Het是芳香族氮杂环；Z具有公式-L-R3-L-；每个L是O，S或N(R4)；每个R3是一个有机基团，R4包括H或一个有机基团。
• Polymerization of silyl- and fluoro-containing monomers
  申请人：The Scripps Research Institute

  公开号：US10717820B2

  公开（公告）日：2020-07-21

  Condensation of fluoro-substituted and silyl-substituted monomers provides polymers suitable for use, e.g., as engineering polymers. A monomer composition is condensed in the presence of a bifluoride or poly(hydrogen fluoride) fluoride salt. The monomer composition contains a compound of formula F-X-F and a compound of formula (R1)3Si—Z—Si(R1)3, and forms an alternating X-Z polymer chain and a silyl fluoride byproduct. X has the formula -A(-R2-A)n-; each A is SO2, C(═O), or Het; R2 is an organic moiety; n is 0 or 1; Het is an aromatic nitrogen heterocycle; Z has the formula -L-R3-L-; each L is O, S, or N(R4); and each R3 is an organic moiety, and R4 comprises H or an organic moiety.

  氟取代单体和硅取代单体的缩合可提供适用于工程聚合物等用途的聚合物。单体组合物在双氟化物或聚（氟化氢）氟化盐存在下缩合。单体组合物含有式 F-X-F 的化合物和式 (R1)3Si-Z-Si(R1)3 的化合物，并形成交替的 X-Z 聚合物链和氟化硅副产物。X具有式-A(-R2-A)n-；每个A是SO2、C(═O)或Het；R2是有机分子；n是0或1；Het是芳氮杂环；Z具有式-L-R3-L-；每个L是O、S或N(R4)；每个R3是有机分子，R4包括H或有机分子。
• Tris(dialkylamino)sulfonium bifluoride catalysts
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0121439B1

  公开（公告）日：1987-03-25
• POLYMERIZATION OF SILYL- AND FLUORO-CONTAINING MONOMERS
  申请人：The Scripps Research Institute

  公开号：EP3310795A1

  公开（公告）日：2018-04-25
• US4598161A
  申请人：——

  公开号：US4598161A

  公开（公告）日：1986-07-01