申请人:Riggs Richard
公开号:US20120097068A1
公开(公告)日:2012-04-26
Process for the preparation of modified zinc oxide nanoparticles, which comprises reacting zinc oxide nanoparticles, which are dissolved in a solvent, in the presence of ammonia or amines with a tetraalkyl orthosilicate and optionally with an organosilane, with the proviso that the reaction takes place at a content of less than 5% by weight of water, based on the total amount of solvent and water. Modified zinc oxide nanoparticles which have Si—O-alkyl groups and are soluble in organic solvents, obtainable by this process for the preparation. Liquid or solid formulations which comprise modified ZnO nanoparticles. Inanimate organic materials, for example plastics or coatings, which comprise modified ZnO nanoparticles. Method of stabilizing inanimate organic materials against the effect of light, free radicals or heat, where modified ZnO nanoparticles, which optionally comprise UV absorbers and/or stabilizers as further additives, are added to the materials.
制备改性氧化锌纳米颗粒的过程包括在溶剂中溶解的氧化锌纳米颗粒与氨或胺在场的情况下,与四烷基正硅酸酯和可选的有机硅烷反应,但反应需在溶剂和水的总量中水含量低于5%的条件下进行。通过该制备过程可获得具有Si-O-烷基基团且可溶于有机溶剂的改性氧化锌纳米颗粒。包含改性ZnO纳米颗粒的液体或固体配方。包含改性ZnO纳米颗粒的无机有机材料,例如塑料或涂料。一种稳定无机有机材料抵抗光线、自由基或热效应的方法,其中将改性ZnO纳米颗粒添加到材料中,这些纳米颗粒可包含紫外吸收剂和/或稳定剂作为进一步添加剂。