丁氧基(三甲基)锡烷 | 64109-22-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 中文名称: 丁氧基(三甲基)锡烷
• 英文名称: trimethyltin(IV) n-butoxide
• 英文别名: trimethyl-butoxytin；Butoxy(trimethyl)stannane；butoxy(trimethyl)stannane
• CAS: 64109-22-4
• 化学式: C₇H₁₈OSn
• 分子量: 236.929
• InChiKey: VLFFYXJCTVNCTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.52
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  五羰基溴化锰(I) 、 丁氧基(三甲基)锡烷 以 正己烷 为溶剂， 生成 tris(tricarbonylbutoxomanganese)
  参考文献：
  名称：

  Syntheses, structures, and reactions of trimeric and tetrameric alkoxotricarbonylmanganese complexes

  摘要：

  DOI：

  10.1039/dt9790000071

文献信息

• Wrackmeyer, Bernd; Klaus, Uwe; Milius, Wolfgang, Chemische Berichte, 1995, vol. 128, # 7, p. 679 - 688
  作者：Wrackmeyer, Bernd、Klaus, Uwe、Milius, Wolfgang

  DOI：——

  日期：——
• Stannacyclohexanes and spiro-tin compounds with s stannole or a stannolene group
  作者：Bernd Wrackmeyer、Uwe Klaus、Wolfgang Milius、Elke Klaus、Torsten Schaller

  DOI：10.1016/0022-328x(96)06162-1

  日期：1996.6

  1,1-Diethynyl-1-stannacyclohexane (5) was prepared, and its reaction with triethylborane or 9-isobutyl-9-borabicyclo[3.3.1]nonane gave the corresponding spiro-tin compounds 6 and 7 with a stannole fragment, The molecular structure of the derivative 7 was determined by X-ray analysis (triclinic, space group P (1) over bar; a = 835.2(7), b = 1117.5(2), c = 1165.6(2) pm; alpha = 72.05(3), beta = 74.32(3), gamma = 50.61(3)degrees). Treatment of 6 with trimethyltin ethoxide gave at first quantitatively the spiro-tin compound 8 with a 2-stannolene unit which rearranges upon heating into the spiro-tin compound 9 with a 3-stannolene unit, The reaction of 7 with trimethyltin butoxide gave quantitatively another tetracyclic compound 10, analogous to 8, All compounds were characterised by H-1, B-11, C-13 and Sn-119 NMR data. Numerous coupling signs (n)J((SnH)-Sn-119-H-1) and (n)J((SnC)-Sn-119-C-13) and (2)J((SnSn)-Sn-119-Sn-117) were determined by 2D(13)C/H-1 and Sn-119/H-1 heteronuclear shift correlations. Compound 7 was studied by solid-state C-13 and Sn-119 CPMAS NMR. This revealed the presence of a second crystalline phase in the bulk of the solid material, as confirmed by powder X-ray diffraction data. Sn-119 CPMAS NMR spectra of 7 show resolved scalar Sn-119-B-11 coupling ((3)J((SnB)-Sn-119-B-11) = 68 +/- 5 and 65 +/- 5 Hz).
• Syntheses, structures, and reactions of trimeric and tetrameric alkoxotricarbonylmanganese complexes
  作者：Edward W. Abel、Graham Farrow、Ian D. H. Towle

  DOI：10.1039/dt9790000071

  日期：——