2-allylphenyl 2-hydroxybenzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 2-allylphenyl 2-hydroxybenzoate
• 英文别名: (2-Prop-2-enylphenyl) 2-hydroxybenzoate
• 化学式: C₁₆H₁₄O₃
• 分子量: 254.285
• InChiKey: AESMMVBBLAPZBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-烯丙基酚 在 copper(l) iodide 、 水 、 sodium carbonate 、 caesium carbonate 、 sodium hydroxide 、 10-甲基-9-均三甲苯基吖啶高氯酸盐 作用下， 以 甲醇 、 水 、 甲苯 、 乙腈 为溶剂， 反应 44.0h， 生成 2-allylphenyl 2-hydroxybenzoate
  参考文献：
  名称：

  2-芳氧基苯甲酸的光氧化还原中性微笑微笑重排

  摘要：

  我们报告了使用可见光光氧化还原催化的2-芳氧基苯甲酸自由基Smiles重排以获得芳基水杨酸酯。该方法不含贵金属，操作简单，反应可在温和的间歇或流动条件下进行。作为氧化还原中性工艺，不需要化学计量的氧化剂或还原剂。

  DOI：

  10.1039/c7ob02579c

文献信息

• RESIN COMPOSITION
  申请人：TEIJIN LIMITED

  公开号：US20150051324A1

  公开（公告）日：2015-02-19

  A resin composition including an aromatic polyester resin and having high levels of hydrolysis resistance and moldability is provided. The resin composition includes an aromatic polyester resin having a terminal carboxyl group content of not more than 30 eq/ton (component A), a cyclic carbodiimide compound having at least two carbodiimide rings, each having only one carbodiimide group (component B), and a polyvalent hydroxyl group-containing compound having a hydroxyl value of not less than 200 (component C).

  提供了一种含有芳香族聚酯树脂的树脂组合物，具有高水解抗性和成型性。该树脂组合物包括具有终端羧基含量不超过30eq/吨的芳香族聚酯树脂（组分A）、至少具有两个仅含有一个羧酸二亚胺基团的羧酸二亚胺环的环状羧酸二亚胺化合物（组分B）和具有不少于200的羟基值的多价羟基含有化合物（组分C）。
• RESIN COMPOSITION AND MOLDED ARTICLE FILM AND FIBER EACH COMPRISING THE SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1445282A1

  公开（公告）日：2004-08-11

  Disclosed are a resin composition comprising a polylactic acid resin and a polyacetal resin, and such a resin composition in which the polylactic acid resin and the polyacetal resin are kept miscible with each other. The resin composition has good moldability, workability, mechanical properties, heat resistance and transparency, and may be worked into moldings, films and fibers for practical use.

  本发明公开了一种由聚乳酸树脂和聚缩醛树脂组成的树脂组合物，以及聚乳酸树脂和聚缩醛树脂保持互溶的树脂组合物。该树脂组合物具有良好的成型性、加工性、机械性能、耐热性和透明性，可加工成模塑件、薄膜和纤维以供实际使用。
• RESIN COMPOSITION, METHOD FOR PRODUCING THE SAME AND MOLDED ARTICLE
  申请人：TEIJIN LIMITED

  公开号：EP2053091A1

  公开（公告）日：2009-04-29

  To provide a resin composition having high heat resistance with a high melting point and excellent melt stability and hydrolysis resistance, a molded article of the resin composition and a method of manufacturing the resin composition; the resin composition comprises an aromatic polyester (component A) having a butylene terephthalate skeleton as the main constituent unit and polylactic acid (component B) having a melting point of 190°C or higher.

  提供一种具有高熔点、高耐热性、优异的熔融稳定性和耐水解性的树脂组合物、一种由该树脂组合物制成的模塑制品以及一种制造该树脂组合物的方法；该树脂组合物由具有对苯二甲酸丁二醇酯骨架作为主要组成单元的芳香族聚酯（A 组分）和熔点为 190°C 或更高的聚乳酸（B 组分）组成。
• POLYLACTIC ACID COMPOSITION
  申请人：Teijin Limited

  公开号：EP2116576A1

  公开（公告）日：2009-11-11

  It is an object of the present invention to provide a polylactic acid composition having excellent crystallinity, wet heat stability and melt stability. It is another object of the present invention to provide a molded article which is obtained from the polylactic acid composition and excellent in appearance and color. The present invention is a composition and molded article thereof which comprises a polylactic acid (component A), a carbodiimide compound (component B) and a phosphoric acid ester metal salt (component C).

  本发明的一个目的是提供一种具有优异结晶度、湿热稳定性和熔融稳定性的聚乳酸组合物。本发明的另一个目的是提供一种由该聚乳酸组合物制成的模塑制品，其外观和色泽极佳。 本发明是一种由聚乳酸（A 组分）、碳化二亚胺化合物（B 组分）和磷酸酯金属盐（C 组分）组成的组合物及其成型品。
• POLYLACTIC ACID COMPOSITIONS AND MOLDED ARTICLES THEREOF
  申请人：Teijin Chemicals, Ltd.

  公开号：EP2351792A1

  公开（公告）日：2011-08-03

  A composition comprising polylactic acid and having excellent heat stability, especially moist heat stability, and a molded article thereof. The composition comprises 100 parts by weight of a resin component (component A) which is composed of 5 to 100 wt% of polylactic acid (component A-α) and 95 to 0 wt% of a thermoplastic resin (component A-β), 0.001 to 5 parts by weight of a phosphono-fatty acid ester (component B), 0.01 to 5 parts by weight of a phosphate metal salt (component C), 0.001 to 2 parts by weight of at least one antioxidant (component D) selected from the group consisting of a phosphite-based compound, a phosphonite-based compound, a hindered phenol-based compound and a thioether-based compound, and 0.001 to 10 parts by weight of an end-sealing agent (component E).

  一种包含聚乳酸且具有优异热稳定性（尤其是湿热稳定性）的组合物及其模塑制品。 该组合物包括 100 重量份的树脂组分（A 组分），它由 5 至 100 重量份的聚乳酸（A-α 组分）和 95 至 0 重量份的热塑性树脂（A-β 组分）组成；0.001 至 5 重量份的膦酰脂肪酸酯（B 组分）；0.01 至 5 重量份的磷酸盐金属盐（C 组分）；0.001 至 2 份（按重量计）至少一种抗氧化剂（组分 D），该抗氧化剂选自亚磷酸基化合物、亚磷酸基化合物、受阻酚基化合物和硫醚基化合物组成的组，以及 0.001 至 10 份（按重量计）端封剂（组分 E）。