乙烯基-二羟基-甲基硅烷 | 3959-12-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 乙烯基-二羟基-甲基硅烷
• 英文名称: methylvinyldihydroxysilane
• 英文别名: methylvinylsilanediol；methyl-vinyl-silanediol；Methyl-vinyl-silandiol；Methylvinylsilandiol；ethenyl-dihydroxy-methylsilane
• CAS: 3959-12-4
• 化学式: C₃H₈O₂Si
• 分子量: 104.181
• InChiKey: JMTARFYECDNZGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.23
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  乙烯基-二羟基-甲基硅烷 、 1,2-二(甲基二氯硅基)乙烷 在 吡啶 作用下， 以 乙醚 为溶剂， 以38%的产率得到1,3,5,7-tetramethyl-3,7-divinylbicyclo<3.2.3>1,3,5,7-tetrasila-2,4,6,8-oxane
  参考文献：
  名称：

  Synthesis and nmr spectra of organobicyclosiloxanes with an ethylene bridge

  摘要：

  DOI：

  10.1007/bf00965378
• 作为产物：
  描述：

  甲基乙烯基二氯硅烷 在 水 、 三乙胺 作用下， 以 乙醚 、 丙酮 为溶剂， 反应 0.5h， 生成 乙烯基-二羟基-甲基硅烷
  参考文献：
  名称：

  Procedures for the preparation of silanols

  摘要：

  Two procedures are described for the preparation of silanols and silanediols from the corresponding chlorosilanes. The first procedure, a two-phase hydrolysis-extraction process, is particularly convenient and suited to the preparation of a wide range of mono-silanols. Hydrolysis of dichlorosilanes by this procedure gives varied results depending on the structure of the dichlorosilane and specific reaction conditions. The second procedure, a modification of a published procedure, is especially beneficial for the preparation of silanols and silanediols prone to undergo self-condensation.

  DOI：

  10.1016/0022-328x(94)87098-5

文献信息

• Momonoi; Suzuki, Nippon Kagaku Zasshi, 1957, vol. 78, p. 1324
  作者：Momonoi、Suzuki

  DOI：——

  日期：——
• ZHDANOV, A. A.;ASTAPOVA, T. V.;LAVRUXIN, B. D., IZV. AN CCCP. CEP. XIM.,(1988) N 3, 657-662
  作者：ZHDANOV, A. A.、ASTAPOVA, T. V.、LAVRUXIN, B. D.

  DOI：——

  日期：——
• Procedures for the preparation of silanols
  作者：James A. Cella、John C. Carpenter

  DOI：10.1016/0022-328x(94)87098-5

  日期：1994.10

  Two procedures are described for the preparation of silanols and silanediols from the corresponding chlorosilanes. The first procedure, a two-phase hydrolysis-extraction process, is particularly convenient and suited to the preparation of a wide range of mono-silanols. Hydrolysis of dichlorosilanes by this procedure gives varied results depending on the structure of the dichlorosilane and specific reaction conditions. The second procedure, a modification of a published procedure, is especially beneficial for the preparation of silanols and silanediols prone to undergo self-condensation.
• Synthesis and nmr spectra of organobicyclosiloxanes with an ethylene bridge
  作者：A. A. Zhdanov、T. V. Astapova、B. D. Lavrukhin

  DOI：10.1007/bf00965378

  日期：1988.3