zirconium nitrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: zirconium nitrate
• 英文别名: zirconium(II) nitrate；Zirconium(2+);nitrate
• 化学式: 2NO₃*Zr
• 分子量: 215.234
• InChiKey: DAZMGDVCVSKUTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.24
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  62.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  zirconium nitrate 以 水 为溶剂， 生成 zirconia
  参考文献：
  名称：

  Synthesis of ceramic oxide powders by microwave plasma pyrolysis

  摘要：

  Ceramic powders prepared pyrolytically exhibit homogeneity and, in most cases, small grain sizes. The energy efficiency of electrically heated systems performing the pyrolysis in a stream of carrier gas is poor. Similar considerations concerning energy demand are valid for spray drying of suspensions. This situation can be improved using a microwave plasma as a source for thermal energy. The process described in this paper works with any aqueous solution of salts used as starting material in ceramics. The process was demonstrated by the synthesis of alumina, zirconia, and zirconia-based ceramic powders; where an energy efficiency of more than 80% was found. For the powder synthesis, aqueous solutions of the nitrates were used as starting materials. Through proper selection of conditions for synthesis, it is possible to obtain nanocrystalline powders, as demonstrated by electron microscopy. Because of the extreme conditions associated with plasma during synthesis, it is possible to prepare non-equilibrium structures and solid solutions in systems in which nearly no equilibrium solubility exists.

  DOI：

  10.1007/bf00365205
• 作为试剂：
  描述：

  乙基苯 在 zirconium nitrate 、 氢溴酸 、 cobalt(II) acetate 、 manganese(II) acetate 、 溶剂黄146 作用下， 130.0 ℃ 、3.0 MPa 条件下， 生成 苯乙酮 、 苯甲酸
  参考文献：
  名称：

  벤조산의 제조 방법

  摘要：

  本发明涉及一种制备苯甲酸的方法，其中涉及含有钴、锰和溴的复合催化剂和锆化合物存在的情况下，包括将乙基苯氧化反应的步骤。

  公开号：

  KR20150123039A

文献信息

• Polyoxometalates as bifunctional templates: engineering metal oxides with mesopores and reactive surfaces for catalysis
  作者：Yan Leng、Jixing Liu、Zihao Zhang、Hao Chen、Pengfei Zhang、Sheng Dai

  DOI：10.1039/c9ta09614k

  日期：——

  between metal salts and POMs, metal precursors undergo pyrolysis around large POM clusters, which can incorporate abundant mesopores into metal oxides (e.g., Co3O4, Fe3O4, NiO, La2O3, MnO2, CeO2, ZrO2, and CuO) with ultrahigh specific surface areas (up to 210 m2 g−1) after simply being recycled by water washing. Unexpectedly, the oxidative feature of POMs naturally contributes to the formation of high valence

  具有优化的孔隙率和活性表面的中孔金属氧化物通常在许多应用中表现出出乎意料的性能。然而，通常需要牺牲模板和复杂的过程来产生中孔。在本文中，我们发现了多金属氧酸盐（POM）的双功能模板人才，不仅可以在金属氧化物中生成中孔，而且还可以生成反应性表面，并且据报道，这种方法简便，可回收且通用。通过金属盐和POM之间的机械化学离子共享，金属前体在大型POM簇周围进行热解，这会将大量的中孔掺入金属氧化物（例如Co 3 O 4，Fe 3 O 4，NiO，La 2 O 3只需通过水洗即可回收，具有超高比表面积（最大210 m 2 g -1）的MnO 2，MnO 2，CeO 2，ZrO 2和CuO 。出乎意料的是，POM的氧化特性自然会导致在材料表面形成高价金属阳离子。作为一个例子，将Co 3 ö 4与两个孔和富集的表面钴样品3+物种比Co更活跃3 ö 4从氧化硅模板衍生（Ť 100 = 200℃）和商业有限公司3
• A novel cobalt-free cathode with triple-conduction for proton-conducting solid oxide fuel cells with unprecedented performance
  作者：Yunpeng Xia、Zongzi Jin、Huiqiang Wang、Zheng Gong、Huanlin Lv、Ranran Peng、Wei Liu、Lei Bi

  DOI：10.1039/c9ta02449b

  日期：——

  Bi and Sn co-doped perovskite BaFe0.8−XSn0.2BiXO3−δ materials have been designed and characterized as a series of new cathodes for proton-conducting solid oxide fuel cells (SOFCs), providing a new life for the traditional BaFeO3-based cathodes. Proton uptake of the cathode increases significantly with bismuth-doping, favoring the application of Bi and Sn co-doped perovskite BaFe0.8−XSn0.2BiXO3−δ materials

  Bi和Sn共掺杂钙钛矿BaFe 0.8− X Sn 0.2 Bi X O 3− δ材料的设计和表征是一系列用于质子传导固体氧化物燃料电池（SOFC）的新型阴极，为传统的传统燃料提供了新的寿命BaFeO 3基阴极。的铋掺杂显著阴极增加质子吸收，有利于Bi和Sn的共掺杂的钙钛矿钡铁氧体的应用0.8- X的Sn 0.2 BiXO 3- δ质子传导SOFC中的材料。密度泛函理论（DFT）的计算还表明，铋掺杂导致BFS材料的水合能急剧增加，质子迁移加速。XPS结果表明，添加铋后，阴极的氧还原反应（ORR）活性增强，这与单电池功率密度的实验结果一致。NiO-BaZr 0.1 Ce 0.7 Y 0.2 O 3− δ | BaZr 0.1 Ce 0.7 Y 0.2 O 3− δ | NiO-BaZr 0.1 Ce 0.7 Y 0.2 O 3− δ结构的单电池的最大功率密度| 钡铁0.5锡0.2Bi 0.3
• Synthesis and Characterization of Complexes of Glipizide with Zirconium and Cobalt
  作者：NEETI RATHORE、BAL KISHAN

  DOI：10.13005/ojc/290320

  日期：2013.9.30

  oxo3pyrroline1carboxamido)ethyl]phenyl]sulphonyl]-3(trans-4-methylcyclohexayl)urea the recently used hypoglycaemic agent is active in NIDDM. Metal complexes of Glipizide have been synthesized by reaction with different metals such asZirconium and Cobalt in the form of their nitrate and chloride salts repectively. Thereafter these were characterized by their physical and analytical data, IR, NMR, electronic

  格列吡嗪1-[[[p- [2-（3-乙基4甲基2oxo3吡咯啉]羧酰胺基）乙基]苯基]磺酰基] -3（反式-4-甲基环己基）脲是最近在NIDDM中具有活性的降血糖剂。格列吡嗪的金属络合物已经通过与不同的金属（例如锆和钴）分别以其硝酸盐和氯化物盐的形式反应而合成。此后，通过它们的物理和分析数据，IR，NMR，电子光谱，质谱和X射线衍射分析对其进行表征。
• Molodetsky, Irina; Navrotsky, Alexandra; Lajavardi, Manoucher, Zeitschrift für Physikalische Chemie, <hi>1998</hi>, vol. 207, # 1-2, p. 59 - 65
  作者：Molodetsky, Irina、Navrotsky, Alexandra、Lajavardi, Manoucher、Brune, Alicia

  DOI：——

  日期：——