二(2-氯乙基)磷酸氢酯 | 3040-56-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 二(2-氯乙基)磷酸氢酯
• 中文别名: 4,6-二壬基-o-甲苯酚
• 英文名称: bis(2-chloroethyl) phosphate
• 英文别名: O,O-Bis(β,β'-chloraethyl)-phosphit；phosphoric acid bis-(2-chloro-ethyl) ester；Phosphorsaeure-bis-(2-chlor-aethylester)；Bis-(2-chlor-aethyl)-phosphat；bis(2-chloroethyl) hydrogen phosphate
• CAS: 3040-56-0
• 化学式: C₄H₉Cl₂O₄P
• 分子量: 222.993
• InChiKey: PMGHIGLOERPWGC-UHFFFAOYSA-N

物化性质

• 沸点：
  301.8±52.0 °C(Predicted)
• 密度：
  1.469±0.06 g/cm3(Predicted)
• 溶解度：
  氯仿（微溶）、乙酸乙酯（微溶）、甲醇（微溶）

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2919900090

反应信息

• 作为反应物：
  描述：

  3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环 、 二(2-氯乙基)磷酸氢酯 以 氘代氯仿 为溶剂， 以28%的产率得到C₅H₈Cl₂F₃O₄P
  参考文献：
  名称：

  亲电性高价碘三氟甲基化试剂与磷酸氢盐的反应机理

  摘要：

  用拟一级装置确定的初始速率和随后的塔夫脱（Taft）分析法研究了用试剂三氟甲基-1,3-二氢-3，3-二甲基-1,2-苯并恶唑（1）对磷酸氢的亲电三氟甲基化反应。计算的相对比率。对于整个数据集，发现了一个正极性灵敏度因子，表明在速率确定步骤中形成了负电荷。

  DOI：

  10.1016/j.jfluchem.2011.08.014
• 作为产物：
  描述：

  二(2-氯乙基)氯磷酸酯 在 sodium hydroxide 作用下， 以 四氢呋喃 、 水 为溶剂， 以70%的产率得到二(2-氯乙基)磷酸氢酯
  参考文献：
  名称：

  亲电性高价碘三氟甲基化试剂与磷酸氢盐的反应机理

  摘要：

  用拟一级装置确定的初始速率和随后的塔夫脱（Taft）分析法研究了用试剂三氟甲基-1,3-二氢-3，3-二甲基-1,2-苯并恶唑（1）对磷酸氢的亲电三氟甲基化反应。计算的相对比率。对于整个数据集，发现了一个正极性灵敏度因子，表明在速率确定步骤中形成了负电荷。

  DOI：

  10.1016/j.jfluchem.2011.08.014

文献信息

• Intumescent composition
  申请人：GREAT LAKES CHEMICAL CORPORATION

  公开号：EP0008939A2

  公开（公告）日：1980-03-19

  There is disclosed an intumescent composition. The applicants disclose such compositions which impart durable flame retardancy to wood, which compositions comprise a cyclic nitrogen compound, a hydroxy-containing organo-phosphorus compound, and organo-phosphorus acid, and water, wherein: a) said cyclic nitrogen compound is wherein a, b, and c are integers selected from the group consisting of 1 and 2, a plus b plus c equal about 3 to 6, and X, X', and X" are independently selected from the group consisting of hydrogen and -CH3; b) said hydroxy-containing organo-phosphorus compound is selected from the group consisting of and and mixtures thereof, wherein d is an integer of from 0 to 2, e is an integer of from 0 to 2, f is an integer of from 1 to 3, and d plus e plus f equal 3; z is an integer of 0 to 1; x is an integer of 1 to 2, y is an integer of 1 to 2, and x plus y plus z eqal 3; R R2, and R3 are selected from the group consisting of alkyl radicals containing from about 1 to about 6 carbon atoms and haloalkyl radicals containing from about 2 to about 6 carbon atoms, provided that when R3 is haloalkyl it contains at least 3 carbon atoms; R4 and R5 are selected from the group consisting of hydrogen, alkyl radicals, and haloalkyl radicals, wherein said radicals contain from about 1 to about 6 carbon atoms; and the total number of carbon atoms in the R1, R2, R3, R4, and R5 groups does not exceed about 14; and c) said acid is selected from the group consisting of and mixtures thereof, wherein R6, R7, R8 and R9 are independently selected from the group consisting of hydrogen, alkyl of from about 1 to about 3 carbon atoms, haloalkyl of from about 1 to about 3 carbon atoms, and hydroxyalkyl of from 1 to about 3 carbon atoms, provided that the total number of carbon atoms in the R6, R7, R°, and R9 groups does not exceed about 5; wherein q is an integer of from 1 to 2, h and i are integers independently selected from the group consisting of 0, 1, and 2, and g plus h plus i equals 3; and wherein R'° and R" are independently selected from the group consisting of alkyl of from about 1 to about 6 carbon atoms, haloalkyl of from about 1 to about 6 carbons atoms and from 1 to about 3 halogen atoms, hydroxy-polyalkyleneoxy containing 2 to 6 carbon atoms and 2 to 6 oxygen atoms, alkoxy of from about 1 to about 6 carbon atoms, hydroxyalkoxy of from about 2 to about 6 carbon atoms, haloalkoxy of from about 2 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, wherein R12 is selected from the group consisting of alkylene of from about 2 to about 6 carbon atoms, haloalkylene of from about 3 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, polyalkyleneoxy containing 2 to 6 carbon atoms and 1 to 5 oxygen atoms, and hydroxyalkylene of from 3 to about 6 carbon atoms and 1 to 4 hydroxyls, and R13 and R14 are independently selected from the group consisting of hydrogen, hydroxyl, alkyl of from about 1 to about 6 carbon atoms, haloalkyl of from about 1 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, hydroxy-polyalkyleneoxy containing about 2 to about 6 carbon atoms and 2 to 6 oxygen atoms, alkoxy of from about 1 to about 6 carbon atoms, hydroxyalkoxy of from about 2 to about 6 carbon atoms, and haloalkoxy of from about 2 to about 6 carbon atoms and 1 to about 3 halogen atoms, provided that the total number of carbon atoms in the R'° and R11 groups does not exceed about 8.

  本发明公开了一种膨胀剂组合物。申请人公开了这种能赋予木材持久阻燃性的组合物，该组合物由环状氮化合物、含羟基的有机磷化合物、有机磷酸和水组成，其中： a) 所述环状氮化合物为 其中 a、b 和 c 是选自 1 和 2 的整数，a 加 b 加 c 约等于 3 至 6，X、X'和 X "独立地选自氢和-CH3 组成的组； b) 所述含羟基的有机磷化合物选自由下列物质组成的组 和 及其混合物，其中 d 是 0 至 2 的整数，e 是 0 至 2 的整数，f 是 1 至 3 的整数，d 加 e 加 f 等于 3；z 是 0 至 1 的整数；x 是 1 至 2 的整数，y 是 1 至 2 的整数，x 加 y 加 z 等于 3；R R2 和 R3 选自由含约 1 至约 6 个碳原子的烷基和含约 2 至约 6 个碳原子的卤代烷基组成的组，但 R3 为卤代烷基时至少含 3 个碳原子；R4 和 R5 选自由氢、烷基和卤代烷基组成的组，其中所述基含有约 1 至约 6 个碳原子；且 R1、R2、R3、R4 和 R5 基团中的碳原子总数不超过约 14 个；以及 c) 所述酸选自以下组成的组 及其混合物，其中 R6、R7、R8 和 R9 独立地选自氢、约 1 至约 3 个碳原子的烷基、约 1 至约 3 个碳原子的卤代烷基和 1 至约 3 个碳原子的羟烷基组成的组，条件是 R6、R7、R° 和 R9 基团中的碳原子总数不超过约 5；其中 q 是 1 至 2 的整数，h 和 i 是独立选自 0、1 和 2 的整数，且 g 加 h 加 i 等于 3；其中 R'° 和 R "独立地选自由约 1 至约 6 个碳原子的烷基、约 1 至约 6 个碳原子和 1 至约 3 个卤素原子的卤代烷基、含 2 至 6 个碳原子和 2 至 6 个氧原子的羟基聚烯氧基、约 1 至约 6 个碳原子的烷氧基、约 2 至约 6 个碳原子的羟基烷氧基、约 2 至约 6 个碳原子和约 1 至约 3 个卤素原子的卤代烷氧基组成的组、 其中 R12 选自由约 2 至约 6 个碳原子的亚烷基、约 3 至约 6 个碳原子和约 1 至约 3 个卤素原子的卤代亚烷基、含 2 至 6 个碳原子和 1 至 5 个氧原子的聚亚烷氧基以及含 3 至约 6 个碳原子和 1 至 4 个羟基的羟基亚烷基组成的组，而 R13 和 R14 独立地选自由氢、羟基、约 1 至约 6 个碳原子的烷基、约 1 至约 3 个卤素原子的卤代烷基、约 2 至约 6 个碳原子的羟基烷氧基、约 2 至约 6 个碳原子的卤代烷氧基、约 2 至约 6 个碳原子的卤代烷氧基和约 1 至约 3 个卤素原子组成的组、约 1 至约 6 个碳原子和约 1 至约 3 个卤素原子的卤代烷基、含有约 2 至约 6 个碳原子和 2 至 6 个氧原子的羟基聚亚烷氧基、约 1 至约 6 个碳原子的烷氧基、约 2 至约 6 个碳原子的羟基烷氧基和约 2 至约 6 个碳原子和 1 至约 3 个卤素原子的卤代烷氧基，条件是 R'° 和 R11 基团中的碳原子总数不超过约 8 个。
• Process for preparing a Methacrylic resin composition having a high solar radiant energy absorbing property
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0019097A1

  公开（公告）日：1980-11-26

  An organic compound (A) containing cupric ion and a compound (B) having at least one P-O-H bond in a molecule are contained into the methacrylic resin selected from poly(methyl methacrylate) or methacrylic polymers containing at least 50% by weight of a methyl methacrylate unit.

  将含有铜离子的有机化合物 (A) 和分子中至少有一个 P-O-H 键的化合物 (B) 加入甲基丙烯酸树脂中，该树脂选自聚甲基丙烯酸甲酯或甲基丙烯酸聚合物，其中甲基丙烯酸甲酯单元的重量至少占 50%。
• Process for preparing scorch inhibited polyurethane foam and polyurethane foam thus obtained
  申请人：OLIN CORPORATION

  公开号：EP0024791A1

  公开（公告）日：1981-03-11

  Polyurethane foam formulations containing halogenated phosphate ester additives are inhibited against scorching through the use of an effective amount of 4,4'-bis(a, α-dimethylbenryl)diphenylamine.

  通过使用有效量的 4,4'-双（a, α-二甲基苯乙烯基）二苯胺，可抑制含有卤化磷酸酯添加剂的聚氨酯泡沫配方的焦烧。
• Polyester polyurethane foam based medical support pad
  申请人：AKZO N.V.

  公开号：EP0153790A2

  公开（公告）日：1985-09-04

  A polyester polyurethane foam formulation useful in medical pads to support bedridden patients is described. The foam is formed by reaction of a polyester polyol, isocyanate and blowing agent combination of water and halogenated hydrocarbon auxiliary blowing agent. A halogenated flame retardant, e.g., an organophosphorus compound, is present. A liquid char forming and dripping ember retardant additive is also present.

  本文介绍了一种聚酯聚氨酯泡沫配方，可用于支撑卧床病人的医用垫。该泡沫由聚酯多元醇、异氰酸酯和水与卤代烃辅助发泡剂的发泡剂组合反应形成。其中含有卤化阻燃剂，如有机磷化合物。还含有一种液态炭形成和滴落微光阻燃添加剂。
• Heat laminatable polyether urethane foam
  申请人：AKZO N.V.

  公开号：EP0189644A2

  公开（公告）日：1986-08-06

  Polyether urethane foams that are heat laminatable are prepared by incorporating within the foam an effective amount of an organophosphorus additive. This organophosphorus additive can be an organophosphite, an organophosphonate, an organophosphate, and a mixture thereof. This foam can also include an halogenated flame retardant.

  可加热层压的聚醚聚氨酯泡沫是通过在泡沫中加入有效量的有机磷添加剂来制备的。这种有机磷添加剂可以是有机亚磷酸酯、有机膦酸盐、有机磷酸酯及其混合物。这种泡沫还可以包括卤化阻燃剂。