二(4-叔-丁基苯基)磷酸氢酯 | 21150-89-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 二(4-叔-丁基苯基)磷酸氢酯
• 英文名称: bis(4-tert-butylphenyl)phosphoric acid
• 英文别名: bis(p-tert-butylphenyl) hydrogen phosphate；Bis(4-tert-butylphenyl) hydrogen phosphate
• CAS: 21150-89-0
• 化学式: C₂₀H₂₇O₄P
• 分子量: 362.406
• InChiKey: NMZURFAPYNEBQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二(4-叔-丁基苯基)磷酸氢酯 、 neodymium(III) nitrate 在 potassium hydroxide 作用下， 以 水 为溶剂， 反应 4.0h， 以98%的产率得到neodymium tris[bis(4-tert-butylphenyl)phosphate]
  参考文献：
  名称：

  Neodymium tris-diarylphosphates: Systematic study of the structure–reactivity relationship in butadiene and isoprene polymerisation

  摘要：

  The catalytic properties of neodymium tris-phosphates with various diarylphosphate ligands in the stereoregular 1,4-cis-polymerisation of butadiene and isoprene were studied. The considerable variability of the diaryl phosphate structure allowed for the systematic investigation of the dependence of the catalytic properties of neodymium tris-diarylphosphates on the electronic and steric properties of the ligand. Electron-withdrawing substituents (F, Cl, Br) in the aryl moiety increased the catalyst activity of tris-diarylphosphate. Neodymium aryl phosphates containing lipophilic bulky ligands provided the synthesis of polydienes with a monomodal molecular-weight distribution. The optimal catalytic properties demonstrated that the neodymium aryl phosphate prepared from bis(2,6-dimethy1-4-tert-butylpheny1)phosphoric acid showed high activity and ensured a monomodal MWD of polydienes (M-w/M-n similar to 2 for polybutadiene and M-w/M-n similar to 3 for polyisoprene) in various conditions. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2014.04.007
• 作为产物：
  描述：

  4-叔丁基苯酚 在 三甲胺 、 三氯氧磷 、 水 作用下， 以 丙酮 为溶剂， 以Ca. 41.7 %的产率得到二(4-叔-丁基苯基)磷酸氢酯
  参考文献：
  名称：

  优先萃取铪锆的新型磷酸酯萃取剂及其机理

  摘要：

  核级锆和铪在核工业中发挥着重要作用。由于镧系元素收缩导致锆和铪具有相似的性质，因此分离和纯化锆和铪非常困难，并且优先提取铪具有挑战性。本工作合成了一种新型萃取剂磷酸二(对叔丁基苯基)酯(DTBPPA)，并评价了其在硫酸体系中锆和铪的分离性能。在相同的萃取条件下，与目前的商业萃取剂（例如 D2EHPA 和 PC88A）相比，DTBPPA 对铪表现出优异的优先萃取特性。 SF Hf/Zr值最高可达16.3。生长了铪萃取物的晶体，研究了铪的萃取机理和优先萃取原理。结果发现，在相同条件下，提取锆的物质的晶体生长很困难。铪提取物晶体揭示了与六个提取剂分子结合的六配位铪离子。芳香族取代基的吸电子效应导致新型萃取剂P-O基团中O原子的电子密度较低，萃取剂配位基团表现出软碱的特征。这与铪离子的软酸性质相匹配。 DTBPPA表现出很强的识别铪离子的能力，从而实现从锆和铪混合物中优先分离铪。

  DOI：

  10.1039/d4nj00830h

文献信息

• Noncovalent Modification Strategy with Achiral Phosphoric Acid Diesters for Designing a Chiral Brønsted Base Organocatalyst
  作者：Momoko Hara、Aya Ogawa、Keiji Minagawa、Yasushi Imada、Yukihiro Arakawa

  DOI：10.1246/bcsj.20210462

  日期：2022.4.15

  A strategy for designing chiral Brønsted base organocatalysts through noncovalent modification of a chiral dibasic molecule with an achiral phosphoric acid diester is introduced for the first time. Such a molecular modification concept utilizing acid-base interactions may facilitate the on-demand design of asymmetric organocatalysts, as preliminarily demonstrated in this work.

  首次介绍了一种通过用非手性磷酸二酯对手性二元分子进行非共价修饰来设计手性 Brønsted 碱有机催化剂的策略。这种利用酸碱相互作用的分子修饰概念可以促进不对称有机催化剂的按需设计，正如这项工作中初步证明的那样。
• Adhesive sheet for dicing
  申请人：——

  公开号：US20030031862A1

  公开（公告）日：2003-02-13

  An adhesive sheet for dicing comprising a base film provided at least one surface thereof with an adhesive layer, wherein the base film comprises an olefinic thermoplastic elastomer comprising propylene and ethylene and/or &agr;-olefin including 4 to 8 carbon atoms as polymerization components, and the peak melting temperature of the olefinic thermoplastic elastomer is 120° C. or more, is free of economical disadvantages with less reduction in the quality level of products and less generation of fibrous off-cuts during dicing. In particular, fibrous off-cuts occur less during dicing when the base film contains a crystal-nucleating agent. Further, generation of chippings during dicing can be prevented by incorporation of an ethylene series polymer into the base film.

  一种用于切割的粘合片，包括至少一表面带有粘合层的基膜，其中基膜包括丙烯和乙烯和/或α-烯烃（4-8个碳原子）作为聚合组分的烯烃热塑性弹性体，且烯烃热塑性弹性体的峰值熔点为120℃或更高，不会产生经济上的不利影响，同时产品质量水平降低和切割过程中纤维碎屑的生成较少。特别是，在基膜中含有结晶成核剂时，切割过程中的纤维碎屑会更少。此外，通过将乙烯系聚合物并入基膜中，可以防止切割过程中产生切屑。
• Synthesis of diaryl phosphates using orthophosphoric acid as a phosphorus source
  作者：Cong Chi Tran、Kazuya Asao、Takeshi Sasaki、Yasuyuki Hayakawa、Shin-ichi Kawaguchi

  DOI：10.1016/j.tetlet.2022.153726

  日期：2022.4

  This paper presents a new synthetic route for diaryl phosphate esters, which are traditionally synthesized from phosphorus oxychloride. Specifically, we report the synthesis of diaryl phosphates by the dehydrative condensation of orthophosphoric acid, a phosphorus source, with aromatic alcohols.

  本文提出了一种新的磷酸二芳基酯合成路线，该路线传统上由三氯氧磷合成。具体来说，我们报道了通过正磷酸（一种磷源）与芳香醇的脱水缩合合成磷酸二芳基酯。
• Method for producing an antibacterial molded article of polyolefin resin
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0423604A1

  公开（公告）日：1991-04-24

  A method for producing an antibacterial molded article of polyolefin resin is described, comprising molding a polyolefin resin composition having compounded therewith 0.01% by weight or more, based on the polyolefin resin composition, of an antibacterial agent containing silver to form a molded article of a desired shape, and thereafter subjecting the antibacterial surface of the molded article to a corona discharge treatment

  描述了一种生产聚烯烃树脂抗菌模塑制品的方法，该方法包括模塑聚烯烃树脂组合物，在聚烯烃树脂组合物中加入重量百分比为 0.01% 或更多的含银抗菌剂，以形成所需形状的模塑制品，然后对模塑制品的抗菌表面进行电晕放电处理。
• Impact resistant graft copolymers
  申请人：Himont Incorporated

  公开号：EP0522233A1

  公开（公告）日：1993-01-13

  Disclosed are graft copolymers comprising a propylene polymer material backbone grafted with a mixture of at least two different copolymerizable monomers having improved impact resistance without decrease in clarity.

  所公开的接枝共聚物包含丙烯聚合物材料主链与至少两种不同的可共聚单体混合物的接枝，具有更好的抗冲击性，且透明度不会降低。