二(4-叔-丁基苯基)苯基磷酸酯 | 115-87-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 二(4-叔-丁基苯基)苯基磷酸酯
• 中文别名: 双(叔丁基苯基)苯基磷酸酯
• 英文名称: bis(p-tert-butylphenyl) phenyl phosphate
• 英文别名: di(p-tert-butylphenyl) phenyl phosphate；phosphoric acid bis-(4-tert-butyl-phenyl ester)-phenyl ester；Phosphorsaeure-bis-(4-tert-butyl-phenylester)-phenylester；Phenyl-bis-(4-tert.-butyl-phenyl)-phosphat；phosphoric acid, bis[4-(1,1-dimethylethyl)phenyl] phenyl ester；bis(4-tert-butylphenyl) phenyl phosphate
• CAS: 115-87-7
• 化学式: C₂₆H₃₁O₄P
• 分子量: 438.504
• InChiKey: PDLPMCXGPIVYQQ-UHFFFAOYSA-N

物化性质

• 溶解度：
  可溶于乙酸乙酯（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2919900090

反应信息

• 作为反应物：
  描述：

  磷酸三苯酯 、 二(4-叔-丁基苯基)苯基磷酸酯 在 potassium carbonate 作用下， 130.0~220.0 ℃ 、1.33 kPa 条件下， 生成 1-二苯氧基磷酰氧基-4-叔丁基苯
  参考文献：
  名称：

  Preparation of Flame-Resistant Liquids Based on Mixed Tri(phenyl, p-tert-butylphenyl) Phosphates by Transesterification of Triphenyl Phosphate with p-tert-Butylphenol

  摘要：

  The possibility of controlling the composition of a mixture of triphenyl phosphate, p-tert-butylphenyl diphenyl phosphate, di(p-tert-butylphenyl)phenyl phosphate, and tri(p-tert-butylphenyl) phosphate, formed by transesterification of triphenyl phosphate withp-tert-butylphenol, was demonstrated. The amount ofp-tert-butylphenol necessary for transesterification of triphenyl phosphate to yield a mixture of phosphates of required composition was determined. If necessary, the composition of the phosphates can be adjusted by selective distillation of triphenyl phosphate in a vacuum.

  DOI：

  10.1134/s1070427220080170
• 作为产物：
  描述：

  磷酸三苯酯 在 potassium carbonate 作用下， 130.0~220.0 ℃ 、1.33 kPa 条件下， 生成 二(4-叔-丁基苯基)苯基磷酸酯
  参考文献：
  名称：

  Preparation of Flame-Resistant Liquids Based on Mixed Tri(phenyl, p-tert-butylphenyl) Phosphates by Transesterification of Triphenyl Phosphate with p-tert-Butylphenol

  摘要：

  The possibility of controlling the composition of a mixture of triphenyl phosphate, p-tert-butylphenyl diphenyl phosphate, di(p-tert-butylphenyl)phenyl phosphate, and tri(p-tert-butylphenyl) phosphate, formed by transesterification of triphenyl phosphate withp-tert-butylphenol, was demonstrated. The amount ofp-tert-butylphenol necessary for transesterification of triphenyl phosphate to yield a mixture of phosphates of required composition was determined. If necessary, the composition of the phosphates can be adjusted by selective distillation of triphenyl phosphate in a vacuum.

  DOI：

  10.1134/s1070427220080170

文献信息

• ANTI-WEAR AGENTS WITH A REDUCED NEUROTOXICITY
  申请人：Frapin Pascal

  公开号：US20120101015A1

  公开（公告）日：2012-04-26

  Described is a lubricating composition of an anti-wear agent or a combination of anti-wear agents having a reduced neurotoxicity, the anti-wear agent(s) being selected from triaryl phosphate compounds preferably substituted with one or more linear or branched alkyl group(s) including from 2 to 12 carbon atoms.

  描述了一种具有降低神经毒性的抗磨剂或抗磨剂组合的润滑组合物，所述抗磨剂被选择自三芳基磷酸酯化合物，最好是取代有一个或多个线性或支链烷基基团（包括2至12个碳原子）的化合物。
• [EN] PROCESS FOR THE PREPARATION OF A TRIARYL PHOSPHATE ESTER COMPOSITION<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UNE COMPOSITION DE PHOSPHATE ESTER DE TRIARYLE
  申请人：PCC ROKITA SA

  公开号：WO2017140609A1

  公开（公告）日：2017-08-24

  The invention relates to a process for the preparation of a triaryl phosphate ester composition comprising a. reacting a phosphorous oxyhalide with a (C1-C15-alkyl)phenol to obtain a first product; b. reacting the first product with phenol to obtain a triaryl phosphate ester composition; wherein in step a., for every mol of phosphorous oxyhalide 1.3 to 1.6 mols of (C1-C15-alkyl)phenol are used. The invention also relates to a triaryl phosphate ester composition obtainable according to the process of the invention.

  本发明涉及一种制备三芳基磷酸酯组合物的过程，包括a.将磷氧卤素与（C1-C15烷基）苯酚反应以获得第一产物；b.将第一产物与苯酚反应以获得三芳基磷酸酯组合物；其中在步骤a中，对于每个摩尔的磷氧卤素，使用1.3至1.6摩尔的（C1-C15烷基）苯酚。本发明还涉及一种根据本发明方法获得的三芳基磷酸酯组合物。
• NOVEL TRIAZINE COMPOUND AND SYNTHETIC RESIN COMPOSITION USING SAME
  申请人：ADEKA CORPORATION

  公开号：US20170327475A1

  公开（公告）日：2017-11-16

  A novel compound excellent in heat resistance, resistance to volatilization, and compatibility with a resin component and useful as a UV absorber and a synthetic resin composition containing the compound are provided. Specifically provided are a triazine compound of general formula (1), preferably general formula (2) and a synthetic resin composition containing 0.001 to 20 parts by mass of the compound per 100 parts by mass of a synthetic resin. The details of formulae (1) and (2) are as defined in the description.

  提供了一种在耐热性、抗挥发性和与树脂成分的相容性方面表现出色的新型化合物，可用作紫外线吸收剂和含有该化合物的合成树脂组合物。具体提供的是一般式（1）的三嗪化合物，优选一般式（2）的化合物和含有该化合物每100份合成树脂中0.001至20质量份的合成树脂组合物。一般式（1）和（2）的细节如描述中定义。
• Liquid substituted 2H-benzotriazole mixtures
  申请人：CIBA-GEIGY AG

  公开号：EP0337942A1

  公开（公告）日：1989-10-18

  Liquid substituted 2H-benzotriazole mixtures are prepared by alkylation with concomitant dealkylation, fragmentation and/or realkylation of 2-(2-hydroxy-5-alkylphenyl)-2H-benzotriazoles or of 2-(2-hydroxy-3,5-dialkylphenyl)-2H-benzotriazoles with straight or branched alkenes of 8 to 40 carbon atoms in the presence of an acid catalyst at 100 - 200°C. The liquid mixtures exhibit outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the processing of stabilized compositions at elevated temperatures.

  液态取代的 2H 苯并三唑混合物是在 100 - 200°C 下，在酸催化剂存在下，通过 2-(2-羟基-5-烷基苯基)-2H-苯并三唑或 2-(2-羟基-3,5-二烷基苯基)-2H-苯并三唑与 8 - 40 个碳原子的直链或支链烯烃进行烷基化并同时进行脱烷基化、破碎和/或再烷基化而制备的。这种液态混合物在保护有机基质免受光引起的劣化方面表现出卓越的功效，并且在高温下加工稳定组合物时，具有良好的抗挥发或抗渗出性。
• ADHESIVE COMPOSITION AND ADHESIVE USING SAME
  申请人：DENKI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP1958996A1

  公开（公告）日：2008-08-20

  To provide an adhesive composition which exhibits sufficient initial strength even in a wet state right after application, and which provides a coating film having sufficient flame retardancy after it is dried, and an adhesive using it. An adhesive composition comprising a chloroprene latex (A), an aromatic phosphate ester type plasticizer (B), and a pH adjusting agent (C).

  提供一种粘合剂组合物，该组合物即使在使用后的湿润状态下也能显示出足够的初始强度，并且在干燥后能提供具有足够阻燃性的涂膜，以及使用该组合物的粘合剂。 粘合剂组合物由氯丁二烯胶乳（A）、芳香族磷酸酯类增塑剂（B）和 pH 值调节剂（C）组成。