(η5-C5Et5)Mn(CO)3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (η5-C5Et5)Mn(CO)3
• 化学式: C₁₈H₂₅MnO₃
• 分子量: 344.333
• InChiKey: IJOGPMWFYQZTNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-C5Et5)Mn(CO)3 、 三溴化铝 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Basicity of metal carbonyl complexes

  摘要：

  DOI：

  10.1007/bf00951297
• 作为产物：
  描述：

  (η-5-C5Et5)Mn(CO)2Xe 、 一氧化碳 以 further solvent(s) 为溶剂， 生成 (η5-C5Et5)Mn(CO)3
  参考文献：
  名称：

  An Investigation into the Reactivity of Organometallic Noble Gas Complexes:  A Time-Resolved Infrared Study in Supercritical Noble Gas and Alkane Solution at Room Temperature

  摘要：

  A series of Group 7 organometallic noble gas complexes, (eta(5)-C5R5)M(CO)(2)L(M = Mn and Re; R = H, Me. and Et (Mn only); L = Kr and Xe) have been characterized in supercritical noble gas solution at room temperature using fast time-resolved infrared spectroscopy. The kinetics and activation parameters for the reaction of these complexes with CO were measured and compared to the analogous alkane complexes, (eta(5)-C5H5)M(CO)(2)(n-heptane) (M = Mn and Re). Evidence obtained from values of the activation enthalpies and experiments, in which the lifetimes of (eta(5)-C5R5)Mn(CO)(2)Xe (R = H, Me, and Et) were measured as a function of [CO] at a constant [CO]/[Xe] ratio, suggests that the reaction of the noble gas complexes with CO occurs mainly via a dissociative or dissociative interchange mechanism.

  DOI：

  10.1021/jp993736v

文献信息

• Basicity of metal carbonyl complexes
  作者：A. G. Ginzburg、V. N. Setkina、D. N. Kursanov

  DOI：10.1007/bf00951297

  日期：1985.2
• Basicity of metal carbonyl complexes Communication 15. Interaction of group VI and VII metal ?-complexes with mercury acetate and trifluoroacetate
  作者：A. G. Ginzburg、V. N. Setkina、D. N. Kursanov

  DOI：10.1007/bf00956165

  日期：1983.5
• Basicity of metal carbonyl complexes communication 17. Protonation of manganese and rhenium cyclopentadienylcarbonyl complexes
  作者：A. G. Ginzburg、P. V. Petrovskii、V. N. Setkina、D. N. Kursanov

  DOI：10.1007/bf01157349

  日期：1985.1
• Hydrogen bond of transition metal carbonyl complexes with perfluoro-tert-butanol
  作者：B. V. Lokshin、S. G. Kazaryan、A. G. Ginzburg

  DOI：10.1007/bf00965357

  日期：1988.3
• Gur'yanova, E. N.; Isaeva, E. S.; Ginzburg, A. G., Koordinatsionnaya Khimiya, 1987, vol. 13, p. 20 - 27
  作者：Gur'yanova, E. N.、Isaeva, E. S.、Ginzburg, A. G.

  DOI：——

  日期：——