全氟(5-氮杂-4-壬烯) | 103573-07-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 亚胺酰卤
• 中文名称: 全氟(5-氮杂-4-壬烯)
• 中文别名: 丁亚胺酰基氟化,2,2,3,3,4,4,4-七氟-N-(九氟亚丁基)-
• 英文名称: perfluoro-5-aza-4-nonene
• 英文别名: Perfluoro-5-azanon-4-ene；Perfluoro(5-aza-4-nonene)；2,2,3,3,4,4,4-heptafluoro-N-(1,1,2,2,3,3,4,4,4-nonafluorobutyl)butanimidoyl fluoride
• CAS: 103573-07-5
• 化学式: C₈F₁₇N
• 分子量: 433.068
• InChiKey: DVQXCHAOWHNHSQ-UHFFFAOYSA-N

物化性质

• 沸点：
  99-102 °C
• 密度：
  1.71±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  全氟(5-氮杂-4-壬烯) 在 肼 作用下， 以 乙醚 为溶剂， 以28%的产率得到3,5-Bis-perfluorpropyl-1,2,4-triazol
  参考文献：
  名称：

  Solvolyis reactions of perfluoro-5-aza-4-nonene, C3F7CFNC4F9

  摘要：

  Hydrolysis of the imine perfluoro-5-aza-4-nonene, C3F7-CF=N-C4F9, in ether was studied by several spectroscopic techniques including O-17 NMR. The initial product is C3F7-CO-NH-C4F9 which is converted to (C3F7CO)(2)NH and then to C3F7CONH2 and C3F7CO2H. Solvolysis in liquid ammonia afforded the amidine C3F7-C(=NH)NH2. Reaction with hydrazine produced 3,5-bis(heptafluoropropyl)-1,2,4-triazole whose crystal structure is reported. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(03)00084-8
• 作为产物：
  描述：

  perfluoro(di-n-butylmethylamine) 在 五氟化锑 作用下， 反应 0.5h， 生成 全氟(5-氮杂-4-壬烯)
  参考文献：
  名称：

  Splitting of perfluorinated tertiary cyclic amines by the action of SbF5

  摘要：

  It was shown that perfluorinated tertiary cyclic amines are dealkylated by the action of SbF5 with the formation of cyclic azomethines. The presence of a perfluoroalkyl substitutent in the alpha-position to the nitrogen atom in the amine molecule considerably decreases its stability to the action of antimony pentafluoride.

  DOI：

  10.1007/bf00957861

文献信息

• Fluorinated monomers, fluorinated polymers having polycyclic groups with fused 4-membered heterocyclic rings, useful as photoresists, and processes for microlithography
  申请人：Feiring E. Andrew

  公开号：US20060167284A1

  公开（公告）日：2006-07-27

  The present invention provides novel fluorine-containing copolymers which comprise at least one fluorinated olefin, at least one polycyclic ethylenically unsaturated monomer with a fused 4-membered heterocyclic ring and, optionally, other components. The copolymers are useful for photoimaging compositions and, in particular, photoresist compositions (positive-working and/or negative-working) for imaging in the production of semiconductor devices. The copolymers are especially useful in photoresist compositions having high UV transparency (particularly at short wavelengths, e.g., 157 nm) which are useful as base resins in resists and potentially in many other applications.

  本发明提供了一种新型的含氟共聚物，其包括至少一种含氟烯烃，至少一种具有融合的4-成员杂环环的多环乙烯不饱和单体，以及可选的其他组分。这些共聚物对于光刻成分特别是用于半导体器件生产中成像的光刻成分（正作用和/或负作用）非常有用。这些共聚物在具有高紫外透明度的光刻成分中特别有用（特别是在短波长，例如157纳米处），这些光刻成分可用作光刻胶的基础树脂，并且潜在地在许多其他应用中也很有用。
• Fluorinated triazapentadienyl ligand supported ethyl zinc(<scp>ii</scp>) complexes: reaction with dioxygen and catalytic applications in the Tishchenko reaction
  作者：Naveen V. Kulkarni、Animesh Das、Shawn G. Ridlen、Erin Maxfield、Venkata A. K. Adiraju、Muhammed Yousufuddin、H. V. Rasika Dias

  DOI：10.1039/c6dt00257a

  日期：——

  bridging-ethoxy or -ethylperoxy groups. The ethyl zinc complexes catalyze the Tishchenko reaction of benzaldehyde under solventless conditions affording benzyl benzoate. The reaction of ethyl zinc complexes with dioxygen and their catalytic behaviour in the Tishchenko reaction are affected by the electronic and steric factors of the triazapentadienyl ligand. [N(C3F7)C(Cy)N}2]ZnOOEt}2 is an excellent reagent

  乙基锌络合物[N （C 3 F 7）C（Dipp）N} 2 ] ZnEt，[N （C 3 F 7）C（Cy）N} 2 ] ZnEt，[N （CF 3）C（由2,4,6-Br 3 C 6 H 2）N} 2 ] ZnEt和[N （C 3 F 7）C（2,6-Cl 2 C 6 H 3）N} 2 ] ZnEt合成相应的1,3,5-三氮杂戊二烯和二乙基锌。X射线数据显示[N （C 3 F 7）C（Dipp）N} 2] ZnEt在锌中心具有变形的三角形平面几何形状。所述triazapentadienyl配体结合到锌在κ 2 -mode。[N （C 3 F 7）C（Dipp）N} 2 ] ZnEt，[N （C 3 F 7）C（Cy）N} 2 ] ZnEt，[N （CF 3）C（2,4,6-Br 3 C 6 H 2）N} 2 ] ZnEt和[N （C 3 F 7）C（2,6-Cl 2 C
• Synthesis of nitrogen-containing heterocyclic compounds using perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene
  作者：Ki-Whan Chi、Georgii G Furin、Yurii V Gatilov、Irina Yu Bagryanskay、Eduard L Zhuzhgov

  DOI：10.1016/s0022-1139(99)00310-3

  日期：2000.4

  perfluoro-5-azanon-4-ene with a range of bidentate nitrogen nucleophiles (urea, acet-, benz-, 4-nitrobenz-amidine hydrochloride, 2-aminopyridine, 2-aminobenzimidazole, guanidine) in the presence of Et3N or KOH effectively provided partially fluorinated heterocycles of pyrimidine, 2H-pyrido[1,2-a]pyrimidine and [1,3,5]triazine derivatives. The structure of 2-pentafluoroethyl-3-trifluoromethyl-pyrido[1,2-a]pyrimidin-4-one

  全氟-2-甲基戊-2-ena或全氟-5-氮杂-4-烯与一系列双齿氮亲核试剂的反应（脲，盐酸，乙酰，苯，4-硝基苯-盐酸盐，2-氨基吡啶，2-氨基苯并咪唑，胍）在Et 3 N或KOH的存在下可有效地提供嘧啶，2H-吡啶并[1,2-a]嘧啶和[1,3,5]三嗪衍生物的部分氟化杂环。通过X射线晶体学分析进一步证实了2-五氟乙基-3-三氟甲基-吡啶并[1,2-a]嘧啶-4-酮的结构。
• Copper(I) Ethylene Complexes Supported by 1,3,5-Triazapentadienyl Ligands with Electron-Withdrawing Groups
  作者：Venkata A.K. Adiraju、Jaime A. Flores、Muhammed Yousufuddin、H. V. Rasika Dias

  DOI：10.1021/om300567v

  日期：2012.11.26

  ligands in copper(I) ethylene chemistry. [N(C3F7)C(2-(NO2)C6H4)N}2]Cu(C2H4) (7), [N(C3F7)C(4-(NO2)C6H4)N}2]Cu(C2H4) (8), [N(C3F7)C(2-(CF3)C6H4)N}2]Cu(C2H4) (9), and [N(C3F7)C(2-F,6-(CF3)C6H3)N}2]Cu(C2H4) (10) are easily isolable, thermally stable solids and display their ethylene proton and carbon resonances in the δ 3.68–3.48 and 85.2–87.6 ppm regions, respectively. X-ray crystal structures reveal

  氟化的1,3,5-三氮杂戊二烯基配体[N （C 3 F 7）C（2-（NO 2）C 6 H 4）N} 2 ] -，[N （C 3 F 7）C（4 -（NO 2）C 6 H 4）N} 2 ] -，[N （C 3 F 7）C（2-（CF 3）C 6 H 4）N} 2 ] -和[N （C 3 F 7）C（2-F，6-（CF 3）C 6 H 3）N}2 ] -在铜（I）乙烯化学中已用作支撑配体。[N （C 3 F 7）C（2-（NO 2）C 6 H 4）N} 2 ] Cu（C 2 H 4）（7），[N （C 3 F 7）C（4- （NO 2）C 6 H 4）N} 2 ] Cu（C 2 H 4）（8），[N （C 3 F 7）C（2-（CF 3）C 6 H 4）N} 2] Cu（C 2 H 4）（9）和[N （C 3 F 7）C（2-F，6-（CF 3）C 6 H 3）N} 2 ] Cu（C
• Reaction of perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene with aniline and its derivatives
  作者：Ki-Whan Chi、Georgii G Furin、Irina Yu Bagryanskay、Yurii V Gatilov

  DOI：10.1016/s0022-1139(00)00247-5

  日期：2000.7

  Reaction of perfluoro-2-methylpent-2-ene (1) and perfluoro-5-azanon-4-ene (2) with aniline, 4-fluoroaniline, 4-methoxyaniline and 2,6-dimethylaniline in the presence of Et3N provides derivatives of quinoline and quinozaline, whereas reaction of 2 yields diazetine derivatives with 2- and 4-nitroanilines, 2,6-dichloroaniline and pentafluoroaniline. The structure of [2-(1,1,2,2,3,3,3-pentafluoroethyl

  在Et 3 N存在下，全氟-2-甲基戊-2-烯（1）和全氟5-氮杂壬4-烯（2）与苯胺，4-氟苯胺，4-甲氧基苯胺和2,6-二甲基苯胺的反应可以提供喹啉和喹唑啉的衍生物，而2的反应可生成二氮杂苯胺衍生物，包括2-和4-硝基苯胺，2,6-二氯苯胺和五氟苯胺。通过X射线结构数据确认了[2-（1,1,2,2,3,3,3-五氟乙基）-3-三氟甲基-喹啉-4-基]-苯胺的结构。讨论了反应路线以及产物的19 F和13 C NMR光谱数据。