六氟铝酸锂锶 | 35361-71-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属盐
• 中文名称: 六氟铝酸锂锶
• 英文名称: lithium strontium hexafluoroaluminate
• 英文别名: Aluminum;lithium;strontium;hexafluoride
• CAS: 35361-71-8
• 化学式: AlF₆*Li*Sr
• 分子量: 235.533
• InChiKey: IEPNMLJMIRCTIV-UHFFFAOYSA-H

物化性质

• 熔点：
  810 °C
• 密度：
  2.988 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  -21.73
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  strontium fluoride 、 氟化铝 、 lithium fluoride 在 HF 作用下， 以 neat (no solvent) 为溶剂， 生成 六氟铝酸锂锶
  参考文献：
  名称：

  Schaffers, Kathleen I.; Keszler, Douglas A., Acta Crystallographica, Section C: Crystal Structure Communications, 1991, vol. 47, p. 18 - 20

  摘要：

  DOI：

文献信息

• Optimized photoluminescence properties of a novel red phosphor LiSrAlF6:Mn4+ synthesized at room-temperature
  作者：Mengmeng Zhu、Yuexiao Pan、Mingmei Wu、Hongzhou Lian、Jun Lin

  DOI：10.1016/j.jallcom.2018.09.172

  日期：2019.2

  A red phosphor with a broad excitation band in blue region and sharp emission peaks in red region is needed for compensating the red components of white light-emitting diodes (WLEDs) by converting blue light with a yellow phosphor Y3Al5O12:Ce3+ (YAG:Ce). The red phosphor LiSrAlF6:Mn4+ (LSAF:Mn) with morphology of flaky particles about 50 mu m in diameter has been synthesized by an ion-exchange reaction route at room-temperature in air. The as-synthesized phosphors were characterized by x-ray powder diffraction (XRD), scanning electron microscope (SEM), and temperature-dependent photoluminescence (PL) spectra. The excitation spectrum of LSAF:Mn shows a broad-band excitation from 400 to 500 nm that is due to the spin-allowed transition of (4)A(2g) -> T-4(2g) of Mn4+, indicating a potential application for solid state lighting. The optimal PL intensity of the phosphor LSAF:Mn has been obtained by optimizing the synthetic parameters. (C) 2018 Published by Elsevier B.V.