六羟甲基三聚氰胺树脂 | 39863-30-4

• 物质功能分类: 催化剂及助剂 - 聚合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 六羟甲基三聚氰胺树脂
• 英文名称: N~2~,N~2~,N~4~,N~4~,N~6~,N~6~-Hexamethoxy-1,3,5-triazine-2,4,6-triamine
• 英文别名: 2-N,2-N,4-N,4-N,6-N,6-N-hexamethoxy-1,3,5-triazine-2,4,6-triamine
• CAS: 39863-30-4
• 化学式: C₉H₁₈N₆O₆
• 分子量: 306.28
• InChiKey: XGJZQNMUVTZITK-UHFFFAOYSA-N

物化性质

• 沸点：
  349.8±25.0 °C(Predicted)
• 密度：
  1.384±0.06 g/cm3(Predicted)
• 稳定性/保质期：
  本品为无色至微黄色的稠厚液体，属于热固型树脂初聚物范畴。遇冷会变为凝胶体，并可被冷水任意比例稀释。呈凝胶体时，可用3～5倍70～80℃的热水溶解。它能与阳离子和非离子型表面活性剂同浴使用，在高温下由可溶性变为不可溶性，并且一旦定型则不可逆。在非酸性水中，它可以保持数天。

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  21
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  104
• 氢给体数：
  0
• 氢受体数：
  12

制备方法与用途

化学性质： 本品为无色至微黄色稠厚液体，属于热固型树脂初聚物范畴。遇冷会变为凝胶体，并可被冷水以任意比例稀释。当呈凝胶体状态时，可用3～5倍的热水（70～80℃）溶解。它能与阳离子和非离子型表面活性剂同浴使用。在高温下由可溶性变为不可溶性，一旦定型便不可逆。此外，在非酸性水中可以保持数天。

生产方法： 将32kg甲醛(37%水溶液)加入反应釜中，并用碱调节pH值至8.0。在搅拌下缓缓加入7.5kg三聚氰胺，加热至70℃后停止加热，温度自然上升至80～85℃并继续搅拌1小时。随后冷却并用水稀释至规定含量，搅拌15分钟后出料即为成品。

反应信息

• 作为反应物：
  描述：

  六羟甲基三聚氰胺树脂 以86的产率得到六甲蜜胺
  参考文献：
  名称：

  Process for the production of methylamino-s-triazines

  摘要：

  甲基氨基-S-三嗪通过在惰性溶剂中，在镍催化剂存在下，在压力下加氢醚并在70℃至150℃之间的温度下制得。实例描述了以六甲基氨基甲醛三嗪-六甲基醚和N，N1，N11-三甲基氨基甲醛三嗪-三甲基醚为起始材料，分别在加氢后得到六甲基三嗪和N，N1，N11-三甲基三嗪。

  公开号：

  US03424752A1

文献信息

• COMPOSITION CONTAINING VINYL-GROUP-CONTAINING COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160046552A1

  公开（公告）日：2016-02-18

  A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

  这个组合物包含一种含有新颖乙烯基团的化合物。该组合物包含一个由通式（1）表示的含有乙烯基团的化合物。在该式中：W1和W2代表由通式（2）表示的一个基团（其中环（Z）是芳香烃环，X是一个单键或—S—，R1是一个单键或C1-4烷基基团，R2是特定的取代基团，如一价碳氢化合物，m是大于或等于0的整数），一个由通式（4）表示的基团（其中环（Z）、X、R1、R2和m如前述），一个羟基，或一个（甲基）丙烯酰氧基团；环（Y1、Y2）是芳香烃环；R代表一个单键或一个特定的二价基团；R3a和R3b代表氰基、卤素原子或一价碳氢基团；n1和n2是0-4的整数。
• Reactive monomer composition modified by a small-amount of lactones, an acrylic polyol resin, a curable resin composition, and a coating composition
  申请人：——

  公开号：US20040171867A1

  公开（公告）日：2004-09-02

  The present invention Nos. I and II relate to a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones in which a proportion of monomers having two or more continuous chains (n≧2) of lactone is less than 50% (area % by GPC) which is obtained by a ring-opening polymerization of a lactone with a hydroxyalkyl(meth)acrylate, a method for the preparation thereof, and an acrylic polyol resin using thereof, 1 (in the formula, R, R 1 , R 2 , and R 3 are independently a hydrogen or a methyl group, “j” is an integer of 2-6, xn pieces of R 4 and R 5 are independently a hydrogen atom or an alkyl group having a carbon number of 1-12, “x” is 4-7, “n” is 0 or an integer of not less than 1, and an average value of “n” in the composition is not less than 0.3 to less than 1.0). By allowing to react the composition with other ethylenic unsaturated monomer and to formulate with a commonly-used crosslinking agent and other commonly-used components, there can be obtained a well-balanced high quality finishing agent for industries, an ultraviolet ray- or electron beam-curable coating agent, a composition which can be modified for a reactive improver, etc., and an acrylic polyol resin using thereof. The present invention No. III relates to a curable resin composition containing 0.5-80 parts by weight of an acrylic polyol resin (A) obtained using a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones and 0.5-50 parts by weight of a melamine resin (B) [total of the (A) and (B) does not exceed, 100 parts by weight] as essential components. By the composition, even in a melamine-based curing system which is low in price, there can be obtained a curable-type coating composition in which an acid resistance is improved and highly well-balanced between an acid resistance and abrasion resistance, and which is also excellent in flexural resistance and adhesion in recoating. The present invention No. IV relates to a curable resin composition containing 0.5-80 parts by weight of an acrylic polyol resin (A) containing a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones as a polymerizing component and 0.5-50 parts by weight of a melamine resin (B) [total of the (A) and (B) does not exceed 100 parts by weight] as essential components. By the composition, even in a melamine-based curing system which is low in price, there can be obtained a curable-type coating composition in which an acid resistance is improved and highly well-balanced between an acid resistance and abrasion resistance. The present invention No. V relates to a curable resin composition containing 0.5-80 parts by weight of an acrylic polyol resin (A) obtained using a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones and 0.5-50 parts by weight of a polyisocyanate compound (B) [total of the (A) and (B) does not exceed 100 parts by weight] as essential components. By the composition, even in an isocyanate-based curing system, there can be obtained a curable-type coating composition in which a pot life is long and workability is improved, and which is highly well-balanced between an acid resistance and abrasion resistance, and which can provide a coating layer which is excellent also in flexural resistance and adhesion in recoating. The present invention No. VI relates to a curable resin composition containing 0.5-80 parts by weight of an acrylic polyol resin (A) obtained using a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones and 0.5-50 parts by weight of a polyisocyanate compound (B) [total of the (A) and (B) does not exceed 100 parts by weight] as essential components. By the composition, even in an isocyanate-based curing system, there can be obtained a curable-type coating composition in which a pot life is long and workability is improved, and which is highly well-balanced between an acid resistance and abrasion resistance, and which can provide a coating layer which is excellent also in flexural resistance and adhesion in recoating. The present invention No. VII relates to a thermosetting resin composition containing 2-50 parts of an acrylic polyol resin obtained using a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones and 30-80 parts of an acrylic copolymer having an alkoxysilyl group. By the composition, there can be obtained a thermosetting resin composition in which crosslinking density is elevated and hardness and abrasion resistance are improved as well as solving a problem of acid resistance and odor. The present invention No. VIII relates to a carboxylic group-contained acrylate composition (a′) modified by a small amount of lactones represented by a formula described below by allowing to react a hydroxyalkyl(meth)acrylate composition (a) modified by a small amount of lactones with a carboxylic anhydride, 2 (in the formula, R, R 1 , R 2 , and R 3 are independently a hydrogen or a methyl group, “j” is an integer of 2-6, xn pieces of R 4 and R 5 are independently a hydrogen atom or an alkyl group having a carbon number of 1-12, “x” is 4-7 , “n” is 0 or an integer of not less than 1, an average value of “n” in the composition is not less than 0.3 to less than 1.0 , R 6 is a residual group of a carboxylic acid, and “m” is an integer of 1-3), and relates to a method for the preparation thereof. By the method, there can be readily, efficiently, and economically obtained the carboxylic group-contained acrylate monomer composition modified by a small amount of lactones. The present invention No. IX relates to a curable resin composition containing 10-70 parts of an acrylic polycarboxylic resin essentially containing the carboxylic group-contained hydroxy(meth)acrylate monomer composition (a′) modified by a small amount of lactones as a polymerizing component and 0.5-80 parts of a polyepoxide. By the composition, there can be obtained a curable-type resin composition which can form a coating layer which is excellent in acid resistance, abrasion resistance, yellowing resistance, and outer appearance, and which is curable at a low temperature. The present invention No. X relates to a polyester unsaturated monomer (a″) modified by a small amount of lactones in which less than 1 mol of &egr;-caprolactone is allowed to react with 1 mol of a radically polymerizable unsaturated monomers containing carboxylic group under the presence of an acidic catalyst, and relates to a method for the preparation thereof. By the method, there can be readily and industrially prepared the monomer in a short step.

  本发明涉及一种由少量内酯修饰的羟基烷基（甲基）丙烯酸酯组合物（a），其中具有两个或多个连续链（n≥2）的内酯单体的比例小于50％（GPC的面积％），其通过羟基烷基（甲基）丙烯酸酯与内酯的开环聚合获得，以及制备方法和使用其的丙烯酸聚醇树脂。其中，在公共使用的交联剂和其他常用组分的反应下，可以获得工业上平衡良好的高质量涂料剂、紫外线或电子束固化涂料剂、可用于反应改进剂的组合物等。本发明还涉及含有0.5-80重量份羟基烷基（甲基）丙烯酸酯组合物（a）修饰的丙烯酸聚醇树脂（A）和0.5-50重量份三聚氰胺树脂（B）的可固化树脂组合物（A）和（B）的总重量不超过100重量份的可固化树脂组合物（III）。此外，还涉及含有0.5-80重量份羟基烷基（甲基）丙烯酸酯组合物（a）修饰的丙烯酸聚醇树脂（A）和0.5-50重量份聚异氰酸酯化合物（B）的可固化树脂组合物（A）和（B）的总重量不超过100重量份的可固化树脂组合物（V）和（VI）。还涉及含有羟基烷基（甲基）丙烯酸酯组合物（a）修饰的丙烯酸聚醇树脂（A）和具有烷氧基硅基团的丙烯酸共聚物的热固性树脂组合物（VII）。此外，还涉及通过使少量内酯与羟基烷基（甲基）丙烯酸酯组合物（a）在存在酸性催化剂的情况下反应而得到的含有羧基丙烯酸酯组合物（a′）的修饰物，以及含有羧基丙烯酸酯组合物（a′）和聚环氧化合物的可固化树脂组合物（IX）。最后，还涉及通过在存在酸性催化剂的情况下使少于1摩尔的ε-己内酯与含有羧基团的自由基聚合可的不饱和单体反应而得到的少量内酯修饰的聚酯不饱和单体（a″）以及其制备方法。
• METHOD FOR PRODUCTION OF ORGANIC-INORGANIC COMPLEX, ORGANIC-INORGANIC COMPLEX, AND POLYMERIC COMPOSITE MATERIAL
  申请人：Tamura Kenji

  公开号：US20090227715A1

  公开（公告）日：2009-09-10

  Disclosed are: a method for production of an organic-inorganic complex by intercalation of a positively charged organic compound between layers of a non-swellable layered silicate which is believed to be difficult to achieve under convenient conditions; the organic-inorganic complex; and a layered silicate/polymer nanocomposite using the organic-inorganic complex. The method comprises: step (I) wherein a hydrous layered silicate having a hydroxyl group in its crystalline structure is heat-treated at a temperature not higher than 1,200° C. and lower than the phase transition temperature of the silicate to dehydrate the silicate; and step (II) wherein the dehydrated layered silicate is contacted with an aqueous solution of a positively charged organic compound.

  本发明涉及一种通过将正电有机化合物插层到非膨胀层状硅酸盐的层间来制备有机-无机复合物的方法，该方法被认为在方便条件下很难实现；所述有机-无机复合物；以及使用所述有机-无机复合物的层状硅酸盐/聚合物纳米复合材料。该方法包括：步骤（I），其中将具有晶体结构中羟基的水合层状硅酸盐在不高于1,200℃且低于硅酸盐相变温度的温度下进行热处理以脱水硅酸盐；以及步骤（II），其中将脱水的层状硅酸盐与正电有机化合物的水溶液接触。
• Negative-working resist composition for electron beams or X-rays
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20020192592A1

  公开（公告）日：2002-12-19

  A negative-working resist composition for electron beams or X-rays comprising (A) a compound generating a sulfonic acid by the irradiation of electron beams or x-rays, (B) a resin which is insoluble in water and soluble in an alkali aqueous solution, (C) a crosslinking agent crosslinking with the resin (B) by the action of an acid, and (D) a compound generating a carboxylic acid having a specific structure by the irradiation of electron beams or x-rays.

  一种用于电子束或X射线的负型光刻胶组合物，包括（A）通过电子束或X射线辐射产生磺酸的化合物，（B）在水中不溶而在碱性水溶液中可溶的树脂，（C）通过酸作用与树脂（B）交联的交联剂，以及（D）通过电子束或X射线辐射产生具有特定结构的羧酸的化合物。
• Photoacid generators for use in photoresist compositions
  申请人：ARCH SPECIALTY CHEMICALS, INC.

  公开号：US20020197558A1

  公开（公告）日：2002-12-26

  A photoacid compound having the following general structure: R—O(CF 2 ) n SO 3 X wherein n is an integer between about 1 to 4; R is selected from the group consisting of: substituted or unsubstituted C 1 -C 12 linear or branched alkyl or alkenyl, substituted or unsubstituted araalkyl, substituted or unsubstituted aryl, substituted or unsubstituted bicycloalkyl, substituted or unsubstituted tricycloalkyl, hydrogen, alkyl sulfonic acid, substituted or unsubstituted perfluoroalkyl, the general structure F((CF 2 ) p O) m (CF 2 ) q — wherein p is between about 1 to 4, m is between about 0 to 3 and q is between about 1 to 4, and substituted or unsubstituted partially fluorinated alkyl, halofluoroalkyl, perfluoroalkylsulfonic, or glycidyl; and X is selected from the group consisting of: organic cations and covalently bonded organic radicals.

  具有以下一般结构的光酸化合物：R—O（CF2）nSO3X，其中n是介于1到4之间的整数；R选自以下组合：取代或未取代的C1-C12线性或支链烷基或烯基，取代或未取代的araalkyl，取代或未取代的芳基，取代或未取代的双环烷基，取代或未取代的三环烷基，氢，烷基磺酸，取代或未取代的部分氟化烷基，一般结构F（（CF2）pO）m（CF2）q—其中p介于1到4之间，m介于0到3之间，q介于1到4之间，以及取代或未取代的部分氟化烷基，卤氟烷基，全氟烷基磺酸或环氧丙基；X选自有机阳离子和共价键合有机基团的组合。