1,2-bis(4-(4-(4-hexyloxybenzoyloxy)benzylideneamino)phenoxy)ethane

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 1,2-bis(4-(4-(4-hexyloxybenzoyloxy)benzylideneamino)phenoxy)ethane
• 英文别名: 2ES6；[4-[[4-[2-[4-[[4-(4-Hexoxybenzoyl)oxyphenyl]methylideneamino]phenoxy]ethoxy]phenyl]iminomethyl]phenyl] 4-hexoxybenzoate；[4-[[4-[2-[4-[[4-(4-hexoxybenzoyl)oxyphenyl]methylideneamino]phenoxy]ethoxy]phenyl]iminomethyl]phenyl] 4-hexoxybenzoate
• 化学式: C₅₄H₅₆N₂O₈
• 分子量: 861.047
• InChiKey: QSBCUIVUSDDOSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.6
• 重原子数：
  64
• 可旋转键数：
  27
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  114
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1-硝基-4-[2-(4-硝基苯氧基)乙氧基]苯 在 palladium on activated charcoal 、 对甲苯磺酸 、 一水合肼 作用下， 以 乙醇 为溶剂， 反应 16.0h， 生成 1,2-bis(4-(4-(4-hexyloxybenzoyloxy)benzylideneamino)phenoxy)ethane
  参考文献：
  名称：

  Liquid crystal dimers having vary oxyethylene flexible spacers

  摘要：

  In this article, we are prepared that the liquid crystal dimers have aromatic-ester type mesogenic units or aromatic-Schiff base typemesogonic units and confirmed by H-1-NMR spectrometry. The mesomorphic and optical properties of the resultant dimers were studied by differential scanning calorimetry and polarizing optical microscopy.

  DOI：

  10.1080/15421406.2016.1263102

文献信息

• Synthesis of Symmetric Liquid Crystal Dimers Based on 1,2-bis{-[-(4-alkoxybenzoyloxy)benzylidene]amino)phenoxy}ethane and Investigation of Phase Behaviour by Varying Alkoxy Terminal Chain Length
  作者：Chang Sin Lee、Tae Hyeong Kim、B. Ramaraj、Seok Gn Ryu、Hyun Hoon Song、Soo-Min Lee、Kuk Ro Yoon

  DOI：10.1080/15421400802331091

  日期：2008.10.9

  With the objective to study the effect of alkoxy terminal chain length on mesomorphic properties of liquid crystals, We have synthesized ester and Schiff base dimers from diamine derivative containing 1,2-dioxyethylene as short spacer with aldehyde derivatives having different lengths of terminal alkoxy chains (n=6-12). The chemical structure of the final products was investigated by fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (H-1 NMR) spectroscopy. The mesomorphic properties and optical textures of the resultant dimers were characterized by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). It was found that all the dimers show mesomorphic properties and the increase in terminal alkoxy chain length has pronounced effect on the mesomorphic properties. The temperature range of smectic phase window widens and nematic-isotropic phase window narrows sharply with increasing alkoxy chain length.
• Liquid crystal dimers having vary oxyethylene flexible spacers
  作者：Joo Hoon Park、Bal Sydulu Singu、Ok Byung Choi、Hwan Myung Lee、Jin Young Lee、Sung Jo Kim、Eun Hee Cha、Seon Nam Park、Myeong Heon Kwak、Bong Keun So、Ran Hee Kim、Soo Min Lee、Kuk Ro Yoon

  DOI：10.1080/15421406.2016.1263102

  日期：2017.6.13

  In this article, we are prepared that the liquid crystal dimers have aromatic-ester type mesogenic units or aromatic-Schiff base typemesogonic units and confirmed by H-1-NMR spectrometry. The mesomorphic and optical properties of the resultant dimers were studied by differential scanning calorimetry and polarizing optical microscopy.