[3-formyl-4-[4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [3-formyl-4-[4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoate
• 化学式: C₃₇H₃₄O₁₅
• 分子量: 718.668
• InChiKey: PTZKATAFQPQVSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  52
• 可旋转键数：
  27
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  193
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  9-amino-3-methylcarbazole 、 [3-formyl-4-[4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoate 在 camphor-10-sulfonic acid 作用下， 以 四氢呋喃 为溶剂， 反应 23.0h， 以89%的产率得到[3-[(E)-(3-methylcarbazol-9-yl)iminomethyl]-4-[4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoate
  参考文献：
  名称：

  [EN] NEW POLYMERIZABLE LIQUID CRYSTAL HAVING A CARBAZOLE CORE
  [FR] NOUVEAU CRISTAL LIQUIDE POLYMÉRISABLE AYANT UN COEUR CARBAZOLE

  摘要：

  该发明涉及公式（I）的新型各向异性化合物，以及包含该化合物的液晶混合物、薄膜和电光器件。

  公开号：

  WO2020260617A1
• 作为产物：
  描述：

  1H-吲唑,6-溴-4-氯- 在 吡啶 、 草酰氯 、 2,2,6,6-四甲基哌啶氧化物 、 4-甲氧基苯酚 、 N,N-二甲基甲酰胺 、 sodium hydroxide 作用下， 以 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 66.0h， 生成 [3-formyl-4-[4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoate
  参考文献：
  名称：

  [EN] NEW POLYMERIZABLE LIQUID CRYSTAL HAVING A CARBAZOLE CORE
  [FR] NOUVEAU CRISTAL LIQUIDE POLYMÉRISABLE AYANT UN COEUR CARBAZOLE

  摘要：

  该发明涉及公式（I）的新型各向异性化合物，以及包含该化合物的液晶混合物、薄膜和电光器件。

  公开号：

  WO2020260617A1

文献信息

• NEW POLYMERIZABLE LIQUID CRYSTAL HAVING A CARBAZOLE CORE
  申请人：Rolic Technologies AG

  公开号：EP3990430A1

  公开（公告）日：2022-05-04
• LIQUID CRYSTAL COMPOSITION AND ANISOTROPIC MATERIAL
  申请人：Yoshida Aiko

  公开号：US20080023670A1

  公开（公告）日：2008-01-31

  A liquid crystal composition, containing a compound represented by formula (I) and a compound represented by formula (II); and an anisotropic material containing the liquid crystal composition: wherein, Q1 and Q2 represent a polymerizable group, SP1 and SP2 represent a spacer group, X1 and X2 represent a linking group, MG represents a mesogen group, R a , R b and R c represent -L 1 -R 1 , -L 2 -R 2 or —NHR, at least one of R a , R b and R c is —NHR, L 1 and L 2 represent a single bond or a divalent linking group, R 1 and R 2 represent a hydrogen atom or a substituent, and R represents a group having a polymerizable group.
• Optical Compensation Sheet, Polarizing Plate and Liquid Crystal Display
  申请人：Fukagawa Nobutaka

  公开号：US20090033835A1

  公开（公告）日：2009-02-05

  An optical compensation sheet is provided and has a stretched polymer film or stretched cellulose acylate film and at least one optical anisotropic layer containing a liquid crystal compound, and has retardations satisfying the specific relationships defined in the specification.
• LIQUID CRYSTAL COMPOSITION AND RETARDATION FILM
  申请人：Takeuchi Hiroshi

  公开号：US20100078593A1

  公开（公告）日：2010-04-01

  The invention relates to a liquid crystal composition comprising two or more species of liquid crystal compounds respectively having a polymerizable group, at least one species of which being a compound represented by formula (I) below, having a content of the compound of from 20% to 80% relative to the total mass of said two or more species of liquid crystal compounds. In formula (I), P 1 represents a polymerizable group; each of L 1 and L 2 represents a divalent spacer group; each of Z 1 to Z 4 represents a divalent linking group; each of A 1 and A 2 represents a divalent cyclic group; each of m and n represents an integer from 0 to 3; MA represents any one group of A-I to A-V below:
• POLYMER, COMPOSITION, OPTICAL FILM, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20170121441A1

  公开（公告）日：2017-05-04

  A polymer having a partial structure formed by performing radical polymerization with respect to a compound having a mesogenic group derived from at least one type of liquid crystal compound selected from a rod-like liquid crystal compound and a disk-like liquid crystal compound, and two or more polymerizable groups, in which the polymer is a branched polymer, and a composition containing the polymer, an optical film, and a liquid crystal display device.